Metal-free hydrogenation catalyst and application

A hydrogenation catalyst, metal-free technology, applied in the direction of physical/chemical process catalyst, cyanide reaction preparation, organic chemistry, etc., can solve the problems of high equipment requirements, flammable air, expensive price, etc., to simplify the production process, catalyze High activity and cost reduction effect

Inactive Publication Date: 2017-06-09
BEIJING UNIV OF CHEM TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, precious metal catalysts have few reserves, are expensive, and have high production costs; although Raney nickel catalysts are relatively cheap, they are easily deactivated and are flammable when exposed to air after hydrogenation, requiring high equipment requirements.
It can be seen that the catalyst has become a bottleneck restricting the further development of catalytic hydrogenation to prepare aromatic amines.

Method used

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  • Metal-free hydrogenation catalyst and application
  • Metal-free hydrogenation catalyst and application
  • Metal-free hydrogenation catalyst and application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] A metal-free hydrogenation catalyst, prepared by chemical vapor deposition, pyrolyzes iron phthalocyanine (FePc) on a quartz glass sheet at 800-1100°C, and feeds a mixed gas of argon and hydrogen into a quartz reaction tube. The obtained carbon tube is acid-washed to remove the residual iron catalyst to obtain the metal-free hydrogenation catalyst nitrogen-doped carbon nanotube. X-ray photoelectron spectroscopy (XPS, see appendix figure 1 ) and thermogravimetric analysis (TG, see attached figure 2 ) and other means, it can be seen that iron has been completely removed in the resulting catalyst.

[0028] The nitrogen-doped carbon nanotubes obtained above are used for liquid-phase hydrogenation reduction to prepare p-aminophenol, using p-nitrophenol solution as a raw material, reacting at room temperature, and using excess sodium borohydride solution as a hydrogen source and reducing agent. First, sodium borohydride solution is added to the nitrophenol solution. It can...

Embodiment 2

[0030] The catalyst used is the same as in Example 1, except that high-pressure hydrogenation catalysis is used.

[0031] The reaction process is carried out in a stainless steel high-pressure reactor with a magnetically driven stirring device. First, add an appropriate amount of nitrogen-doped carbon nanotubes and a certain concentration of p-nitrophenol solution in the kettle, stir quickly, and replace it with hydrogen for 4-5 minutes after sealing. After heating to the predetermined reaction temperature, hydrogen gas was introduced to raise the predetermined pressure, and then the reaction was started by timing. The reaction pressure is 1.6MPa, the reaction temperature is 100°C, and the temperature and pressure are kept constant during the reaction process. After the reaction, the pressure is released and cooled. The reaction effect is close to that of Example 1. The reaction rate can be controlled by factors such as catalyst dosage, reaction temperature, reaction pressure,...

Embodiment 3

[0033] Repeat Example 1 with the difference that the reducing agent used is potassium borohydride. Its catalytic effect is close to that of Example 1.

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PUM

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Abstract

The invention discloses a metal-free hydrogenation catalyst. The metal-free hydrogenation catalyst comprises a carbon-based material containing heteroatoms; the metal-free hydrogenation catalyst does not contain a metal component. The invention further discloses application of the metal-free hydrogenation catalyst. Especially, the application of the metal-free hydrogenation catalyst to catalytic hydrogenation reaction, provided by the invention, can be used for preparing an aromatic amine compound through a catalytic hydrogenation method. The metal-free hydrogenation catalyst provided by the invention is low in price, high in catalytic activity and good in stability, is environment-friendly and can replace a noble metal catalyst and a Raney nickel catalyst in an existing hydrogenation process; a production process is effectively simplified and the cost is reduced; the metal-free hydrogenation catalyst has important practicability and economical efficiency.

Description

technical field [0001] The present invention relates to a catalyst and its application. More specifically, it relates to a metal-free hydrogenation catalyst and its application. Background technique [0002] Catalysts play an extremely important role in the modern chemical industry. Catalysts are used in more than 90% of industrial processes, such as petrochemical, fine chemical, biochemical, pharmaceutical, environmental protection, new energy, etc. Among them, the most commonly used catalysts are metals, metal oxides, metal sulfides, and metal matrix composites. For example, noble metals such as platinum, ruthenium, gold, silver, and palladium are often used in oxygen reduction reactions, Fischer-Tropsch synthesis reactions, carbon monoxide oxidation, carbon dioxide conversion, and selective hydrogenation reactions. With the rapid development of the economy and the continuous improvement of human living standards, the demand for various chemicals in the world has increas...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J27/24B01J21/18B01J27/02B01J27/14B01J27/06C07C213/02C07C215/76C07C215/80C07C209/36C07C211/46C07C211/52C07C211/51C07C211/47C07C227/06C07C229/64
CPCB01J27/24B01J21/02B01J21/06B01J21/18B01J27/02B01J27/06B01J27/14C07C209/36C07C213/02C07C227/06C07C215/76C07C215/80C07C211/46C07C211/52C07C211/51C07C211/47C07C229/64
Inventor 陈建峰刘江永
Owner BEIJING UNIV OF CHEM TECH
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