Nanometer silver paste for terminal electrode of multi-layer ceramic capacitor and method for preparing same
A nano-silver paste, multi-layer ceramic technology, applied in the direction of fixed capacitor terminal, fixed capacitor parts, conductive materials dispersed in non-conductive inorganic materials, etc., can solve problems such as insufficient yield of finished products and reduce production. Cost, environmental protection, smooth surface effect
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[0028] The preparation method of the nano-silver paste according to the above-mentioned component ratio is as follows:
[0029] 1) Powder mixing: Mix silver powder with a particle size of 10-100nm and titanium boroaluminosilicate glass powder together, use absolute ethanol as a carrier, and mix for 3-10 hours with a ball mill or a ball grinder;
[0030] 2) Powder drying: Dry the mixed silver powder and titanium borosilicate glass powder at 40-80°C for 1-2 hours, then cool naturally to room temperature;
[0031] 3) Preparation of organic vehicle: Add polyacrylic acid resin to ethyl acetate or ethyl acetate, and dissolve polyacrylic acid resin completely at constant temperature in a water bath at 60-80°C, and then cool to room temperature. Among them, polyacrylic acid resin : The mass ratio of ethyl acetate or ethyl acetate is 40~70:30~60; polyacrylic resin is polymethyl acrylate, polyethyl acrylate, polymethyl methacrylate with molecular weight between 10000~15000 species or sev...
Embodiment 1
[0036] First weigh 60g of nano-silver powder with a particle size of 10-100nm, then weigh 4g of titanium borosilicate glass powder, then mix the weighed nano-silver powder and titanium borosilicate glass powder together, and use Use water and ethanol as a carrier, mix with a ball mill or a ball mill for 4 hours; dry the mixed nano-silver powder and titanium boroaluminosilicate glass powder at 60°C for 1.5 hours, and then cool at room temperature;
[0037] Weighed 65 g of polymethyl acrylate with a molecular weight of 12000 and added it to 35 g of ethyl acetate, completely dissolved the polyacrylic resin in a water bath at a constant temperature of 65° C., and then cooled to room temperature.
[0038] Weigh 30g of the aforementioned organic vehicle and 1g of dispersant DP270, 2.5g of antifoaming agent polysiloxane, 3.5g of surfactant Span-60 (Span-60) and add it to the silver powder and boroaluminosilicate titanium In the mixture of glass powder, fully stir with a planetary mix...
Embodiment 2
[0041] First weigh 45g of nano-silver powder with a particle size of 10-100nm, then weigh 10g of titanium borosilicate glass powder, then mix the weighed nano-silver powder and titanium borosilicate glass powder together, and use Use water and ethanol as a carrier, mix with a ball mill or a ball grinder for 4.5 hours; dry the mixed nano-silver powder and lead-free glass powder at 70°C for 1 to 3 hours, and then cool at room temperature;
[0042] Weigh 70g of poly(ethyl acrylate) with a molecular weight of 13,000 and add it to 60g of ethyl acetate, completely dissolve the poly(acrylic acid) resin in a water bath at a constant temperature of 65°C, and then cool to room temperature.
[0043] Weigh 40g of the above-mentioned organic vehicle and 1g of dispersant sodium dodecylsulfonate, 2g of antifoaming agent calcium carbonate, and 2g of surfactant di-tert-butylhydroxytoluene and add them to the aforementioned nano-silver powder and lead-free glass In the powder mixture, fully sti...
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