Highly effective viscosity-reducing agent for thermodynamic oil extraction process

A technology of thermal oil recovery and viscosity reducer, which is applied in the direction of drilling compositions, chemical instruments and methods, etc., can solve the problems of difficult thermal oil recovery process practicality, limited viscosity reduction ability, limited wax crystal ability, etc. Timeliness problem, strong viscosity and pour point reduction ability, simple implementation effect

Active Publication Date: 2013-04-24
盘锦河升大地石油科技有限公司
View PDF5 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The water-soluble viscosity reducer is mainly composed of surfactant and water, and has the following defects when used in thermal oil recovery technology: first, it mainly uses the principle of emulsification to reduce viscosity, and cannot directly dissolve asphaltenes, colloids, and wax crystals. The viscosity-reducing effect is limited; second, it is difficult to automatically diffuse into the crude oil after being injected into the oil layer from the oil well; third, there is no effect or the opposite effect when the crude oil in the oil layer has a low water content
[0004] The oil-in-water emulsion viscosity reducer is mainly composed of surfactants, water and organic solvents. It has the following defects when used in thermal oil recovery technology: First, it mainly uses the principle of emulsification to reduce viscosity, directly dissolves and breaks asphaltenes, Colloids and wax crystals have limited ability to reduce viscosity; second, it is difficult to automatically diffuse into the crude oil after being injected into the oil layer from the oil well; third, the effect is extremely poor or opposite when the water content of the oil layer is low; The oil emulsion immediately delaminates under the heating of high-temperature fluid, and the synergistic injection construction process cannot be realized
[0005] Oil-soluble viscosity reducers are mainly composed of oil-soluble pour point depressants, organic solvents, etc., and have the following defects: First, although oil-soluble viscosity reducers can inhibit or disperse wax crystals, colloids, and asphaltenes, they cannot make them reach the true level. The size of the sol particles has a limited ability to reduce viscosity; the second is that its flash point is low, and there are construction safety problems when it is injected with high-temperature fluid; the third is that it is highly targeted and the workload of the screening test is large; the fourth is that it cannot solve the emulsification existing in the oil layer. Particle clogging; Fifth, there is a problem of timeliness, that is, its viscosity-reducing ability will continue to decrease with time; Sixth, its high cost makes it difficult to apply large doses in thermal oil recovery processes
[0006] Organic solvent-type viscosity reducers are mainly composed of hydrocarbon organic solvents, and have the following defects: first, they have limited solubility for wax crystals and colloids, and extremely poor solubility for layered asphaltene, so their viscosity reduction capabilities are limited; The flash point is low, and there are construction safety problems when it is injected with high-temperature fluid; third, it is difficult to suppress the geometric size of asphaltene and wax crystal structure; fourth, it cannot solve the problem of emulsified particle clogging in the oil layer; fifth, it has timeliness The problem is that its viscosity-reducing ability will continue to decrease with the extension of time; the sixth is that the addition amount is too large, resulting in a significant increase in production costs, and it is difficult to be practical in thermal oil recovery processes
[0007] In short, the existing viscosity reducers have poor practicability in thermal oil recovery technology and are difficult to apply on a large scale

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] A kind of high-efficiency viscosity reducer for thermal oil recovery process of the present invention, it is made up of the following raw materials by weight:

[0046] 1) Biphenyl 4%;

[0047] 2) Diesel 35%;

[0048] 3) Sodium alkyl sulfonate 18%;

[0049] 4) fusel oil 5%;

[0050] 5) Ethylene glycol butyl ether 10%;

[0051] 6) Alkylphenol formaldehyde resin 2%;

[0052] 7) Performic acid 0.5%,

[0053] Dicumyl peroxide 0.5%;

[0054] 8) Urea 20%;

[0055] 9) Cyclopentanone 5%

[0056] The content of chlorine element and sulfur element in the diesel oil is less than one thousandth. The high-efficiency viscosity reducing agent used in the thermal oil recovery process of the present invention is prepared by mixing the above-mentioned raw materials at normal temperature and pressure.

Embodiment 2

[0058] A kind of high-efficiency viscosity reducer for thermal oil recovery process of the present invention, it is made up of the following raw materials by weight:

[0059] 1) Naphthalene 0.1%;

[0060] 2) 97.7% of natural hydrocarbon aggregates in granular state at room temperature;

[0061] 3) Alkyl trimethyl amine chloride 0.1%;

[0062] 4) fusel oil 0.5%;

[0063] 5) Diethylene glycol ether 0.5%;

[0064] 6) Polyacrylate 0.1%;

[0065] 7) Ammonium carbonate 0.5%;

[0066] 8) cyclopentanone 0.5%;

[0067] The content of chlorine element and sulfur element in the hydrocarbon natural aggregate in the particle state at normal temperature is less than one thousandth. The high-efficiency viscosity reducing agent used in the thermal oil recovery process of the present invention is prepared by mixing the above-mentioned raw materials at normal temperature and pressure.

Embodiment 3

[0069] A kind of high-efficiency viscosity reducer for thermal oil recovery process of the present invention, it is made up of the following raw materials by weight:

[0070] 1) methylnaphthalene 1%;

[0071] 2) Emulsified diesel oil 89%;

[0072] 3) Polyoxyethylene alkyl phenol ether carboxylic acid sodium salt 1%;

[0073] 4) fusel oil 1%;

[0074] 5) Diethylene glycol butyl ether 1%;

[0075] 6) Polyvinylcarboxylate 1%;

[0076] 7) Dibenzoyl peroxide 2%;

[0077] 8) Ammonium bicarbonate 2%;

[0078] 9) Hexanone 2%;

[0079] The content of chlorine element and sulfur element in the emulsified diesel oil is less than one thousandth. The high-efficiency viscosity reducing agent used in the thermal oil recovery process of the present invention is prepared by mixing the above-mentioned raw materials at normal temperature and pressure.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
flash pointaaaaaaaaaa
Login to view more

Abstract

High efficiency viscosity-reducing agent which is used on THE thermal oil extraction technology, which is formed by the following raw materials with percentage by weight, firstly phenyl benzene, fused ring aromatic hydrocarbon or fused ring aromatic hydrocarbon derivative which does not contain chlorine element and sulfur element, secondly liquid petroleum product whose aromatic hydrocarbons content is no more than 5%, petroleum resin which is liquid state under the constant temperature or hydrocarbons natural aggregation which is particle state under the constant temperature, thirdly water-soluble anionic surface active agent, water-soluble non-ionic surface active agent, oil solubility anionic surface active agent or oil solubility non-ionic surface active agent, fourthly fusel oil, fifthly alcohol ether, sixthly oil solubility or water-soluble polymer which respectively has nonpolar portion which has eutectic crystal with ceresin wax molecular and polar portion which can make wax crystal system twisty on main chain and or branch chain, seventhly hyperoxide, eighthly carbamide, ammonium carbonate, ammonium acid carbonate or ammonium nitrite and ninthly ketone. The high efficiency viscosity-reducing agent has strong suitability, strong viscosity-reducing ability, safety and reliability, can largely reduce extract cost and increase the yield of oil pump, and increases the final recovery efficiency of oil reservoir.

Description

technical field [0001] The invention relates to an auxiliary agent for oil extraction, in particular to a high-efficiency viscosity reducing agent used in thermal oil extraction technology. Background technique [0002] At present, the thermal oil recovery process is mainly used for the recovery of heavy oil and high pour point oil, and viscosity reducers are commonly used as auxiliary agents. The existing type of viscosity reducer is usually divided into two types: water-based viscosity reducer and oil-based viscosity reducer. Base viscosity reducers are further divided into oil-soluble viscosity reducers and organic solvent-based viscosity reducers, all of which have different defects. [0003] The water-soluble viscosity reducer is mainly composed of surfactant and water. It has the following defects in the thermal oil recovery process: First, it mainly uses the principle of emulsification to reduce viscosity, and cannot directly dissolve asphaltenes, colloids and wax cr...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Patents(China)
IPC IPC(8): C09K8/524
Inventor 李向东
Owner 盘锦河升大地石油科技有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products