Anisotropic bonded permanent magnet material and method for preparing same

A manufacturing method and anisotropic technology, applied in the direction of magnetic materials, inorganic material magnetism, adhesives, etc., can solve the problems of oxidation resistance, corrosion resistance deterioration, insufficient mechanical strength, product quality decline, etc., to improve corrosion resistance. and heat resistance, improved oxidation and corrosion resistance, and improved compactness

Active Publication Date: 2018-07-27
圣航粉末冶金河北有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] However, because the injection molding process requires high temperature heating, it is difficult to avoid the deterioration of oxidation resistance and corrosion resistance of rare earth permanent magnet powder caused by high temperature.
At the same time, although the commonly used thermoplastic resin binder endows the permanent magnet with excellent heat resistance, it is obviously insufficient in terms of mechanical strength, and in the face of increasingly harsh use environments and requirements, even the heat resistance needs to be further improved
In addition, in order to meet the requirements of injection molding for the flow properties of the mixed melt, it is necessary to increase the content of thermoplastic resin binder, which usually comes at the expense of the magnetic properties and mechanical strength of permanent magnet products, but if the thermoplastic resin bond is reduced If the content of the additive is low, it will lead to poor molding caused by defects such as microscopic cavities inside the bonded magnet, which will also cause problems such as reduced mechanical strength and reduced product quality.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] The anisotropic adhesive rare earth permanent magnet material is prepared by the following method:

[0029] 1) Provide SmFeN rare earth permanent magnet powder raw material; the nominal chemical formula of the SmFeN rare earth permanent magnet powder raw material is Sm 2 Fe 17 N 3 , and the Sm 2 Fe 17 N 3 The average particle size (D50) of the rare earth permanent magnet powder is 5-10 μm.

[0030] 2) Alloying the SmFeN rare earth permanent magnet powder with an aluminum-magnesium alloy; wherein the mass ratio of aluminum to magnesium in the aluminum-magnesium alloy is 1:2, and based on 100 parts by weight of the SmFeN rare earth permanent magnet powder, The aluminum-magnesium alloy is 3 parts by weight. The aluminum-magnesium alloy is a powder with an average particle diameter (D50) of 7 μm. The alloying treatment is to mix the SmFeN rare-earth permanent magnet powder and the aluminum-magnesium alloy powder in a mechanical device, then heat to 450° C. under a ni...

Embodiment 6

[0039] In embodiment 6, step 3) adopts isobutyltrimethoxysilane to carry out surface treatment to described SmFeN rare earth permanent magnet powder; Wherein is described SmFeN rare earth permanent magnet powder and with described SmFeN rare earth permanent magnet powder 100 parts by weight 0.5 parts by weight of isobutyltrimethoxysilane and 2 parts by weight of water were mixed and stirred, and the remaining process steps, parameters and other conditions were the same as in Example 1. In embodiment 7, the SmFeN rare earth permanent magnet powder is mixed with 2 parts by weight of isobutyltrimethoxysilane and 2 parts by weight of water based on 100 parts by weight of the SmFeN rare earth permanent magnet powder. , parameters and other conditions are all the same as in Example 1.

[0040] In Examples 8-9, step 3) uses isobutyltrimethoxysilane to carry out surface treatment on the SmFeN rare earth permanent magnet powder; wherein the heat treatment temperatures are 70°C and 120°...

Embodiment 10

[0041] In embodiment 10, step 4) mix the SmFeN rare earth permanent magnet powder after alloying treatment and surface treatment with composite resin binder and then knead in a mixer to obtain injection molding raw materials; wherein, composite resin binder In the agent, the content of each component is 42% of polyphenylene sulfide ketone, 41% of polybutylene terephthalate, 15% of styrene-ethyl acrylate copolymer, 2% of organic bentonite, and the benzene The monomer mass ratio of styrene to ethyl acrylate in the ethylene-ethyl acrylate copolymer is 2. Conditions such as all the other processing steps, parameters are identical with embodiment 1.

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Abstract

The invention provides an anisotropic bonded rare-earth permanent magnet material and a method for preparing the same. The method includes steps of 1), providing SmFeN rare-earth permanent magnet powder materials; 2), carrying out alloying treatment on SmFeN rare-earth permanent magnet powder by the aid of aluminum magnesium alloy; 3), carrying out surface treatment on the SmFeN rare-earth permanent magnet powder by the aid of isobutyltrimethoxysilane; 4), mixing the SmFeN rare-earth permanent magnet powder and composite resin binders with one another to obtain mixtures after the alloying treatment and the surface treatment are carried out on the SmFeN rare-earth permanent magnet powder, and then carrying out mixing on the mixtures in a mixing mill to obtain injection molding raw materials; 5), filling preheated molds with the injection molding raw materials and carrying out injection molding on the injection molding raw materials so as to obtain the anisotropic bonded rare-earth permanent magnet material. The composite resin binders comprise polyphenylene sulfide ketone, polybutylene terephthalate, styrene-ethyl acrylate copolymers and bentonite. The anisotropic bonded rare-earthpermanent magnet material and the method have the advantage that the anisotropic bonded rare-earth permanent magnet material prepared by the aid of the method is excellent in magnetic performance, mechanical performance, temperature resistance, corrosion resistance and recycling performance.

Description

technical field [0001] The invention relates to the technical field of rare earth permanent magnet materials, in particular to an anisotropic adhesive rare earth permanent magnet material and a manufacturing method thereof. Background technique [0002] Rare earth permanent magnet materials refer to permanent magnet materials made of alloys formed of rare earth metals and transition metals through a certain process. Compared with traditional magnets, ferrite and other magnetic materials, rare earth permanent magnet materials have more excellent performance, and have been widely used in various fields such as machinery, electronics, instrumentation and medical treatment. [0003] Specifically, rare earth permanent magnet materials are alloys composed of rare earth metals such as samarium and neodymium and transition metals (such as cobalt, iron, etc.), which are formed by powder metallurgy, sintered or bonded, and then magnetized by a magnetic field. A magnetic material obta...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01F1/059H01F1/08B22F1/00B22F3/22C09J181/02C09J167/02C09J11/08C09J11/04
CPCH01F1/059H01F1/08C09J11/04C09J11/08C09J181/02B22F3/225C08K2201/01C08L2205/03B22F1/103B22F1/10C08L67/02C08L25/14C08K3/34C08K3/28
Inventor 韩爱文
Owner 圣航粉末冶金河北有限公司
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