A polyamide nanofiltration membrane containing sulfobetaine-type colloidal nanoparticles and preparation method thereof
A sulfobetaine and nanoparticle technology, applied in chemical instruments and methods, membrane technology, semi-permeable membrane separation, etc., can solve the problems of membrane defects, insignificant modification effect, and easy membrane aggregation, and achieve excellent membrane performance. , good industrial practicability, the effect of improving transmission efficiency
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[0016] The polyamide nanofiltration membrane preparation method containing sulfobetaine type colloidal nanoparticles comprises the following steps:
[0017] (1) Using sulfobetaine group-containing olefin monomers and hydroxyalkyl acrylate monomers as functional monomers, prepare an aqueous solution, add a water-soluble oxidation-reduction initiator, and use soap-free emulsion polymerization to prepare sulfonate Acid betaine type colloidal nanoparticles;
[0018] (2) Uniformly disperse polyamine monomers and sulfobetaine-type colloidal nanoparticles in water, add sodium hydroxide as an acid absorbent, and prepare an aqueous phase solution; dissolve polyacyl chloride monomers in an organic solvent, and prepare organic phase solution;
[0019] (3) Immerse the porous polysulfone support membrane in the aqueous phase solution for 2 to 5 minutes, take out and remove the excess aqueous phase solution on the surface; then immerse in the organic phase solution for 0.5 to 3 minutes, ta...
Embodiment 1
[0029] Take 10g of 3-[N,N-dimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]ammonium]propane-1-sulfonic acid inner salt and 2g of hydroxyethyl acrylate and add In 100ml of water, nitrogen gas was introduced, and potassium persulfate and sodium bisulfite (mass ratio 1:1) with a concentration of 1 wt% were added, at 30 o Soap-free emulsion polymerization was carried out at C for 5 hours, after several times of centrifugation, water washing, and vacuum drying, the sulfobetaine-type colloidal nanoparticles were obtained; the porous polysulfone support membrane was immersed in the aqueous phase solution for 2 minutes, and the aqueous phase solution was The concentration of piperazine is 0.2 wt%, the concentration of sulfobetaine-type colloidal nanoparticles is 0.05 wt%, and the concentration of NaOH is 0.01 wt%, take out and remove the excess aqueous phase solution on the surface; then immerse to a concentration of 0.1 wt% In the n-hexane solution of trimesoyl chloride, the interfacial po...
Embodiment 2
[0032] Take 30g of 3-[N,N-dimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]ammonium]propane-1-sulfonic acid inner salt and 10g of hydroxyethyl acrylate and add In 100ml of water, nitrogen gas was introduced, and potassium persulfate and sodium bisulfite (mass ratio 1:1) were added with a concentration of 3 wt%, at 45 o Soap-free emulsion polymerization was carried out at C for 1 hour, after repeated centrifugation, water washing, and vacuum drying, sulfobetaine-type colloidal nanoparticles were obtained; the porous polysulfone support membrane was immersed in the aqueous phase solution for 5 minutes, and in the aqueous phase solution The concentration of piperazine is 2 wt%, the concentration of sulfobetaine type colloidal nanoparticles is 0.5 wt%, the concentration of NaOH is 0.5 wt%, take out and remove the excess aqueous phase solution on the surface; In the n-hexane solution of trimesoyl chloride, the interfacial polymerization reaction was carried out for 3 minutes at 70 o C f...
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