Emulsion polymerization reaction method
An emulsion polymerization and reaction technology, applied in the direction of ester copolymer adhesives, adhesive types, etc., can solve the inherent quality (dry resistance, water washability cannot be guaranteed, poor water washability and cold resistance, product dispersion, Poor stability and other problems, to achieve the effect of improving self-crosslinking performance, soft hand feel, and improved water resistance
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preparation example Construction
[0016] A method for preparing self-crosslinking water-based polyacrylate powder-free base paste for clothing adhesive lining, comprising the following steps: first, mixing water-based polyacrylate emulsion, auxiliary agents and deionized water, wherein the water-based polyacrylate Acrylate emulsion is prepared by pre-emulsion, seed emulsion, sub-emulsion, 10% adipic hydrazide aqueous solution and ammonia water. The pre-emulsion is composed of methyl methacrylate, butyl acrylate, acrylic acid, diacetone acrylamide , sodium alkylamide ethylene sulfonate, fatty alcohol polyoxyethylene ether and deionized water. The seed emulsion is prepared from a composite initiator and a polymerization bottom material. Oxyethylene ether and deionized water are prepared, the composite initiator is prepared from ammonium persulfate, sodium dodecylbenzenesulfonate and deionized water, and the secondary emulsion is composed of monomers and emulsifiers, The monomer is composed of methyl methacrylate...
preparation example 1
[0077] The present invention adopts the semi-continuous emulsion polymerization process and seed emulsion polymerization method of pre-emulsified monomers to carry out conventional emulsion polymerization and core-shell emulsion polymerization respectively on the same formula, and designs the composition of the core-shell to synthesize a series of polymer emulsions. The formulation composition is shown in Table 1.
[0078] Table 1 Different polymerization methods and formulation composition
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[0081] Table 2 shows the stability and emulsion properties of different polymerization methods.
[0082] Table 2 Stability and emulsion properties of different polymerization methods
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Embodiment 1
[0085] Take the PRA-2 sample emulsion in Preparation Example 1 and cool it down to room temperature, slowly add 10% adipic hydrazide (ADH) aqueous solution, and neutralize it with ammonia water until the pH value is 7-8. Filtration, discharge, to obtain a milky white emulsion in blue light, which is the product of the present invention—a main emulsion of self-crosslinking type water-based polyacrylate powder-free base slurry for clothing adhesive interlining.
[0086]The basic formula of the powder-free base slurry includes, in addition to the medium water, the main emulsion of the base, a pH regulator, a thickener, a tackifier, a whitening agent, a preservative, and a defoamer. Calculate the amount of deionized water and main emulsion according to the preset plan, adjust the pH value of the system to neutral with ammonia water, and then add the corresponding water-based additives to adjust the viscosity [viscosity <30000 (mPa·s / 20°C)] After that, the product of the present in...
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