SiCf/SiC composite material flame tube and automatic preparation method thereof

A composite material, flame tube technology, applied in chemical instruments and methods, combustion methods, metal material coating processes, etc., can solve the problems of long construction period, high cost, uncontrollable quality, etc. Improved thermal shock resistance and controllability

Active Publication Date: 2019-10-15
CENT SOUTH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] Existing silicon carbide fiber reinforced ceramic matrix (SiC f /SiC) composites have excellent performance and are the first choice to replace superalloys as materials for the hot end components of aero-engines. However, the stress in the service environment will promote the cracking of the composite material matrix, accelerate the damage and corrosion of the material, and affect its performance. The requirement of long service life in high temperature gas environment seriously restricts SiC f /SiC composite material in the application of engine combustion chamber flame tube; for example, the patent of US20120076927A1 provides a method to improve the mechanical properties of fiber-reinforced silicon-carbon composite materials. In the patent, the fiber interface coating is improved by controlling the heat treatment of composite materials. layer and ceramic matrix, and can remove excess silicon in the phase matrix, but the patent has very strict restrictions on treatment time-temperature-environmental conditions, heat treatment even reaches a treatment temperature of 1900 ° C, in vacuum or at a purity greater than 99% In an inert gas environment, the processing time is as long as 100 hours. In addition, the CVI process is used to prepare the ceramic matrix. Although the free silicon can be effectively controlled, the high density of the material cannot be guaranteed, which is not conducive to the application in the market. Therefore, the development of a low-cost Cost-effective preparation of high-performa...

Method used

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  • SiCf/SiC composite material flame tube and automatic preparation method thereof
  • SiCf/SiC composite material flame tube and automatic preparation method thereof
  • SiCf/SiC composite material flame tube and automatic preparation method thereof

Examples

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Embodiment 1

[0054] This embodiment provides a SiC f The automatic preparation method of / SiC composite material flame cylinder is characterized in that, comprises the steps:

[0055] 1) Place the SiC fiber in a resistance furnace at the corresponding chemical vapor deposition temperature of the PyC interface layer, use methane as the precursor, hydrogen as the reaction gas, and argon as the dilution gas, and introduce the gas into the chemical vapor deposition furnace by bubbling method In the process, the deposition temperature is 500°C, the deposition pressure is 12KPa, the deposition time is 600min, and the thickness of the deposited interface layer is 100nm; after cooling in the furnace, SiC fibers with a continuous PyC interface layer are obtained;

[0056] 2) According to the fiber volume and fiber direction obtained by the simulation calculation, the SiC fiber with a continuous interface layer obtained in step 1) is placed in a unidirectional tape and wound into shape, including th...

Embodiment 2

[0069] This embodiment provides a SiC f The automatic preparation method of / SiC composite material flame cylinder is characterized in that, comprises the steps:

[0070] 1) Place the SiC fiber in a resistance furnace at the corresponding chemical vapor deposition temperature of the PyC interface layer, use methane as the precursor, hydrogen as the reaction gas, and argon as the dilution gas, and introduce the gas into the chemical vapor deposition furnace by bubbling method In the process, the deposition temperature is 1400°C, the deposition pressure is 0.5KPa, the deposition time is 60min, and the thickness of the deposited interface layer is 2um; after cooling in the furnace, SiC fibers with a continuous interface layer are obtained;

[0071] 2) According to the fiber volume and fiber direction obtained by the simulation calculation, the SiC fiber with a continuous interface layer obtained in step 1) is placed in a unidirectional tape and wound into shape, including the fol...

Embodiment 3

[0084] This embodiment provides a SiC f The automatic preparation method of / SiC composite material flame cylinder is characterized in that, comprises the steps:

[0085] 1) Place the SiC fiber in a resistance furnace at the corresponding chemical vapor deposition temperature of the PyC interface layer, use methane as the precursor, hydrogen as the reaction gas, and argon as the dilution gas, and introduce the gas into the chemical vapor deposition furnace by bubbling method In the process, the deposition temperature is 1000°C, the deposition pressure is 8KPa, the deposition time is 300min, and the thickness of the deposited interface layer is 1um; after cooling in the furnace, SiC fibers with a continuous interface layer are obtained;

[0086] 2) According to the fiber volume and fiber direction obtained by the simulation calculation, the SiC fiber with a continuous interface layer obtained in step 1) is placed in a unidirectional tape and wound into shape, including the foll...

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Abstract

The invention discloses an automatic preparation method of a SiCf/SiC composite material flame tube. The preparation method comprises the following steps: preparing an interface layer from SiC fibersby adopting chemical vapor deposition, so as to obtain SiC fibers with a continuous interface layer; performing unidirectional tape laying and filament winding on the SiC fibers with the continuous interface layer according to the fiber volume and fiber orientation obtained by simulation calculation, so as to obtain net size forming preform; performing densifying treatment on the obtained preformby adopting a reactive melt infiltration process and the chemical vapor deposition process; preparing an environmental barrier coating on the surface of the obtained preform; finally, continuously preparing a thermal barrier coating on the surface, thereby fully intelligently obtaining the high-density SiCf/SiC composite material flame tube. The SiCf/SiC composite material flame tube prepared withthe method disclosed by the invention has the characteristics of high temperature resistance and long service life and also has the advantages such as low thermal expansion coefficient, high thermalconductivity, high thermal shock resistance and excellent mechanical property. Meanwhile, the preparation method is high in degree of automation, short in production cycle, low in cost and controllable in quality.

Description

technical field [0001] The invention relates to the technical field of aviation structural materials, in particular to a SiC f / SiC composite material flame cylinder and its automatic preparation method. Background technique [0002] The combustion chamber is one of the core components of an aero-engine. Its main function is to convert the chemical energy of the fuel into heat energy through combustion, so as to improve the ability of the gas to expand in the turbine and nozzle. In the structural composition of the combustion chamber, the flame tube is The place where the combustion is organized is a key component to ensure air splitting, sufficient combustion, uniform mixing and effective cooling of the wall. The reliability, economy and life of the combustion chamber depend to a large extent on the reliability and reliability of the flame tube. Therefore, the development of a high-performance and long-life combustor flame cylinder plays a vital role in improving engine pe...

Claims

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Application Information

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IPC IPC(8): C04B35/80C04B35/573C04B35/622C04B35/626C04B41/89
CPCC04B35/573C04B35/622C04B35/62605C04B41/89C04B41/52C04B2235/96C04B2235/9607C04B41/5024C04B41/4533C04B41/5031C04B41/5027C04B41/50C04B2235/614C04B41/009C04B2235/5244C04B35/62884C04B2235/5268C04B35/80C04B2235/94C04B35/62873C04B35/62863C04B35/6286C04B35/62868C04B35/62871C04B35/62897C04B2235/445C04B2235/3409C04B2235/3244C04B2235/3251C04B2235/3418C04B35/6269C04B2235/404B32B18/00C04B2237/38C04B2237/365C04B35/62894C04B2235/9684C04B2235/77F23R3/007F23R2900/00018C23C16/045C23C16/32C23C16/325C23C16/345C23C16/342C23C16/26C04B35/565C04B41/5096C04B41/4527C04B2103/0021C04B41/5042C04B41/5045C04B41/522C04B35/62281C04B41/4505C04B41/4523C04B41/4531C04B41/455C04B41/4584C04B41/4933F23R3/42
Inventor 阳海棠郭小军黄小忠
Owner CENT SOUTH UNIV
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