Starch-based fully degraded packaging material and preparation method thereof
A packaging material and a fully degradable technology, applied in the field of starch-based fully degradable packaging materials and their preparation, can solve the problems of unsatisfactory starch-based degradable packaging performance, and achieve the effects of low price, low density and wide sources.
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[0064] The starch composition can also be modified by conventional methods (for example, a one-step method) to obtain the starch-based fully degradable packaging material of the present invention. But after many experiments, the present invention provides a preparation method as follows, mainly through the following steps:
[0065] A. Plasticization modification: ordinary starch undergoes modification reaction to prepare plasticization modified starch.
[0066] Put the plant starch, toughening polymer, compatibilizer, modification auxiliary, softener, and plasticizer into the mixer in sequence according to the formula ratio. At 1~6kg / cm 2 Stir for 15-60 minutes in a high-speed mixer at 3000 rpm under pressure and within a temperature gradient of 85-95°C. The plasticized modified starch component is obtained in a loose state.
[0067] In this step, various polymer modification, toughening, softening, compatibilization, and plasticizers are added to the starch, and reaction condition...
Embodiment 1
[0080] Prepare the raw materials with the following proportions:
[0081] Corn starch: 100 servings
[0082] Wood pulp fiber: 12 parts
[0083] EAA: 7 copies
[0084] Titanate coupling agent: 1 part
[0085] Soy Lecithin: 4 servings
[0086] Dioctyl maleate: 2 parts
[0087] Polyethylene glycol 200 15 parts
[0088] Hydroxypropyl methylcellulose 0.5 parts
[0089] Light calcium carbonate: 4 servings
[0090] Rosin glyceride: 1~3 parts
[0091] Chitosan: 0.3 parts
[0092] 0.1 part of sodium dehydroacetate
[0093] Water: 160 parts
[0094] A: Plasticization modification
[0095] Put the above components corn starch, EAA, titanate coupling agent, dioctyl maleate, soybean lecithin, and polyvinyl alcohol 200 into the mixer in sequence according to the formula ratio. Stir in a high-speed mixer at 3000 rpm for 40 minutes under a pressure of 4 kg / cm2 and a temperature gradient of 85-95°C. The plasticized modified starch component is obtained in a loose state.
[0096] B: Homogeneous mixing:
[0097] Co...
Embodiment 2
[0101] Tapioca starch: 100 servings
[0102] Bamboo pulp fiber: 20 parts
[0103] 10 parts of EVOH
[0104] Silicone coupling agent: 2 parts
[0105] Maleic anhydride: 1.5 parts
[0106] Calcium stearoyl lactate: 10 parts
[0107] Glycerin: 18 parts
[0108] Polyvinylpyrrolidone: 0.2
[0109] Sodium Alginate: 0.8 parts
[0110] Nano calcium carbonate: 6 parts
[0111] Liquid paraffin: 3 parts
[0112] Cinnamaldehyde: 0.1 part
[0113] Sodium benzoate 0.5 part
[0114] Water: 210 parts
[0115] A: Modified ordinary starch to plasticized modified starch
[0116] Put tapioca starch, EVOH, maleic anhydride, silicone coupling agent, and glycerin into the blender in sequence according to the formula ratio. Stir in a high-speed mixer at 3000 rpm for 30 minutes under a pressure of 6 kg / cm2 and a temperature gradient of 80-90°C. The plasticized modified starch component is obtained in a loose state.
[0117] B: Combine the plasticized modified starch component with bamboo pulp fiber, sodium alginate, pol...
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