Green environmentally-friendly polymer deodorant capable of efficiently degrading plurality of odorous organic substances and application of deodorant in air purification

A green, environmentally friendly, polymer technology, applied in other chemical processes, deodorization, separation methods, etc., can solve the problems of incomplete removal, slow removal speed, limited practicability, etc., and achieve significant removal effect and increased specific surface area Effect

Active Publication Date: 2018-05-08
浙江裕文环保科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The adsorption method mostly uses activated carbon, clay, molecular sieve and corresponding modified substances as adsorption materials to adsorb and remove odor substances, which has wide applicability, but has the disadvantages of low efficiency of passive adsorption and removal, and needs to be used in combination with purification equipment (with fan) In order to achieve a better removal effect; fragrance masking method is currently a more commonly used method for removing odors, using aromatic components or plant, fruit and other extracts to cover up odors, but there are shortcomings such as treating the symptoms but not the root cause. It is diluted rather than removed, and the harm to the human body has not been eliminated; the plant absorption method mostly uses plants such as tiger Pilan and Chlorophytum, tropical fruits such as pineapples, tea leaves or grapefruit peels to achieve odor removal, which has the characteristics of absorption and aroma masking. , cheap and effective, but the removal speed is relatively slow; the chlorine dioxide oxidation method is more common in odor-removing materials, and the strong oxidizing property of chlorine dioxide itself can achieve the removal of odorous substances, but the removal is not complete, and it is ineffective for many odorous substances , its own toxicity and other disadvantages; the ozone oxidation method is similar to the chlorine dioxide oxidation method, and has a good removal effect on the odor caused by some organic volatile components, but the ozone itself also has a relatively large odor, and has certain damage to the human body Emerging photocatalytic methods mostly use photocatalyst materials to achieve the effect of removing odors under the excitation of light (mostly ultraviolet light is effective), and generally have a certain removal and killing effect on some organic matter and bacteria. source, so the practicality is extremely limited

Method used

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  • Green environmentally-friendly polymer deodorant capable of efficiently degrading plurality of odorous organic substances and application of deodorant in air purification
  • Green environmentally-friendly polymer deodorant capable of efficiently degrading plurality of odorous organic substances and application of deodorant in air purification

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preparation example Construction

[0031] Preparation of bismuth vanadate

[0032] Dissolve 0.0015 mol of sodium vanadate and 0.006 mol of bismuth nitrate in deionized water respectively, drop the sodium vanadate solution into the bismuth nitrate solution drop by drop, stir for 30 minutes, let it stand for 5 hours, and put it in a constant temperature drying box After reacting at 160 degrees Celsius for 12 hours, after cooling to room temperature, continue to keep stirring and add 0.01 mol of hydrogen peroxide, filter with suction, wash and dry to obtain bismuth vanadate powder.

[0033] At room temperature, 8 parts by weight of niobium pentachloride were dissolved in 100 parts by weight of absolute ethanol to obtain a niobium pentachloride ethanol solution, which was left to stand for 15 minutes; 15 parts by weight of bismuth vanadate, 0.08 parts by weight of sulfurous acid Sodium hydrogen blocked HDI was added to the ethanol solution of niobium pentachloride, and the mixture was uniform to obtain the first mi...

Embodiment 1

[0035] In the container of the stirring device, 100 parts by weight of the water-based hyperbranched polymer A2, 15 parts by weight of porous silica and zirconia balls are added to the container, stirred at 3000 rpm for 2 hours and then filtered to remove the zirconia balls , add 0.12 parts by weight of hydrogen peroxide, stir at 1000 rpm for 2 hours; add 6 parts by weight of the modified nano niobium oxide prepared above, stir for 1 hour at 1000 rpm, add 3 parts by weight of polyethylene glycol Stir the alcohol evenly to obtain a polymer deodorant.

Embodiment 2

[0037]In the container of the stirring device, 100 parts by weight of the water-based hyperbranched polymer A2, 24 parts by weight of porous silica and zirconia balls are added to the container, stirred at 3000 rpm for 2 hours, then filtered to remove the zirconia balls , add 0.27 parts by weight of hydrogen peroxide, stir at 1000 rpm for 2 hours; add 9 parts by weight of the modified nano niobium oxide prepared above, stir for 1 hour at 1000 rpm, add 3 parts by weight of polyethylene glycol Stir the alcohol evenly to obtain a polymer deodorant.

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Abstract

The invention relates to a green environmentally-friendly polymer deodorant capable of efficiently degrading a plurality of odorous organic substances. A purifier includes an air passage, the inner surface of the air passage is coated by the polymer deodorant, and the polymer deodorant is prepared from 100 parts by weight of a water-based hyperbranched polymer, 1-5 parts by weight of polyethyleneglycol, 6-30 parts by weight of porous silicon dioxide, 0.03-0.3 part by weight of hydrogen peroxide and 3-10 parts by weight of modified nano niobium oxide, wherein the solid content of the water-based hyperbranched polymer is 5-15%. The green environmentally-friendly polymer deodorant provided by the invention can efficiently degrade the plurality of odorous organic substances.

Description

technical field [0001] The invention relates to a green environment-friendly polymer deodorant capable of efficiently degrading various odorous organic substances, and also relates to the application of the green environment-friendly polymer deodorant capable of efficiently degrading various odorous organic substances in air purification. Background technique [0002] The peculiar smell in the home environment not only brings bad sensory stimulation to people, but also has great harm to the body. For example, second-hand smoke contains more than 4,000 harmful chemicals and dozens of carcinogens such as tar, ammonia, nicotine, suspended particles, PM2.5, and polonium-210. Indoor air pollution is a major cause of death in the world; formaldehyde odor brought by home decoration has negative effects such as irritation, allergies, and mutagenesis, which greatly endangers people's health; musty smell in the environment, kitchen odor (oil smoke, sour smell) Odor, etc.), toilet odo...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/26B01D53/86A61L9/014
CPCA61L9/014B01D53/02B01D53/86B01D2255/207B01D2255/802B01J20/06B01J20/262B01J20/264
Inventor 徐淑萍郑文华张世英楼伟杰应康霖
Owner 浙江裕文环保科技有限公司
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