Preparation method of composite sol and method for producing solar battery packaging glass by using same

A technology for solar cells and encapsulation glass, which is applied in the preparation of composite sol and in the field of manufacturing encapsulation glass for solar cells, can solve the problems of poor film-forming properties, hardness, resistance to salt spray, complicated operation, and inability to achieve

Inactive Publication Date: 2010-12-01
DONGGUAN CSG SOLAR GLASS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The disadvantages of these existing coating materials are: (1) the low refractive index and good adhesion cannot be effectively combined, and an optimal effect cannot be achieved; (2) the coating materials prepared by the similar sol-gel method do not combine various oxides The materials are aggregated together and cannot form a strong three-dimensional network, so that ordinary nanoporous anti-reflective coatings will have strong water absorption, resulting in a significant decrease in light transmittance when placed outdoors for a long time
In addition, the method for preparing coating materials in the prior art is not only complicated to operate and has a long cycle, but also has poor film-forming performance, hardness performance and salt spray resistance. In addition, under long-term outdoor exposure, The adhesion, hardness, salt spray resistance and other indicators of the anti-reflection coating coated with the above coating solution will continue to decrease with the passage of time, and cannot withstand long-term harsh environments

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] A method for preparing a composite sol for solar cell encapsulation glass coated with an anti-reflection film of the present embodiment comprises the following steps:

[0038] Step 1: Mix silicon alkoxide, water, basic catalyst and alcoholic organic solvent according to the volume ratio of 1-100:0.1-10:0.01-1:3-300 to form mixed solution A. The silicon alkoxide is mixed under alkaline conditions according to the volume ratio of silicon alkoxide, water, basic catalyst and alcohol organic solvent respectively 1-100:0.1-10:0.01-1:3-300, and the formed The stability of mixed solution A is better.

[0039] Step 2, adjusting the pH value of the mixed solution A in step 1 to 8-10.

[0040] Step 3: Add an inhibitor and a dispersant to the mixed solution A after adjusting the pH value in Step 2, mix and stir at room temperature for 1h-10h, seal and leave to age for 1d-10d to obtain the first sol. Adding inhibitors and dispersants can control the reaction process, so that the p...

Embodiment 2

[0053] A method for preparing a composite sol for solar cell encapsulation glass coated with an anti-reflection film of the present embodiment comprises the following steps:

[0054] Step 1: Mix methyl orthosilicate, water, ammonia water and anhydrous methanol according to the volume ratio of 75-90:1.4-8.8:0.05-0.09:110-250 to form a mixed solution A. Firstly, methyl orthosilicate is used to prepare a sol with better stability under alkaline conditions to ensure its low refractive index.

[0055] Step 2, adjusting the pH value of the mixed solution A in step 1 to 8.5-9.5.

[0056] Step 3: Add polyvinyl alcohol and glycerol to the mixed solution A after adjusting the pH value in Step 2, mix and stir at room temperature for 5h-8h, seal and leave to age for 6d-8d to obtain the first sol.

[0057] Step 4, changing the reaction conditions, adding glacial acetic acid, acetylacetone and diethanolamine to the first sol obtained in Step 3 to form a mixed solution B.

[0058] Step fiv...

Embodiment 3

[0062] A method for preparing a composite sol for solar cell encapsulation glass coated with an anti-reflection film of the present embodiment comprises the following steps:

[0063] Step 1: Mix silicon alkoxide, water, triethanolamine and isopropanol according to the volume ratio of 20-75:0.2-1.4:0.02-0.07:3-110 to form a mixed solution A.

[0064] Step 2, adjusting the pH value of the mixed solution A in step 1 to 8.1-9.4.

[0065] Step 3: Add polyethylene glycol and CMC to the mixed solution A after pH adjustment in Step 2, mix and stir at room temperature for 2h-6h, seal and leave to age for 1d-3d to obtain the first sol.

[0066] Step 4, changing the reaction conditions, adding sulfuric acid, acetylacetone and diethanolamine to the first sol obtained in Step 3 to form a mixed solution B.

[0067] Step five, adjusting the pH value of the mixed solution B in step four to 3-4.

[0068] Step 6: Add a certain amount of zirconium oxychloride as a zirconium source to the mixed...

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Abstract

The invention relates to a preparation method of composite sol and a method for producing solar battery packaging glass by using the composite sol. The preparation method of composite sol comprises the following steps of: mixing silica-alkoxides, water, basic catalysts and alcohol organic solvents in the volume ratio of 1-100: 0.1-10: 0.01: 1:3-300 to obtain A; adjusting the pH of the A to 8-10; adding inhibitors and dispersing agents in the A and then ageing 1d-10d to obtain a first sol; adding acidic catalysts, the inhibitors and stabilizers in the first sol to form B; adjusting the pH of the B to 2-5; adding metal alkoxides or metal salts in the B and then ageing 5d-20d to obtain a second sol; dissolving the second sol, aqueous silane coupling agents and wetting flatting agents for coatings in mixed environmental-protection solvents and then stirring at least for 0.5h to prepare the compound sol. The preparation method of the composite sol has the advantages of simple process and low cost and can greatly reduce the cost of a coating material used in plating anti-reflection films, and the composite sol coating material basically has no water absorbency so that the prepared anti-reflection films keep higher light transmittance.

Description

technical field [0001] The invention relates to the technical field of solar photoelectric conversion glass manufacturing, in particular to a method for preparing a composite sol and a method for manufacturing solar cell encapsulation glass using the same. Background technique [0002] In the long-term energy strategy, solar photovoltaic power generation has a more important position in many renewable energy sources such as solar thermal power generation, wind power generation, ocean power generation, and biomass power generation. [0003] In the prior art, the solar photovoltaic power generation system is mainly composed of solar cell components, and the photoelectric conversion of solar energy in the solar cell components is generally realized through the absorption of the solar spectrum by silicon wafers. Taking crystalline silicon solar cell components as an example, the theoretical efficiency of solar energy is only about 30%, the current highest efficiency in the labor...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C17/00
Inventor 刘沐阳康正辉陈金桂
Owner DONGGUAN CSG SOLAR GLASS
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