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Fracture-resistant refractory material and preparation process thereof

A refractory material and a preparation process technology, applied in the field of refractory materials, can solve the problems of poor mechanical toughness, reduce the service life of the refractory material, affect the thermal shock resistance, etc., and achieve a simple preparation method, easy production, and excellent thermal shock resistance. Effect

Active Publication Date: 2017-01-11
CHANGXING MENGYOU REFRACTORIES
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The poor mechanical toughness of inorganic non-metallic materials is a common problem in inorganic non-metallic materials and materials. As refractory materials that belong to inorganic non-metallic materials, their mechanical toughness is also poor. However, its poor mechanical toughness also affects its thermal shock resistance at high temperatures. Due to the large temperature difference between rapid cooling and rapid heating and use, refractory materials are prone to cracking and peeling under the action of thermal expansion and contraction. The situation that affects the integrity of refractory materials reduces the service life of refractory materials; at the same time, for those refractory products that need to be moved frequently, their poor mechanical toughness will greatly increase the damage rate of refractory products and affect their daily use.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] A fracture-resistant refractory material, comprising the following raw materials in parts by weight: 100 parts of alumina-silicon oxide mixed powder, 8 parts of calcium oxide, 6 parts of magnesium oxide, 2 parts of manganese oxide, 3 parts of titanium oxide, and 1 part of niobium pentoxide part, 10 parts of toughening fiber; in the alumina-silica mixed powder, the silica is 30mol%, and the alumina is 70mol%;

[0030] Wherein, the toughening fiber is a modified zirconia fiber, which is obtained through the following steps: 50 parts by weight of zirconia, after adding 3 parts by weight of calcium oxide and 1 part by weight of sodium oxide, and 400 parts by molar ratio of 1:1 The sodium chloride and potassium chloride compound salts were mixed and ground for 12 hours with absolute ethanol as the grinding medium, dried and calcined at 850°C for 6 hours, after calcined and cooled, ground, cleaned and dried.

[0031] A preparation process for a fracture-resistant refractory m...

Embodiment 2

[0036] A fracture-resistant refractory material, comprising the following raw materials in parts by weight: 100 parts of alumina-silicon oxide mixed powder, 9 parts of calcium oxide, 7 parts of magnesium oxide, 2.5 parts of manganese oxide, 3.5 parts of titanium oxide, and 1.5 parts of niobium pentoxide part, 12 parts of toughening fiber; in the alumina-silica mixed powder, the silica is 33mol%, and the alumina is 67mol%;

[0037] Wherein, the toughening fiber is a modified zirconia fiber, which is obtained through the following steps: 50 parts by weight of zirconia, after adding 3 parts by weight of calcium oxide and 1 part by weight of sodium oxide, and 400 parts by molar ratio of 1:1 The sodium chloride and potassium chloride compound salts were mixed and ground for 12 hours with absolute ethanol as the grinding medium, dried and calcined at 850°C for 6 hours, after calcined and cooled, ground, cleaned and dried.

[0038] A preparation process for a fracture-resistant refra...

Embodiment 3

[0043] A fracture-resistant refractory material, comprising the following raw materials in parts by weight: 100 parts of alumina-silicon oxide mixed powder, 10 parts of calcium oxide, 8 parts of magnesium oxide, 3 parts of manganese oxide, 4 parts of titanium oxide, and 2 parts of niobium pentoxide part, 15 parts of toughening fiber; in the alumina-silica mixed powder, the silica is 35mol%, and the alumina is 65mol%;

[0044] Wherein, the toughening fiber is a modified zirconia fiber, which is obtained through the following steps: 50 parts by weight of zirconia, after adding 3 parts by weight of calcium oxide and 1 part by weight of sodium oxide, and 400 parts by molar ratio of 1:1 The sodium chloride and potassium chloride compound salts were mixed and ground for 12 hours with absolute ethanol as the grinding medium, dried and calcined at 850°C for 6 hours, after calcined and cooled, ground, cleaned and dried.

[0045] A preparation process for a fracture-resistant refractory m...

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Abstract

The invention discloses a fracture-resistant refractory material and a preparation process thereof. The refractory material is prepared from the raw materials, such as aluminum oxide-silicon oxide mixed powder, calcium oxide, magnesium oxide, manganese oxide, titanium oxide, niobium pentoxide, toughened fiber and the like, by the following steps: mixing the raw materials, ball-milling the raw material mixture in absolute ethanol, drying the raw material powder and performing dry pressing on the dry raw material powder to obtain a refractor material green body; sintering the refractor material green body, and naturally cooling to room temperature after sintering to obtain the fracture-resistant refractory material. The refractory material prepared by the preparation process has high mechanical toughness, high fracture resistance and excellent thermal shock resistance; the refractory material is simple in preparation method and is easily produced by the conventional equipment.

Description

technical field [0001] The invention relates to the technical field of refractory materials, in particular to a fracture-resistant refractory material and a preparation process thereof. Background technique [0002] In the traditional sense, refractory materials refer to inorganic non-metallic materials with a refractoriness of not less than 1580 °C. And parts of the material, and can withstand the corresponding physical and chemical changes and mechanical action. [0003] Most refractory materials are made of natural ores (such as refractory clay, silica, magnesite, dolomite), and some industrial raw materials and synthetic raw materials (such as industrial alumina, silicon carbide, synthetic mullite, Synthetic spinel, etc.) are also increasing, so there are many types of refractory materials. According to the mineral composition, refractories can be divided into silica, aluminum silicate, magnesia, dolomite, olivine, spinel, carbonaceous, zirconium-containing refractorie...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/66C04B35/185C04B35/622
CPCC04B35/185C04B35/6225C04B35/66C04B2235/3206C04B2235/3208C04B2235/3232C04B2235/3251C04B2235/3262C04B2235/96
Inventor 佘玉明
Owner CHANGXING MENGYOU REFRACTORIES
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