Super-hydrophobic modified hydrogenated butadiene-acrylonitrile rubber magnetic composite material and preparation method thereof

A technology of hydrogenated nitrile butadiene rubber and magnetic composite materials, which is applied in the field of superhydrophobic modified hydrogenated nitrile butadiene rubber magnetic composite materials and its preparation method, and can solve the problems of easy wear and tear, poor hydrophobic performance, and wear resistance of hydrogenated nitrile butadiene rubber The performance is not high, to achieve the effect of strong oxidation resistance, good elastic modulus and tensile properties, and broaden the scope of use

Inactive Publication Date: 2020-03-06
黄春美
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Aiming at the deficiencies in the prior art, the invention provides a superhydrophobic modified hydrogenated nitrile butadiene rubber magnetic composite material and its preparation method, which solves the problem of poor hydrophobicity of the

Method used

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preparation example Construction

[0028] nano-SiO 2 The composite material is Al-Fe layered double hydroxide-modified SiO 2Composite material, preparation method comprises the following steps:

[0029] (1) Add an appropriate amount of ethanol solvent to the reaction bottle, and then add nano-SiO 2 and tridecafluorooctyltriethoxysilane, the molar ratio of the two substances is 8-10:1, the solution is placed in a constant temperature water bath, heated to 80-90 ℃, stirred and refluxed at a constant speed for 15-20 h , the solution was cooled to room temperature, concentrated under reduced pressure to remove the solvent, the solid product was washed with an appropriate amount of ethanol solvent, and fully dried to prepare modified nano-SiO 2 .

[0030] (2) Add an appropriate amount of sodium carbonate solution with a mass fraction of 5-8% into the reaction bottle, and add FeCl while stirring 3 and AlCl 3 After stirring and dissolving, add the modified nano-SiO 2 , the mass ratio of the three is 2.4-2.6:1:70...

Embodiment 1

[0038] (1) Preparation of modified nano-SiO 2 Component 1: Add an appropriate amount of ethanol solvent to the reaction flask, and then add nano-SiO 2 and tridecafluorooctyltriethoxysilane, the molar ratio of the two substances is 8:1, the solution is placed in a constant temperature water bath, heated to 80°C, stirred and refluxed at a constant speed for 15 hours, and the solution is cooled to room temperature , concentrated under reduced pressure to remove the solvent, washed the solid product with an appropriate amount of ethanol solvent, and fully dried to prepare modified nano-SiO 2 Component 1.

[0039] (2) Preparation of nano-SiO 2 Composite material 1: Add an appropriate amount of sodium carbonate solution with a mass fraction of 5% to the reaction bottle, and add FeCl while stirring 3 and AlCl 3 After stirring and dissolving, add the modified nano-SiO 2 Component 1, the mass ratio of the three is 2.4:1:70, then add sodium hydroxide, adjust the pH of the solution ...

Embodiment 2

[0044] (1) Preparation of modified nano-SiO 2 Component 2: Add an appropriate amount of ethanol solvent to the reaction flask, and then add nano-SiO 2 and tridecafluorooctyltriethoxysilane, the molar ratio of the two substances is 10:1, the solution is placed in a constant temperature water bath, heated to 90°C, stirred and refluxed at a constant speed for 15 hours, and the solution is cooled to room temperature , concentrated under reduced pressure to remove the solvent, washed the solid product with an appropriate amount of ethanol solvent, and fully dried to prepare modified nano-SiO 2 Component 2.

[0045] (2) Preparation of nano-SiO 2 Composite material 2: Add an appropriate amount of sodium carbonate solution with a mass fraction of 5% to the reaction bottle, and add FeCl while stirring 3 and AlCl 3 After stirring and dissolving, add the modified nano-SiO 2 Component 2, the mass ratio of the three is 2.4:1:75, then add sodium hydroxide, adjust the pH of the solution...

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Abstract

The invention relates to the technical field of super-hydrophobic magnetic rubber materials and discloses a super-hydrophobic modified hydrogenated butadiene-acrylonitrile rubber magnetic composite material and a preparation method thereof. A formula for the material comprises the following raw materials: hydrogenated butadiene-acrylonitrile rubber, graphene oxide, a SiO2 nanocomposite material, amodified ferrite nanocomposite material, a plasticizer, an activating agent, an accelerant, an anti-aging agent, a reinforcing agent--carbon black and a vulcanizing agent--sublimed sulfur. Accordingto the invention, nanometer SiO2 is uniformly loaded into an Al-Fe double-metal hydroxide layered structure, so the agglomeration and caking of the nanometer SiO2 are avoided, and the anti-ageing performance of the rubber material is improved; the ferrite composite material with strong magnetism enhances the damping performance and the magnetic performance of the rubber material; and the tridecafluorooctyltriethoxysilane modified SiO2 and an isopropyldioleoylacyloxy(dioctyl phosphate acyloxy)titanate modified ferrite composite material enhance the hydrophobic performance of the rubber material.

Description

technical field [0001] The invention relates to the technical field of superhydrophobic magnetic rubber materials, in particular to a superhydrophobic modified hydrogenated nitrile rubber magnetic composite material and a preparation method thereof. Background technique [0002] Rubber is a highly elastic polymer material with reversible deformation. It is elastic at room temperature, can produce large deformation under a small external force, and can restore its original shape after the external force is removed. Rubber belongs to completely amorphous polymerization. It has a low glass transition temperature and a large molecular weight. Rubber materials are mainly divided into nitrile rubber, silicone rubber, fluorine rubber, polysulfide rubber, and polyurethane rubber. Rubber materials are widely used in transportation, agriculture, forestry, water conservancy, military and national defense. , civil engineering, electrical communication and other fields have a wide range ...

Claims

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Application Information

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IPC IPC(8): C08L15/00C08K13/06C08K3/04C08K3/36C08K3/22C08K5/12C08K9/06C08K7/00C08K9/04C08K9/12
CPCC08K3/22C08K3/36C08K5/12C08K7/00C08K9/04C08K9/06C08K9/12C08K13/06C08K2201/011C08K3/042C08L15/005
Inventor 黄春美
Owner 黄春美
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