Preparation method of high-performance aluminum-doped cadmium sulfide silicon-based heterojunction light-emitting diode
A light-emitting diode and cadmium sulfide technology, which is applied in semiconductor devices, electrical components, circuits, etc., can solve the problems of low energy consumption, high energy consumption, and low luminous efficiency of diodes, so as to increase carrier mobility and reduce The effect of starting the operating voltage and improving the luminous efficiency
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[0039] (1) Preparation and post-processing of P-type nanoporous silicon columnar arrays
[0040] The process of preparing P-type nanoporous silicon columnar arrays by hydrothermal etching method is as follows: (1) Firstly, soak the cut P-type heavily doped single crystal silicon wafer in acetone or ethanol solution for 5 minutes to remove surface organic pollutants , and then deep clean it using the standard RCA cleaning process. (2) Fix the cleaned silicon wafer on the sample holder, put it vertically into the hydrothermal reaction kettle, inject the prepared corrosion solution (0.03mol / L ferric nitrate nonahydrate, 13mol / L hydrofluoric acid) into the reaction kettle Acid and deionized water composition, reactor filling degree 83%). (3) Put the reactor into a drying oven, raise the temperature to 142°C, keep it warm for 45 minutes, take it out from the drying oven, cool for 60 minutes and open the cover, then cool to room temperature and take out the corroded silicon wafer f...
Embodiment 1
[0048] A method for preparing a high-performance aluminum-doped cadmium sulfide silicon-based heterojunction light-emitting diode, comprising the following steps:
[0049] Step A. Soak the cut P-type heavily doped monocrystalline silicon wafer in acetone or ethanol solution to remove surface organic pollutants, and then perform deep cleaning with standard RCA cleaning process;
[0050] Step B. Fix the cleaned silicon wafer on the sample holder, put it vertically into the hydrothermal reaction kettle, and inject the prepared etching solution into the reaction kettle;
[0051] Step C, putting the reaction kettle into a drying oven, first heating up, and then heat preservation;
[0052] Step D, take it out from the drying oven, cool for 60 minutes and open the cover, then cool to room temperature, take out the corroded silicon wafer from the reaction kettle, rinse it repeatedly with deionized water, and dry it naturally to obtain the nanoporous silicon columnar array;
[0053] S...
Embodiment 2
[0061] A method for preparing a high-performance aluminum-doped cadmium sulfide silicon-based heterojunction light-emitting diode, comprising the following steps:
[0062] Step A. Soak the cut P-type heavily doped monocrystalline silicon wafer in acetone or ethanol solution to remove surface organic pollutants, and then perform deep cleaning with standard RCA cleaning process;
[0063] Step B. Fix the cleaned silicon wafer on the sample holder, put it vertically into the hydrothermal reaction kettle, and inject the prepared etching solution into the reaction kettle;
[0064] Step C, putting the reaction kettle into a drying oven, first heating up, and then heat preservation;
[0065] Step D, take it out from the drying oven, cool for 60 minutes and open the cover, then cool to room temperature, take out the corroded silicon wafer from the reaction kettle, rinse it repeatedly with deionized water, and dry it naturally to obtain the nanoporous silicon columnar array;
[0066] S...
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