Method for preparing titanium dioxide-zinc oxide nuclear shell structure nanometer fiber membrane for dye sensitized battery

A technology of dye-sensitized cells and nanofiber membranes, applied in photosensitive equipment, circuits, photovoltaic power generation, etc., to achieve the effects of improving conversion efficiency, increasing collection efficiency, and improving performance

Inactive Publication Date: 2012-06-13
ZHEJIANG SCI-TECH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Accordingly, it is expected that with the help of coaxial electrospinning and sintering, the formation of TiO 2 As ...

Method used

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  • Method for preparing titanium dioxide-zinc oxide nuclear shell structure nanometer fiber membrane for dye sensitized battery
  • Method for preparing titanium dioxide-zinc oxide nuclear shell structure nanometer fiber membrane for dye sensitized battery
  • Method for preparing titanium dioxide-zinc oxide nuclear shell structure nanometer fiber membrane for dye sensitized battery

Examples

Experimental program
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Effect test

Embodiment 1

[0024] 0.68g polymer PVAc was added to 4ml DMF organic solvent to form a solution with a mass percentage of 15wt.%, and 1ml Triton X-100, 1.36g TiP, and 0.68g C 4 h 6 o 4 Zn·2H 2 O, clear and viscous TiO was obtained by magnetic stirring for 8 h 2 / ZnO composite precursor spin-coating solution; and use a spin-coating instrument to spin-coat it on the FTO conductive glass cleaned ultrasonically by acetone and absolute ethanol to form a layer of spin-coating, the spin-coating instrument speed is 2000r min -1 , the spin coating time used is 30s.

[0025] 0.52g PVAc was added to 4ml DMF to form a solution with a mass percentage of 11.5wt.%. The same solution was prepared in two parts, i.e. solution I and solution II; in solution I was added 0.6ml Triton X-100 and 0.52g C 4 h 6 o 4 Zn·2H 2 O, magnetic stirring for 8h to obtain the precursor spinning solution 1 of ZnO. Add 0.6ml Triton X-100, 0.4ml HAc, and 1.04g TiP to solution II, and stir magnetically for 8 hours to ob...

Embodiment 2

[0028] 0.68g polymer PVAc was added to 4ml DMF organic solvent to form a solution with a mass percentage of 15wt.%, and 1ml Triton X-100, 1.36g TiP, and 0.68g C 4 h 6 o 4 Zn·2H 2 O, clear and viscous TiO was obtained by magnetic stirring for 8 h 2 / ZnO composite precursor spin-coating solution; and use a spin-coating instrument to spin-coat it on the FTO conductive glass cleaned ultrasonically by acetone and absolute ethanol to form a layer of spin-coating, the spin-coating instrument speed is 2000r min -1 , the spin coating time used is 30s.

[0029] 0.52g PVAc was added to 4ml DMF to form a solution with a mass percentage of 11.5wt.%. The same solution was prepared in two parts, i.e. solution I and solution II; in solution I was added 0.6ml Triton X-100 and 0.52g C 4 h 6 o 4 Zn·2H 2 O, magnetic stirring for 8h to obtain the precursor spinning solution 1 of ZnO. Add 0.6ml Triton X-100, 0.4ml HAc, and 1.04g TiP to solution II, and stir magnetically for 8 hours to ob...

Embodiment 3

[0032] 0.68g polymer PVAc was added to 4ml DMF organic solvent to form a solution with a mass percentage of 15wt.%, and 1ml Triton X-100, 1.36g TiP, and 0.68g C 4 h 6 o 4 Zn·2H 2 O, clear and viscous TiO was obtained by magnetic stirring for 8 h 2 / ZnO composite precursor spin-coating solution; and use a spin-coating instrument to spin-coat it on the FTO conductive glass cleaned ultrasonically by acetone and absolute ethanol to form a layer of spin-coating, the spin-coating instrument speed is 2000r min -1 , the spin coating time used is 30s.

[0033] 0.52g PVAc was added to 4ml DMF to form a solution with a mass percentage of 11.5wt.%. The same solution was prepared in two parts, i.e. solution I and solution II; in solution I was added 0.6 ml Triton X-100 and 0.52g C 4 h 6 o 4 Zn·2H 2 O, magnetic stirring for 8h to obtain the precursor spinning solution 1 of ZnO. Add 0.6ml Triton X-100, 0.4ml HAc, and 1.04g TiP to solution II, and stir magnetically for 8 hours to o...

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Abstract

The invention discloses a method for preparing a titanium dioxide-zinc oxide nuclear shell structure nanometer fiber membrane, which is characterized in that: a light anodized membrane is a core part of a dye sensitized solar battery, physical and chemical decoration such as surface coverage is undertaken on the light anodic membrane, and development of a novel nanometer structure light anodic membrane is an important way for improving the property of the dye sensitized solar battery. A unique coaxial electrostatic spinning technique is adopted to prepare the titanium dioxide (TiO2)/zinc oxide (ZnO) nuclear shell structure nanometer membrane for a dye sensitized solar battery light anode. Due to the adoption of the technique, the formation of a standard quasi one-dimensional nanometer structure and the shell wrapping treatment for preventing the recombination of electric charges can be simultaneously realized. Crystal boundaries of the quasi one-dimensional nanometer structure is fewer, so the electronic recombination can be reduced, and short-circuit current Isc of the battery can be improved. By introducing a shell, an open-circuit voltage Voc of the battery can be increased. Correspondently, overall transformation efficiency Eta of the battery can be improved by 18 percent to 27 percent.

Description

technical field [0001] The invention relates to the technical field of solar cell manufacturing, in particular to a method for preparing a titanium dioxide-zinc oxide core-shell nanofiber film for a dye-sensitized cell. Background technique [0002] With the continuous development of society and economy, the depletion of non-renewable energy sources such as oil and coal, the survival and development of human beings are facing unprecedented challenges. Finding clean, renewable energy has become a global issue. It is estimated that the energy that the earth obtains from solar radiation every year is about 100,000 times the annual energy consumption of human beings. Therefore, the development and utilization of solar energy is a major issue in the field of new energy. Solar cells based on the pn junction principle of semiconductor silicon are currently the most mature photoelectric conversion devices. In recent years, the pace of large-scale application of silicon solar cells ...

Claims

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Application Information

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IPC IPC(8): H01G9/04H01G9/20H01M14/00H01L51/48
CPCY02E10/542Y02E10/549
Inventor 杜平凡熊杰宋立新席珍强
Owner ZHEJIANG SCI-TECH UNIV
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