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Anti-ultraviolet nanometer polyurethane wood surface coating and preparation method thereof

A surface coating, anti-ultraviolet technology, applied in the field of nanomaterials, can solve the problems of uneven gloss, poor flame retardant effect, poor mechanical properties, etc., and achieve the effects of simple preparation process, improved corrosion resistance, and simple composition

Inactive Publication Date: 2018-06-08
大连保税区百克经贸有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At room temperature, the final hardness cannot be reached within many days, and the products are easy to stick when stacked, which cannot meet the requirements of industrial high-quality and high-efficiency coating
The heat of evaporation of water is relatively high, and in high and low temperature environments, the drying of water-based coatings is slower, and it is particularly prone to construction problems such as whitening, cracking, mirror frames, and uneven gloss; (2) general-purpose polyurethane resin Poor mechanical properties, low strength, and poor toughness; easy to crack after curing, and has no shielding effect on electromagnetic waves, and is easy to age under ultraviolet light
Although the existing toughening modification methods improve the toughness of polyurethane resin to a certain extent, they damage other excellent properties of the resin, such as reducing the strength and wear resistance of the resin.
(3) poor flame retardant effect

Method used

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  • Anti-ultraviolet nanometer polyurethane wood surface coating and preparation method thereof
  • Anti-ultraviolet nanometer polyurethane wood surface coating and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] In the present embodiment, the anti-ultraviolet nano-polyurethane wood surface coating has the following components and contents in parts by weight: 100 parts of polyurethane resin, 18 parts of nano-composite mother liquor, 7 parts of composite corrosion inhibitor, and organic corrosion inhibitor 0.8 parts, 2 parts of anti-ultraviolet pigment (carbon black, particle size 50-100nm), 2 parts of flame retardant filler, 7 parts of toluene diisocyanate (TDI) (curing agent), 8 parts of organic solvent; among them, the organic corrosion inhibitor is Zinc p-nitrocinnamate, the organic solvent is acetone; the flame retardant filler is mixed with quartz powder and antimony trioxide in a weight ratio of 1:1, and the particle size is 50-100nm.

[0032]In the nano-composite mother liquor, the weight ratio of nano-titanium dioxide, nano-silica, nano-zinc oxide and organic solvent is 45:35:25:35, the coupling agent accounts for 4% of the total weight of the above-mentioned nanoparticle...

Embodiment 2

[0041] In the present embodiment, the anti-ultraviolet nano-polyurethane wood surface coating has the following components and contents in parts by weight: 100 parts of polyurethane resin, 15 parts of nano-composite mother liquor, 6 parts of composite corrosion inhibitor, and organic corrosion inhibitor 1.0 parts, 1 part of anti-ultraviolet pigment (titanium dioxide, particle size 50-100nm), 3 parts of flame retardant filler, 6 parts of diphenylmethane diisocyanate (MDI), 5 parts of organic solvent; among them, the organic corrosion inhibitor is Calcium nitrocinnamate, the organic solvent is acetone; the flame retardant filler is mixed with quartz powder and asbestos fiber in a weight ratio of 2:1, and the particle size is 50-100nm.

[0042] In the nano-composite mother liquor, the weight ratio of nano-titanium dioxide, nano-silica, nano-zinc oxide and organic solvent is 40:40:20:50, the coupling agent accounts for 3% of the total weight of the above-mentioned nanoparticles, an...

Embodiment 3

[0051] In the present embodiment, the anti-ultraviolet nano-polyurethane wood surface coating has the following components and contents in parts by weight: 100 parts of polyurethane resin, 20 parts of nano-composite mother liquor, 8 parts of composite corrosion inhibitor, and organic corrosion inhibitor 0.5 parts, 3 parts of anti-ultraviolet pigment (fast yellow, particle size 50-100nm), 1 part of flame-retardant filler, 8 parts of 1,6-hexamethylene diisocyanate (HDI), 10 parts of organic solvent; among them, organic corrosion inhibitor It is zinc p-nitrocinnamate, the organic solvent is acetone; the flame retardant filler is mixed with asbestos fiber and antimony trioxide in a weight ratio of 1:2, and the particle size is 50-100nm.

[0052] In the nano-composite mother liquor, the weight ratio of nano-titanium dioxide, nano-silica, nano-zinc oxide and organic solvent with a particle size between 1 and 50nm is 50:30:30:20, and the coupling agent accounts for the total weight of...

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Abstract

The invention belongs to the field of nanometer materials, and specifically provides an anti-ultraviolet nanometer polyurethane wood surface coating and a preparation method thereof. The coating comprises the following components with contents in parts by weight: 100 parts of polyurethane resin, 15 to 20 parts of a nanocomposite mother liquor, 6 to 8 parts of a composite corrosion inhibitor, 0.5 to 1.0 part of an organic corrosion inhibitor, 1 to 3 parts of an anti-ultraviolet pigment, 1 to 3 parts of a flame-retardant filler, 6 to 8 parts of isocyanate and 5 to 10 parts of an organic solvent.The preparation method comprises the following steps: weighing the polyurethane resin, the nanocomposite mother liquor, the composite corrosion inhibitor, the organic corrosion inhibitor, the anti-ultraviolet pigment, the flame-retardant filler, the isocyanate and the organic solvent, carrying out mixing in proportion, carrying out dispersion, and carrying out grinding until a particle size is 100 nm or below so as to prepare the anti-ultraviolet nanometer polyurethane wood surface coating. The coating provided by the invention has rapid drying speed and high strength and toughness, has shielding effect to electromagnetic wave, is insusceptible to aging, and can meet the requirements of flame retardancy, ultraviolet resistance and aging resistance.

Description

technical field [0001] The invention belongs to the field of nanometer materials, in particular to an anti-ultraviolet nanometer polyurethane wood surface coating and a preparation method thereof. Background technique [0002] Wood products include solid wood and wood-based panels (plywood, medium density fiberboard and particle board). Coatings used for supplies, stationery, toys, etc. are mainly furniture coatings. Wood coatings are divided into two categories according to the wood manufacturing process, plate pre-coating and finished wood coating coatings, and are divided into solvent-based coatings, water-based coatings and solvent-free coatings according to coating types. [0003] Polyurethane wood lacquer is a relatively common type of coating at present, which can be divided into two-component polyurethane coatings and one-component polyurethane coatings. Two-component polyurethane topcoat paint is generally composed of isocyanate prepolymers (also known as low mole...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D175/04C09D5/08C09D5/18C09D7/62C09D7/63C09D7/61
CPCC09D175/04C08K2003/2241C08K2003/2296C08L2201/08C08L2205/025C09D5/08C09D5/18C08L75/04C08K13/06C08K9/08C08K9/06C08K3/36C08K3/34C08K3/04C08K3/2279C08K7/12C08K3/22
Inventor 王晓强
Owner 大连保税区百克经贸有限公司
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