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A kind of polystyrene cross-linked divinylbenzene resin honeycomb body and preparation method thereof

A technology of divinylbenzene and polystyrene, which is applied in the field of polystyrene crosslinked divinylbenzene resin honeycomb and its preparation, can solve problems such as incomplete desorption, affecting adsorption, and increased pressure drop of equipment. It achieves the effect of being convenient for commercial application, convenient for storage and transportation, and less dust pollution

Active Publication Date: 2019-10-29
广州市环境保护设备厂有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, activated carbon adsorbents still have the following deficiencies in the application: (1) The excessive development of the microporous region leads to low adsorption capacity and incomplete desorption due to the limitation of pore volume; (3) The catalytic effect of heteroatoms on the surface, the high heat of adsorption when adsorbing high-concentration VOCs can lead to serious deterioration of the carbon layer, carbonization, and even fire; (4) The presence of hydrophilic oxygen-containing functional groups on the surface, the moisture in the gas will significantly affect the adsorption of VOCs

Method used

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  • A kind of polystyrene cross-linked divinylbenzene resin honeycomb body and preparation method thereof
  • A kind of polystyrene cross-linked divinylbenzene resin honeycomb body and preparation method thereof
  • A kind of polystyrene cross-linked divinylbenzene resin honeycomb body and preparation method thereof

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] The raw materials used for the polystyrene crosslinked divinylbenzene resin honeycomb body in this example are: based on the total mass fraction of 100%, including polystyrene crosslinked divinylbenzene resin powder 84%, water-based acrylic acid emulsion 5%, fat Amide 1%, Phosphate 1%, Carboxymethyl Cellulose 2%, and Attapulgite 7%.

[0026] The specific preparation steps of the polystyrene crosslinked divinylbenzene resin honeycomb body are:

[0027] Step (1): Add 6 L of polystyrene cross-linked divinylbenzene resin particles and 6 L of deionized water into the grinding barrel of the ball mill, and the ratio of ball to water is 2:1:1. Add all the materials successively in the order of 2L polystyrene cross-linked divinylbenzene resin particles + 2L deionized water + 4L ball mill. After sealing, grind at a speed of 30 rpm for 8 hours to obtain a slurry-like resin. Slurry resin can pass through a 300-mesh sieve;

[0028] Step (2): The slurry resin is subjected to vacuu...

Embodiment 2

[0032] The raw materials used for the polystyrene crosslinked divinylbenzene resin honeycomb body in this embodiment are: based on the total mass fraction of 100%, including polystyrene crosslinked divinylbenzene resin powder 49%, epoxy resin 20%, fat Amide 3%, Phosphate 3%, Polyacrylamide 5%, and Bentonite 20%.

[0033] The specific preparation steps of the polystyrene crosslinked divinylbenzene resin honeycomb body are:

[0034] Step (1): Add 6 L of polystyrene cross-linked divinylbenzene resin particles and 6 L of deionized water into the grinding barrel of the ball mill, and the ratio of ball to water is 2:1:1. Add all the materials in the order of 2L resin + 2L deionized water + 4L ball mill. After sealing, grind at a speed of 30 rpm for 8 hours to obtain a slurry-like resin. Slurry resin can pass through a 300-mesh sieve;

[0035]Step (2): The slurry resin is subjected to vacuum filtration (double-layer filter paper with a pore size of 0.22 μm, pressure −0.07 MPa) to ...

Embodiment 3

[0038] The raw materials used for the polystyrene crosslinked divinylbenzene resin honeycomb body in this embodiment are: based on the total mass fraction of 100%, including polystyrene crosslinked divinylbenzene resin powder 87%, phenolic resin 5%, twelve Sodium Alkylbenzene Sulfonate 1%, Phosphate 1%, Carboxymethyl Cellulose 1%, and Kaolin 5%.

[0039] The specific preparation steps of the polystyrene crosslinked divinylbenzene resin honeycomb body are:

[0040] Step (1): Add 6 L of polystyrene cross-linked divinylbenzene resin particles and 6 L of deionized water into the grinding barrel of the ball mill, and the ratio of ball to water is 2:1:1. Add all the materials in the order of 2L resin + 2L deionized water + 4L ball mill. After sealing, grind at a speed of 30 rpm for 8 hours to obtain a slurry-like resin. Slurry resin can pass through a 300-mesh sieve;

[0041] Step (2): The slurry resin is subjected to vacuum filtration (double-layer filter paper with a pore size ...

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Abstract

The invention discloses a polystyrene crosslinked divinylbenzene resin honeycomb and a preparation method thereof. The method includes the following steps: evenly mixing polystyrene crosslinked divinylbenzene resin powder, binder, auxiliary agent, thickener and clay as raw materials to obtain a stock, extruding the stock into a honeycomb blank by a molding extruder and drying the honeycomb blank to obtain a polystyrene crosslinked divinylbenzene resin honeycomb adsorbing VOCs. The preparation method is simple in operation, and the raw materials are easy to obtain. Compared with granular resin,the honeycomb material has lower wind resistance, and further reduces the energy consumption during use. At the same time, gas and the materials can be in full contact by honeycomb molding under thesame weight condition, and the material adsorption efficiency is improved. Compared with honeycomb activated carbon and honeycomb molecular sieves, the material has higher saturated adsorption capacity for volatile organic gas, and is beneficial to large-scale commercial applications.

Description

Technical field: [0001] The invention belongs to the technical field of forming volatile organic compound adsorption materials, and in particular relates to a polystyrene crosslinked divinylbenzene resin honeycomb body for absorbing VOCs and a preparation method thereof. Background technique: [0002] Volatile organic compounds (VOCs) refer to organic compounds that participate in atmospheric photochemical reactions, including non-methane hydrocarbons (alkanes, alkenes, alkynes, aromatic hydrocarbons, etc.), oxygen-containing organic compounds (aldehydes, ketones, alcohols, ethers, etc.), chlorine-containing Organic matter, nitrogen-containing organic matter, sulfur-containing organic matter, etc. Most VOCs are toxic and harmful substances, which pose a serious threat to human health. When the concentration is too high, they will cause poisoning and can cause diseases of human organs. Some VOCs can even cause gene mutations and carcinogenicity, such as certain ketones, Benz...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J20/26B01J20/28B01J20/30B01D53/02
CPCB01D53/02B01D2257/708B01D2258/06B01J20/12B01J20/22B01J20/267B01J20/2803B01J20/28045
Inventor 曾思泉龚绍峰钟润洪黄荣贵刘迎伟
Owner 广州市环境保护设备厂有限公司