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Low melting point metal alloy modified superhydrophobic material and its preparation method and application

A low-melting-point metal, super-hydrophobic technology, used in epoxy resin coatings, coatings, special surfaces, etc., can solve the problems of damage, insufficient use strength, short service life, etc., and achieve a simple production process, good stability, and durability. Sex-enhancing effects

Active Publication Date: 2020-02-11
HENAN INST OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The current problems of this method mainly include: 1. This method needs to use various preparation methods to prepare micro-nano particles before application, which makes the preparation process of superhydrophobic materials cumbersome, high production cost, and low production efficiency; 2. The prepared The surface micro-nano composite structure of super-hydrophobic materials is very fragile, easily damaged by external influences, the use strength is not enough, and the service life is short

Method used

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  • Low melting point metal alloy modified superhydrophobic material and its preparation method and application
  • Low melting point metal alloy modified superhydrophobic material and its preparation method and application
  • Low melting point metal alloy modified superhydrophobic material and its preparation method and application

Examples

Experimental program
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Effect test

Embodiment 1

[0034] Weigh 5g of indium-tin-bismuth alloy with a melting point of 60°C, 3.0g of polydimethylsiloxane (PDMS) prepolymer, 0.3g of curing agent, 3g of epoxy resin glue, and 100mL of tetrahydrofuran, and mix them directly in a 250ml beaker. At the same time, the beaker was heated in a water temperature ultrasonic cleaner at 75°C and ultrasonicated for 10 minutes to promote the liquefied indium-tin-bismuth alloy to be highly dispersed in the liquid into small droplets, and immediately placed the beaker in an ultrasonic cleaner filled with cold water to cool and continue Ultrasonication, stop the ultrasonication after the temperature of the mixture in the beaker drops and the highly dispersed indium tin bismuth alloy droplets solidify into a highly dispersed solid powder. Soak the pre-cleaned and dried 300-mesh 316 stainless steel mesh of 5 cm in length and width into the solution in the beaker for 3 minutes, take it out, drain the solution on the top of the beaker, and vacuum-dry ...

Embodiment 2

[0036] Weigh 5g of gallium-zinc alloy with a melting point of 81°C, 2g of perfluorooctyltrimethoxysilane, 3g of acrylate glue, and 100mL of N,N-dimethylformamide, and mix them together directly in a 250mL beaker. Heat in a water bath at 100°C and stir mechanically for 10 minutes to promote the highly dispersed liquefied gallium-zinc alloy into small droplets in the liquid. Immediately place the beaker in a water bath filled with cold water to cool and continue to stir until the temperature of the mixture in the beaker drops to a high degree of dispersion. The gallium-zinc alloy droplets are solidified into a highly dispersed solid powder and the stirring is stopped. Soak the pre-cleaned and dried polyurethane foam of 5 cm in length, width, and 1 cm in height into the solution in the beaker for 3 minutes, repeatedly squeeze the polyurethane foam during this period, drain the solution on the top of the beaker after taking it out, and place it in a preheated 75°C Vacuum-dry in a ...

Embodiment 3

[0038] The low-melting-point metal-modified superhydrophobic stainless steel mesh made in Example 1 is cut into a circle with a diameter of 4.2 cm, placed between two clamps, clamped and sealed, and the upper and lower ends of the clamp are connected to a glass tube with an outer diameter of 4.2 cm. The oil-water separation device is clamped vertically (oil with a separation density greater than water) or at an angle of 30° to the horizontal plane (oil with a separation density lower than water) on a solid iron stand, pour the oil-water mixture, and the oil will quickly pass through the stainless steel mesh and enter the lower part The receiver, while the water will stagnate in the upper glass tube. The low-melting-point metal-modified superhydrophobic stainless steel mesh prepared by the present invention can efficiently and rapidly separate oil-water mixtures including dichloromethane, chloroform, n-hexane, petroleum ether, isooctane, peanut oil, soybean oil, and corn oil, an...

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Abstract

The invention discloses a low-melting-point metal alloy modified super-hydrophobic material as well as a preparation method and application thereof, which belongs to the technical field of inorganic materials. The modified super-hydrophobic material is prepared by adopting stable and nontoxic metal alloy with lower melting point such as gallium-zinc alloy, gallium-indium alloy, gallium-indium-tinalloy, gallium-indium-tin-zinc alloy and gallium-tin-bismuth alloy. The dispersibility of the liquid low-melting-point metal alloy and the high strength and good stability of the solid low-melting-point metal alloy can be ingeniously utilized. The preparation process is simplified, the process is simple, the preparation cost is low, the preparation efficiency is high, the prepared super-hydrophobic material has higher wear resistance and longer service life, and the super-hydrophobic material can be more widely used.

Description

technical field [0001] The invention relates to a super-hydrophobic material, in particular to a low-melting-point metal-modified super-hydrophobic material and a preparation method and application thereof, belonging to the technical field of inorganic chemistry or material chemistry. Background technique [0002] Superhydrophobic materials refer to functional materials with a water contact angle greater than 150° and a rolling angle less than 10° on its surface. The performance of superhydrophobic materials mainly depends on two aspects: the micro-nano-scale roughness and low surface energy of the surface of the material, so there are two main strategies for the preparation of super-hydrophobic materials: the micro-nano-scale rough surface of the material uses low surface energy substances (such as Polydimethylsiloxane, fluorine-containing silane, etc.) for modification and micro-nano roughening of the low surface energy surface of the material. The preparation methods of ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D183/04C09D163/00C09D133/04C09D7/61B22F9/08B05D7/24B05D5/00
CPCB05D5/00B05D7/24B22F9/08B22F2009/0812C08K2003/0837C08K2003/0893C09D133/04C09D163/00C09D183/04C08L63/00C08K3/08C08L83/04
Inventor 张毅军白秀芝陈军陈娜张裕平
Owner HENAN INST OF SCI & TECH