Manufacturing method of antibacterial ceramic tiles

A manufacturing method and technology for ceramic tiles, applied in the field of architectural ceramics, can solve the problems of incomplete pattern, waste of antibacterial agent, reduced wear resistance of glaze layer, etc., so as to improve structural strength and microporosity, enhance antibacterial effect, and improve antibacterial effect. The effect of grinding performance

Active Publication Date: 2017-01-25
淄博新博陶瓷科技有限公司
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  • Summary
  • Abstract
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  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] With the improvement of people's living standards, antibacterial tiles have gradually become an emerging technology and have been widely concerned: this type of function is required in indoor environments, especially in hospitals, schools and shopping malls with large traffic and closed spaces. Higher, by adding a photocatalyst to the glaze, the tiles will have a sterilizing effect under ultraviolet light, but the antibacterial effect in natural light or indoor lighting environment is not yet able to achieve the desired effect. Metal ions are directly added to the glaze or carried by a carrier. The antibacterial ceramic tiles obtained after firing mainly use silver, copper and zinc plasma to achieve the bactericidal effect, but these ions are easy to volatilize when fired at high temperature. Not resistant to high temperature, which greatly reduces the antibacterial performance of ceramic tiles; in some technologies, rare earth elements are added to the glaze to activate the antibacterial performance of nanocomposite high temperature resistant materials. Specifically, layered clay is used to adsorb strontium ions and rare earth ions to Between the clay crystal layers, the antibacterial effect activated by rare earth ions is realized, which successfully improves the heat resistance of the antibacterial particles; but this technology using clay reduces the wear resistance of the glaze layer, making the tiles durable in long-term use. In the end, not only the glaze layer is worn and the pattern is incomplete, which affects the appearance, but also because the antibacterial agent can only work on the surface of the glaze layer, and the thickness of the glaze layer will cause waste of antibacterial agent, so the thin layer is not wear-resistant. The glaze layer, resulting in a very short time for the tile to really have antibacterial effect; the antibacterial effect of the tile is also consumed with the wear of the glaze layer
The addition of conventional anti-wear materials returns to the dense structure of the glaze layer, resulting in the antibacterial particles being completely sealed and unable to contact with bacteria, and the antibacterial effect cannot be displayed

Method used

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  • Manufacturing method of antibacterial ceramic tiles

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] The preparation steps include: selection of body raw materials - ball milling pulping - spray drying powder making - pressing molding - dry material green body - glaze formation - bottom glaze - surface glaze - inkjet printing - printing protection glaze - kiln firing - finished product;

[0019] Mix the weighed kaolin, quartz and feldspar according to the ratio of 48:32:18 by mass percentage, put them into a ball mill for wet ball milling for 30 hours, spray granulate and age for 20 hours to obtain green body pellets; The granules are put into the mold, and the green tiles are obtained after pressing and forming under the pressure of 200MPa;

[0020] The glaze slurry of bottom glaze and top glaze is poured successively;

[0021] The inkjet printer sprays ink on the glaze of the tile surface according to the pre-selected pattern;

[0022] 12 parts of air knife soil, 12 parts of superfine calcium carbonate with a particle size of 0.02μm~0.06μm, 5 parts of barium carbon...

Embodiment 2

[0025] The preparation steps include: selection of body raw materials - ball milling pulping - spray drying powder making - pressing molding - dry material green body - glaze formation - bottom glaze - surface glaze - inkjet printing - printing protection glaze - kiln firing - finished product;

[0026] Mix the weighed kaolin, quartz and feldspar according to the ratio of 48:32:18 by mass percentage, put them into a ball mill for wet ball milling for 36 hours, spray granulate and age for 24 hours to obtain green body pellets; The granules are put into the mold, and the green tiles are obtained after compression molding under the pressure of 200MPa;

[0027] The glaze slurry of bottom glaze and top glaze is poured successively;

[0028] The inkjet printer sprays ink on the glaze of the tile surface according to the pre-selected pattern;

[0029] 11.5 parts of air knife soil, 12.5 parts of superfine calcium carbonate with a particle size of 0.02 μm ~ 0.06 μm, 4.7 parts of bari...

Embodiment 3

[0032] The preparation steps include: selection of green body raw materials - ball milling pulping - spray drying powder - pressing molding - dry material green body - glaze forming - bottom glaze - top glaze - inkjet printing - printing protection glaze - kiln firing - finished product;

[0033] The weighed kaolin, quartz and feldspar were mixed in a ratio of 48:32:18 by mass, and then put into a ball mill for wet ball milling for 36 hours, and after spray granulation and aging for 24 hours, green body pellets were obtained; The pellets are put into the mold, and the green ceramic tile is obtained after pressing and molding under the pressure of 200MPa;

[0034] Pour the glaze slurry of the bottom glaze and the top glaze successively;

[0035] The inkjet printer is applied to the tile surface glaze according to the preselected pattern;

[0036] 12.5 parts of air knife soil, 11.5 parts of calcium carbonate, 5.2 parts of barium carbonate, 4.7 parts of calcined bone, 31 parts ...

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Abstract

The invention provides a manufacturing method of antibacterial ceramic tiles, and belongs to the technical field of architectural ceramics. The manufacturing method of the antibacterial ceramic tiles is characterized by comprising the following steps: printing protective glaze after inkjet printing, wherein the protective glaze comprises the following raw materials in parts by weight: 11-13 parts of Qidao clay, 11-13 parts of calcium carbonate, 4.5-5.5 parts of barium carbonate, 4.5-5.5 parts of burnt bone stone, 28.5-32.5 parts of potassium feldspar, 14-16 parts of glaze frits, 1.7-2.3 parts of zirconium silicate, 15-18 parts of albite, 1.7-2.3 parts of zinc oxide and 7-9 parts of an antibacterial agent; and in the firing step, increasing the temperature of a kiln to 835-840 DEG C, insulating for 1.5-2.5 hours, then heating to the temperature of 1,200-1,210 DEG C, insulating for 3-4 hours, and then cooling. The protective glaze is suitable for the antibacterial agent to efficiently play effects for a long time, and by a ceramic tile firing mode for the glaze, the wear-resistant and long-acting antibacterial ceramic tile can be obtained.

Description

technical field [0001] A method for manufacturing antibacterial tiles belongs to the technical field of building ceramics. Background technique [0002] Floor tiles and wall tiles for architectural decoration have been widely used for a long time. Compared with other floor decoration materials, ceramic tiles have obvious advantages in terms of decorative effect and sanitation. After the inkjet printing technology is widely used in tile production, the decorative patterns, textures and colors of tiles are more realistic and vivid, which greatly satisfies consumers' pursuit of decorative effects. [0003] With the improvement of people's living standards, antibacterial tiles have gradually become an emerging technology and have been widely concerned: this type of function is required in indoor environments, especially in hospitals, schools and shopping malls with large traffic and closed spaces. Higher, by adding a photocatalyst to the glaze, the tiles will have a sterilizing...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B41/89C03C8/04
CPCC03C8/04C04B41/52C04B41/89C04B2235/96C04B41/504C04B41/5022
Inventor 高名胜高名忠
Owner 淄博新博陶瓷科技有限公司
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