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Vehicle paint film based on nanometer composite material, and preparation method thereof

A nano-composite material and car paint technology, applied in the field of car paint film, can solve the problems of poor impact resistance of car paint, volatile harmful substances, easy agglomeration of nano-powders, etc., and achieve excellent salt spray resistance and surface contact angle. The effect of improving and increasing the surface contact angle

Active Publication Date: 2019-08-23
山东亿隆薄膜材料有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to people's increasing attention to the environment in recent years, the emission of volatile organic compounds (VOC) is being restricted more and more strictly. The paint film coatings used by most domestic bus and passenger car factories are solvent-based coatings and contain a lot of harmful substances. components, its VOC emission is 100g / m3, which does not meet the requirements of green environmental protection, and in the spraying process, a large amount of volatile harmful substances are produced, which affects the health of workers. These are the challenges faced by the car during use
[0003] The patent with authorized notification number CN100554352C discloses a preparation method of a scratch-resistant nano-water-based automotive coating, which uses polyurethane as the main film-forming resin, introduces nano-powders, including silicon dioxide, titanium dioxide, etc., and uses mechanical and physical dispersion methods Nano water-based automotive coatings are prepared under the action of cross-linking agents, but this method cannot realize the uniform dispersion of silica and titanium dioxide in the resin matrix, and the nano-powders are easy to agglomerate and difficult to disperse stably for a long time, which ultimately affects the appearance of the car. Quality, and the impact resistance of the car coating is not strong

Method used

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  • Vehicle paint film based on nanometer composite material, and preparation method thereof

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preparation example Construction

[0045] The preparation method of the car paint film based on the nanocomposite material comprises the following steps:

[0046] Step S1, put the nanocomposite material and carnauba wax into a beaker, add 1 / 3 of deionized water, 1 / 3 of defoamer, wetting and dispersing agent, stir at 1000r / min for 15-30min, and then shake at high speed Shake the machine for 30-50 minutes to obtain the premix;

[0047] Step S2, under the stirring condition of 1000r / min, add the premix prepared in step S1 into the modified modified acrylic emulsion, then add the remaining deionized water and defoamer, stir for 40-50min, add thickening agent, adjust the liquid viscosity to be 20-25S, and obtain the car paint film coating;

[0048] Step S3, pre-cleaning and drying the surface of the car paint. Compared with the traditional cleaning pre-treatment, attention should be paid to strengthening the pre-cleaning wiping process and adjusting the cleaning spray;

[0049] Specifically, strengthen the pre-cle...

Embodiment 1

[0054] Preparation of modified acrylic emulsion:

[0055] (1) Add 19.9 g of hydroxyethyl methylcellulose, 16.74 g of perfluorobutyl ethyl methacrylate, 136.5 g of n-butyl acrylate, 137.3 g of methyl methacrylate, and Acrylic acid 5.2g, methacrylate ethylene urea ethoxylate 5g, fully stirred for 30min to obtain the first pre-emulsion;

[0056] (2) Add 5.5 g of hydroxyethyl methylcellulose, 8 g of perfluorobutyl ethyl methacrylate, 40 g of n-butyl acrylate, 135 g of methyl methacrylate, and 2 g of methacrylic acid in 45 g of deionized water. 1 g of ethylene urea ethoxy methacrylate, fully stirred for 0.5 h to obtain the second pre-emulsion;

[0057] (3) Add 280g deionized water and 2.2g maleic acid ester type emulsifier in the flask that reflux condenser, thermometer and stirring device are housed, temperature is raised to 85 ℃, add 10% under the constant temperature condition of 85 ℃ Stir the first pre-emulsion for 10 minutes, then add 0.6 g of sodium metabisulfite, and after...

Embodiment 2

[0059] Preparation of nanocomposites:

[0060] (1) Weigh 6g of microcrystalline cellulose and add it to 60mL of sulfuric acid solution with a mass fraction of 68%, stir at room temperature for 20min at 200r / min, heat, and keep stirring for 2h after the temperature rises to 45°C;

[0061] (2) Take out the precipitate and add 60mL of deionized water to the precipitate, centrifuge at 4000r / min for 5min, and repeat the centrifugation until the supernatant becomes turbid;

[0062] (3) Put the precipitate and nano-silicon carbide into the dialysis bag according to the mass ratio of 2:1 and dialyze until the pH of the system is 7, and finally move the dialyzed product into a high-pressure homogenizer for high-pressure homogenization treatment. The pressure is 80MPa, and the number of cycles is 5 times to obtain a nanocomposite material.

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Abstract

The invention discloses a vehicle paint film based on a nanometer composite material. The vehicle paint film is prepared from, by weight, 55 to 65 parts of modified acrylic emulsion, 7 to 10 parts ofthe nanometer composite material, 3 to 4 parts of carnauba wax, 2 to 3 parts of a wetting and dispersing agent, 0.8 to 1 part of a defoaming agent, 0.6 to 0.9 part of a thickening agent, and 30 to 40parts of deionized water. The invention also discloses a preparation method of the vehicle paint film. According to the preparation method, water-soluble modified acrylic emulsion is taken as a paintfilm base body, deionized water is taken as a solvent, VOC content is low, and environment protection requirements are satisfied; and in addition, the modified acrylic emulsion is capable of providingthe paint film with excellent water resistance, and salt spray resistance; the nanometer composite material is capable of increasing the hardness and the adhesion force of the paint film greatly; theobtained vehicle paint film possesses water resistance, salt spray resistance, wear resistance, is capable of protecting vehicle paint effectively, is low in VOC content, is capable of reducing environment pollution degree, no organic solvent residue is left, and vehicle paint environment protection requirements are satisfied.

Description

technical field [0001] The invention belongs to the technical field of car paint films, and in particular relates to a car paint film based on nanocomposite materials and a preparation method thereof. Background technique [0002] Car paint is the paint that is sprayed on the car. Car paint can not only protect, but also decorate. The outer layer of modern car paint is also called transparent paint layer, which is only 0.05mm thick. It has a beautiful luster and can form a protective layer on the surface of the car body, making the car paint The layer is not easy to be corroded, scratched, which can prolong the service life of the car body. Because the car has been exposed to wind and rain all year round, extremely high requirements are put forward for the performance of the car paint film as a car paint protection film. It not only needs to have good mechanical properties, good fullness, high gloss, but also its attached Higher requirements are put forward for strength, h...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D151/00C09D7/65C09D7/61C09D7/20C08F265/06C08F220/24C08F220/18C08F220/14C08F220/06C08F220/36
CPCC08F265/06C08K2201/011C09D151/003C09D7/20C09D7/61C09D7/65C08L91/06C08L1/04C08K3/34C08F220/1804
Inventor 魏依依高碧香
Owner 山东亿隆薄膜材料有限责任公司
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