Coal dust depressor and preparation method thereof

A dust suppressant, coal technology, applied in chemical instruments and methods, other chemical processes, etc., can solve the problems of easy mold cost, complex synthesis process, corrosion and other problems, and achieve good water retention performance and high chemical stability , the effect of high cellulose content

Active Publication Date: 2015-04-29
XIAN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

It is not difficult to see that most of the existing dust suppressant formulas are relatively single, and the raw materials are basically concentrated in starch (although the degradation performance is good, but the product is prone to mildew and the cost is high), chloride inorganic salt (has a negative effect on the dust suppressant spraying equipment). Corrosion), synthetic water-soluble polymers (the synthesis process is complicated and difficult to control), although natural plant fibers are used to replace the synthetic water-soluble polymers in individual formulations, the preparation process still uses the simple emulsion synthesis method, synthetic After a long time, the film-forming strength of the product is generally not high
Moreover, the performance design and development of existing products mostly stay in the two aspects of water absorption and water retention, and the overall degree of functional design and development is insufficient
[0007] On the other hand, although some of the existing coal dust suppressants have good experimental results, most of them have not been popularized and applied. The main reason is that the coal dust is generated in a large amount, involving a wide range of coal types, and the research and development work is rarely fully integrated. The microscopic properties of the coal dust surface, and the lack of systematic analysis of the molecular structure of the agent, generally rely on a large number of experiments, and the blindness of research and development is obvious, resulting in prolonged product development cycles, increased costs, and unstable product performance.

Method used

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  • Coal dust depressor and preparation method thereof

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] The coal dust suppressant of this embodiment is made of the following raw materials in parts by weight: 1 kg of modified sunflower stalks, 20 kg of acrylic acid solution with a neutralization degree of 70%, 0.01 kg of ethylene glycol dimethacrylate, and 0.6 kg of purified diatomaceous earth. kg, initiator 0.04kg; the initiator is potassium persulfate; the modified sunflower stalk is the sunflower stalk after alkalization; the preparation method of the acrylic acid solution with a neutralization degree of 70% is as follows: The sodium hydroxide solution with a concentration of 21% was added to the acrylic acid, stirred evenly to make it completely neutralized, and the molar ratio of the acrylic acid to the sodium hydroxide in the sodium hydroxide solution was 1:0.7.

[0031] The preparation method of the modified sunflower stalks is as follows: crush the sunflower stalks and pass through an 80-mesh sieve, take the undersieve and place them in a sodium hydroxide solution w...

Embodiment 2

[0040] The coal dust suppressant of this embodiment is made of the following raw materials in parts by weight: 1 jin of modified sunflower stalks, 22 jin of acrylic acid with a neutralization degree of 70%, 0.008 jin of ethylene glycol dimethacrylate, purified diatomaceous earth 0.8 jin, 0.04 jin of initiator; the initiator is hydrogen peroxide; the modified sunflower stalk is the sunflower stalk after alkalization treatment; the preparation method of the acrylic acid solution with a neutralization degree of 70% is as follows: Sodium hydroxide solution with a mass concentration of 21% was added to acrylic acid, stirred evenly to completely neutralize, and the molar ratio of the acrylic acid to sodium hydroxide in the sodium hydroxide solution was 1:0.7.

[0041] The preparation method of the modified sunflower stalks is as follows: crush the sunflower stalks and pass through a 100-mesh sieve, take the undersieve and place them in a sodium hydroxide solution with a mass concentr...

Embodiment 3

[0050] The coal dust suppressant of this embodiment is made of the following raw materials in parts by weight: 1 kg of modified sunflower stalks, 18 kg of acrylic acid solution with a neutralization degree of 70%, 0.012 kg of ethylene glycol dimethacrylate, and 0.4 kg of purified diatomaceous earth. kg, initiator 0.03kg; the initiator is potassium persulfate; the modified sunflower stalks are alkalized sunflower stalks; the preparation method of the acrylic acid solution with a neutralization degree of 70% is as follows: The sodium hydroxide solution with a concentration of 21% was added to the acrylic acid, stirred evenly to make it completely neutralized, and the molar ratio of the acrylic acid to the sodium hydroxide in the sodium hydroxide solution was 1:0.7.

[0051] The preparation method of the modified sunflower stalks is as follows: crush the sunflower stalks and pass through a 120-mesh sieve, take the undersieve and place them in a sodium hydroxide solution with a mas...

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Abstract

The invention discloses a coal dust depressor which is prepared from the following raw materials in parts by weight: 1 part of modified sunflower straw, 14-32 parts of acrylic acid solution with the neutralization degree of 50-70%, 0.0048-0.0176 part of ethylene glycol dimethyl acrylate, 0.2-0.8 part of purified kieselguhr and 0.02-0.04 part of initiator. Besides, the invention also discloses a preparation method of the coal dust depressor. The purified kieselguhr containing abundant internal micropores is used as a nucleating agent, the water-soluble molecular acrylic acid is used as the polymerizable monomer, the modified sunflower straw with high cellulose content is used instead of the starch used in the traditional method for preparing the dust depressor, microwave radiation is used for accelerating the decomposition of the initiator, and the acrylic acid and cellulose are subjected to in-situ graft copolymerization on the nuclear surface formed by the kieselguhr particles to form the shell-core coated-structure copolymer, thereby preparing the coal dust depressor with favorable absorptivity, water retention property and film-forming property.

Description

technical field [0001] The invention belongs to the technical field of coal industry, and in particular relates to a coal dust suppressant and a preparation method thereof. Background technique [0002] Coal is an important basic energy in my country. The basic characteristics of China's energy resources are rich in coal, poor in oil, and low in gas. Comparing my country's coal resources with primary energy resources such as oil, natural gas, hydropower, and nuclear energy, the proven resource reserves are converted into It is standard coal, and coal accounts for more than 85%. The existing resource structure has caused the absolute proportion of coal in my country's primary energy consumption structure to reach 70%. Therefore, my country's energy production and consumption are still dominated by coal. [0003] However, as an inevitable product in the process of coal production and processing, coal dust seriously threatens the safety of coal mining, crushing and storage, incr...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K3/22C08F289/00C08F220/06
Inventor 杨伏生林敏群杨志远周安宁
Owner XIAN UNIV OF SCI & TECH
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