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Method for controlling corrosion under thermal insulation layer

A technology for corrosion and control methods under the insulation layer, applied in the directions of insulation, weather resistance/light resistance/corrosion resistance, coating, etc.

Active Publication Date: 2020-04-28
SUZHOU NUCLEAR POWER RES INST +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In the prior art, there are two ways to solve the problem of corrosion under the insulation layer: one is to improve the performance of the insulation layer, such as selecting insulation materials with low water content and fast drying, to enhance the performance of the protective layer to prevent moisture from entering Insulation layer, but there is no insulation layer that can completely isolate moisture in practical applications. At the same time, due to design defects or insulation installation and maintenance problems, moisture directly enters the insulation layer
The second is to apply ordinary anti-corrosion coatings on the metal surface, but due to the performance factors of the coating itself, such as the thermal expansion coefficient is different from that of the metal, the thermal cycle will often lead to an increase in the internal stress of the coating, which will eventually cause early failure of the coating. It cannot effectively solve the corrosion problem under the insulation layer

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  • Method for controlling corrosion under thermal insulation layer
  • Method for controlling corrosion under thermal insulation layer
  • Method for controlling corrosion under thermal insulation layer

Examples

Experimental program
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Effect test

Embodiment 1

[0071] Embodiment 1 Corrosion control method under insulation layer

[0072] The corrosion control method under the insulation layer in the present embodiment comprises the following steps:

[0073] 1) Preparation of paint: The thermal conductivity of the coating formed by the paint must be less than or equal to 0.05 [W / (m.K)], the decontamination rate of the coating formed by the paint is greater than 95.0%, and the contamination sensitivity rate is greater than 4.5%.

[0074] 2) coating coating: the coating prepared in step 1) is coated on the pipeline and the equipment surface, and the coating is formed after the coating dries, and the insulation layer is installed on the coating surface, and the insulation layer adopts the existing insulation layer, such as Glass wool, airgel blanket, etc.; in step 2), the paint is directly coated on the surface of the pipeline and equipment by scraping or mold fixing. The single curing thickness of the mold is greater than 15mm, and the t...

Embodiment 2

[0082] Example 2 Flame retardant containing cyclic phosphate ester phenolic derivatives and its preparation

[0083] The flame retardant containing cyclic phosphoric ester phenolic derivatives in this embodiment is a phosphorus-ring low-molecular-weight novolac resin derivative modified with phenyl phosphate dichloride as a phosphorus source, and its structural formula is as follows:

[0084]

[0085] Wherein, n is a positive integer greater than 0.

[0086] The preparation method of this cyclic phosphate-containing phenolic derivative flame retardant comprises the steps of: getting 100 parts of low molecular weight linear p-tert-butylphenolic resin, 120 parts of chlorobenzene, and 35 parts of potassium hydroxide in a closed reaction kettle, Disperse at high speed for 10 minutes under ice bath and nitrogen protection, and it becomes a paste; prepare 70 parts of phenyl phosphate dichloride and add it to 200 parts of chlorobenzene to disperse evenly, and add it to the above r...

Embodiment 3

[0098] The flame-retardant thermal insulation coating suitable for nuclear power irradiation environment in this embodiment includes a first component and a second component, and the mass ratio of the first component to the second component is 4:1.

[0099] Among them, the first component includes the following raw materials in parts by weight: 100 parts of mixed phenolic resin, 8 parts of flame retardant containing cyclic phosphate ester phenolic derivatives, 20 parts of resin toughening agent, 22 parts of reactive diluent, inorganic low thermal conductivity 100 parts of filler, 9 parts of surface treatment agent.

[0100] In the first component: the mixed phenolic resin includes 20 parts of phenolic resin, 80 parts of novolac epoxy resin; the resin toughening agent is epoxy-terminated liquid nitrile rubber; the reactive diluent is 8 parts of benzyl glycidyl ether and 12 parts Neopentyl glycol diglycidyl ether; In the first component, the inorganic thermally conductive filler...

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Abstract

The invention provides a method for controlling corrosion under a thermal insulation layer. The method includes the following steps: 1) preparing paint, wherein the thermal conductivity of a coating formed by the paint needs to be smaller than or equal to 0.05 [W / (m.K)], the decontamination rate of the coating formed by the paint is larger than 95.0%, and the contamination sensitivity rate is larger than 4.5%; 2) applying the paint, wherein the paint is applied to the surfaces of pipelines and equipment, the coating is formed after the paint is dried, and the thermal insulation layer is installed on the surface of the coating; 3) installing a corrosion monitoring device, wherein the corrosion monitoring device comprises metal coupling electrodes, a signal transmitter and an indicator, andthe metal coupling electrodes are installed on the surface of a metal substrate, in the coating and in the thermal insulation layer in the construction process; and 4) performing corrosion monitoring,wherein current signals of the metal coupling electrodes are transmitted to the signal transmitter, the signal transmitter receives the current signals and amplifies the current signals, and the indicator is driven to display the current signals. The method for controlling corrosion under the thermal insulation layer can provide an effective basis for the strategy of maintenance under the thermalinsulation layer, and the purpose of controlling corrosion of the metal substrate is achieved.

Description

technical field [0001] The invention relates to the technical field of corrosion and protection of pipeline equipment in nuclear power plants, in particular to a method for controlling corrosion under insulation layers suitable for nuclear power plant environments. Background technique [0002] Corrosion under insulation (CUI, corrosion under insulation) refers to a corrosion phenomenon that occurs on the outer surface of pipes or equipment with insulation materials applied. Insulation materials usually have a loose and porous structure with a large specific surface area, so they have a strong water absorption capacity. Due to insulation design defects, mechanical damage, maintenance problems, etc., water vapor will gradually enter the insulation layer. Most insulation materials are inorganic substances, which contain a large amount of chloride, fluoride, sulfide, etc., which will promote metal corrosion. [0003] In the prior art, there are two ways to solve the problem of...

Claims

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Application Information

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IPC IPC(8): F16L58/04F16L57/04F16L59/02C09D163/04C09D161/06C09D5/18C09D7/65C09D7/62G01N17/00
CPCF16L58/04F16L57/04F16L59/028C09D163/04C09D5/18C09D7/65C09D7/62C09D7/70G01N17/00C08K2003/2241C08L61/06C08K9/06C08K7/26C08K7/28C08K3/22C08K13/06
Inventor 梁耀升刘晓伟金哲
Owner SUZHOU NUCLEAR POWER RES INST