Abrasive material-free polishing fluid for chemical mechanical polishing of rigid fragile material

A non-abrasive polishing liquid and chemical mechanical technology, applied in the field of polishing liquid, can solve the problems of difficult cleaning of the polishing surface, single function of the polishing liquid, and poor versatility, and achieve the effects of small surface damage, low environmental requirements, and reduced processing costs

Inactive Publication Date: 2010-10-20
NANJING UNIV OF AERONAUTICS & ASTRONAUTICS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The object of the present invention is to aim at the existing hard and brittle material chemical mechanical polishing liquid because of adding abrasives, so scratches will be generated on the polishing surface during the chemical mechanical polishing process and it is not easy to clean after polishing. At the same time, the existing polishing liquid has a single function and is universal. Poor performance, it is necessary to prepare corresponding polishing liquid for different materials to be processed and other defects and deficiencies, to provide a kind of chemical mechanical polishing of hard and brittle materials with good versatility, no scratches on the processed surface, easy to clean, and low cost non-abrasive polishing fluid

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] A non-abrasive polishing liquid for chemical mechanical polishing of hard and brittle materials, which is composed of hydrofluoric acid (corrosion agent, and can also be used in a mixed solution of phosphoric acid, phosphate and pyrophosphate or oxalic acid, concentrated sulfuric acid, nitric acid, hydrochloric acid and acetic acid during specific implementation. One or more mixtures of the above) 6kg, ammonium fluoride (corrosion inhibitor, can also be replaced by ammonium chloride and / or ammonium bromide) 3kg, alkylphenol polyoxyethylene ether (surfactant One or more of polyoxyethylene alkylphenol, fatty acid polyoxyethylene ester, polyoxyethylene fatty acid ester, polyoxyethylene amide, polyoxyethylene amine and high-carbon fatty alcohol polyoxyethylene ether can also be used during specific implementation Combination instead) 1.5kg, tetramethylammonium hydroxide (PH value adjuster, can also be used in potassium hydroxide, sodium hydroxide, ammonia water, hydroxylamin...

Embodiment 2

[0029] A non-abrasive polishing liquid for chemical mechanical polishing of hard and brittle materials, which is composed of tripotassium phosphate (corrosion agent can also be used in hydrofluoric acid, oxalic acid, concentrated sulfuric acid, nitric acid, hydrochloric acid and acetic acid One or more mixed solutions Replacement) 2kg, potassium pyrophosphate (corrosion agent) 10kg, ammonium chloride (corrosion inhibitor, can also be replaced by ammonium fluoride and / or ammonium bromide) 0.5kg, alkylphenol polyoxyethylene ether (surfactant One or more of polyoxyethylene alkylphenol, fatty acid polyoxyethylene ester, polyoxyethylene fatty acid ester, polyoxyethylene amide, polyoxyethylene amine and high-carbon fatty alcohol polyoxyethylene ether can also be used during specific implementation Combination to replace) 1.5kg, potassium hydroxide (pH value adjuster, also available sodium hydroxide, ammoniacal liquor, hydroxylamine, tetramethylammonium hydroxide, triethanolamine, sod...

Embodiment 3

[0031]A non-abrasive polishing liquid for chemical mechanical polishing of hard and brittle materials, which is composed of hydrochloric acid (corrosion agent, a mixture of hydrofluoric acid, phosphoric acid, phosphate and pyrophosphate or one of oxalic acid, nitric acid and acetic acid) or multiple mixed solutions instead) 6kg, concentrated nitric acid (corrosion agent) 4kg, polyoxyethylene alkylphenol (surfactant, fatty acid polyoxyethylene ester, polyoxyethylene fatty acid ester, polyoxyethylene amide, One or a combination of polyoxyethylene amine, alkylphenol polyoxyethylene ether and high-carbon fatty alcohol polyoxyethylene ether) 3.5kg, ammonium chloride (corrosion inhibitor, fluorine can also be used in specific implementation ammonium chloride and / or ammonium bromide instead) 1.5kg, tetramethylammonium hydroxide (pH value regulator, potassium hydroxide, sodium hydroxide, ammonia, hydroxylamine, triethanolamine, sodium ethylate and acetic acid can also be used during sp...

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Abstract

The invention discloses abrasive material-free polishing fluid free for chemical mechanical polishing of a rigid fragile material. The polishing fluid is characterized by consisting of 0.5 to 40 percent of corrosive, 0.5 to 20 percent of corrosion inhibitor, 0.5 to 15 percent of surfactant, 0.1 to 10 percent of pH regulator and de-ionized water. The abrasive material-free polishing fluid has the advantages of no abrasive material, small damage to the surface of a polished material, capability of obtaining a non-damage super smooth surface, no precipitate, capability of being stored and used for a long time, high stability, difficult volatilization, high fluidity, easy cleaning and small corrosion to equipment. The abrasive material-free polishing fluid is prepared special for the chemical mechanical polishing of the rigid fragile material, so the abrasive material-free polishing fluid has the advantages of conventional abrasive material-free polishing fluid, has high removal ratio for the rigid fragile material, can obtain high surface quality and has low cost and a simple and easy method.

Description

technical field [0001] The invention relates to a polishing liquid used in the chemical mechanical polishing process, in particular to a non-abrasive polishing liquid for chemical mechanical polishing, in particular to a non-abrasive polishing liquid for chemical mechanical polishing of hard and brittle materials. Background technique [0002] Chemical mechanical polishing technology is widely used in precision ultra-precision machining of semiconductors, crystals, ceramics, glass, metals and other materials, and is currently the only practical technology that can achieve local and global planarization. However, the polishing liquid of traditional chemical mechanical polishing contains hard abrasive particles. During the polishing process, the hard particles in the polishing liquid are easy to scratch, embed or adsorb on the surface of the processed material to form processing defects, such as pits, scratches, and microcracks. , particle embedding or adsorption and other sur...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09G1/04
Inventor 李军朱永伟左敦稳张彦高平蒋毕亮杨涛周睿洋王军
Owner NANJING UNIV OF AERONAUTICS & ASTRONAUTICS
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