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Carbon electrode material of perovskite thin film solar cell and preparation method of carbon electrode material

A solar cell and carbon electrode technology, applied in the field of solar cells, can solve the problems of poor solar cell stability, unsatisfactory photoelectric conversion efficiency, and high solar cell preparation cost, and achieve good storage stability and high photoelectric conversion efficiency. , the effect of reducing costs

Active Publication Date: 2019-06-18
SOUTHWEST PETROLEUM UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] In the preparation process of perovskite solar cells, it is usually necessary to use noble metal gold or silver as the counter electrode of the battery, which makes the preparation cost of solar cells higher and is not conducive to large-scale production. Now carbon materials have been added to perovskite It is used as an electrode in solar cells, but the existing carbon material preparation process is complicated, and the stability of the solar cells is not very good, and the photoelectric conversion efficiency is not very ideal

Method used

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  • Carbon electrode material of perovskite thin film solar cell and preparation method of carbon electrode material
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  • Carbon electrode material of perovskite thin film solar cell and preparation method of carbon electrode material

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Embodiment 1

[0025] A preparation method of a carbon electrode material for a perovskite thin film solar cell, specifically comprising the following steps:

[0026] S1. Add 1g of glucose into an autoclave with 40ml ethylene glycol-water solution (the volume ratio of ethylene glycol to distilled water is 2:1), stir and dissolve to obtain carbon-ethylene diol-water solution;

[0027] S2. Add 0.2 g of cetyltrimethylammonium bromide to the carbon-ethylene glycol-water solution obtained in S1, and stir for 30 minutes to obtain a mixed solution;

[0028] S3, reacting the mixed solution obtained in S2 in an oven at 160° C. for 1 hour to obtain a reaction solution, and then filtering, washing and drying the reaction solution to obtain a reactant;

[0029] S4. Calcining the reactant obtained in S3 at 550° C. for 2 hours in a tube furnace under an argon atmosphere, and then washing, centrifuging, and drying to obtain a carbon electrode material.

Embodiment 2

[0031] A method for preparing a carbon electrode material for a perovskite thin-film solar cell. The specific steps are the same as in Example 1, except that the mass of cetyltrimethylammonium bromide used in S2 is 0.6g.

Embodiment 3

[0033] A method for preparing a carbon electrode material for a perovskite thin-film solar cell. The specific steps are the same as in Example 1, except that the mass of cetyltrimethylammonium bromide used in S2 is 1 g.

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Abstract

The invention discloses a carbon electrode material of a perovskite thin film solar cell. According to the carbon electrode material, a carbon source and a template agent are used as raw materials, and the carbon electrode material is prepared through a solvothermal reaction under the temperature of 100-200 DEG C and a pyrolytic carbonization reaction under the temperature of 500-650 DEG C. The invention furthermore discloses a preparation method of the carbon electrode material. The method comprises the steps that the carbon source is added into a glycol-water solution, the template agent isadded for uniform mixing, and then the mixture is subject to a reaction under the temperature of 100-200 DEG C for 1-2h to obtain a reactant; and then under a protective gas atmosphere, the reactant is calcined under the temperature of 500-650 DEG C for 2-3h, and the carbon electrode material is obtained. The carbon electrode material replaces expensive noble metal to serve as a hole transportingelectrode material, so that cost is lowered; and the prepared carbon electrode material has a hollow spherical structure and has stable performance when applied to the solar cell, and photoelectric conversion efficiency is improved. Meanwhile, the carbon electrode material is prepared by synthesizing two reactions, namely the solvothermal reaction and the pyrolytic carbonization reaction, so thatoperation is easy and convenient.

Description

technical field [0001] The invention belongs to the technical field of solar cells, and in particular relates to a carbon electrode material for a perovskite thin-film solar cell and a preparation method thereof. Background technique [0002] With the continuous consumption of coal, oil, and natural gas, the three traditional fossil energy sources, the energy crisis has become a common problem faced by all mankind. At the same time, the environmental pollution caused by the burning of fossil fuels has gradually deepened. People urgently need to find a clean and non-toxic polluting alternative energy sources. Among them, solar energy is inexhaustible and has always been considered as one of the most ideal energy sources. At present, about 85% of the market share of solar cells is occupied by crystalline silicon solar cells, but the high price of crystalline silicon seriously restricts its development. Perovskite solar cell is an emerging photovoltaic industry developed in r...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L51/42H01L51/44C01B32/05
CPCY02E10/549
Inventor 于华章文峰张富
Owner SOUTHWEST PETROLEUM UNIV
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