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A carbonyl composite carbon source biological carbon supplement and preparation method thereof

A composite carbon source, biological technology, applied in chemical instruments and methods, biological water/sewage treatment, water pollutants, etc. The problem of poor effluent quality, etc., achieves good economic and social benefits, short domestication period, and no waste water and exhaust emissions.

Active Publication Date: 2021-01-05
北京环球中科水务科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Glucose is generally used as an ideal carbon replenishing agent, which is easy for microorganisms to absorb, but the control of the dosing position and dosage is relatively strict. If the control is not done properly, it will easily cause filamentous bacteria to multiply, cause sludge swelling, and degrade the quality of the effluent from the sedimentation tank; Organic acid salt carbon supplements can be roughly divided into low-molecular straight-chain organic acid salts and aromatic benzene-ring organic acid salts. Low-molecular-weight direct-chain organic acid salts are conducive to microbial absorption, while aromatic benzene-ring organic acid salts are hardly directly absorbed by microorganisms. use, and organic acid salt carbon supplements are likely to cause changes in pH and salinity, and the dosage will be greatly limited; alcohol carbon supplements are generally ethanol or methanol, which are dangerous chemicals and have special effects during use and management. Great limitations; although the by-products of chemical production enterprises are cheap, their components are complex and unstable. Harmful and toxic substances are likely to cause fatal harm to the sewage treatment system and cause the entire biological system to collapse.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] This example is used to illustrate the preparation of the carbonyl complex carbon source biological carbon supplement of the present invention.

[0033] 1. Raw materials

[0034] 1. Starch liquefaction pulp: starch liquefaction pulp with a mass fraction of 30% to 35%, purchased from Xiwang Group Co., Ltd.;

[0035] 2. Acetic acid solution: the mass fraction is 42wt%;

[0036] 3. Methanol solution: the volume fraction is 95%;

[0037] 4. Saccharification catalyzing enzyme: a commercially available product, which can be purchased from Shanghai Macklin Biochemical Technology Co., Ltd. as the product "Amyloglucosidase".

[0038] Two, the preparation method of biological carbon supplement

[0039] (1) to 5m 3 Add 2.8m into the reactor 3 The above-mentioned starch liquefaction slurry, start the mixer, add acetic acid solution, make the pH value of the starch liquefaction slurry about 4.5, and complete the deployment of the starch liquefaction slurry.

[0040] (2) Turn o...

experiment example 1

[0043] A sewage treatment plant in Ningxia, with a wastewater treatment capacity of 10,000 m 3 / day, pH=6.5~7.2, COD of sewage plant influent is 360mg / L~410mg / L. The total nitrogen fluctuates greatly, the lowest value is 39.8mg / L, the highest value is 110.5mg / L, ammonia nitrogen is 16mg / L~56mg / L, and the designed effluent is Class A discharge.

[0044] The AAO treatment process is adopted in the biological treatment section of the sewage treatment plant, and the radial flow sedimentation tank is used in the latter section.

[0045] The original design of the system is to add food-grade glucose: when the total nitrogen of the effluent exceeds 15mg / L, glucose is added, and the dosage is added in proportion to the detection value of total nitrogen, and 900kg-1300kg of food-grade glucose is added every day. The total nitrogen reached the standard on the third day after the addition. However, with the fluctuation of total nitrogen, the total nitrogen of the effluent exceeded the s...

experiment example 2

[0048] A sewage treatment plant in Hebei, with a wastewater treatment capacity of 20,000 m 3 / day, using the SBR+biological aerated filter process, the pH of the raw water is 6.4~6.9, and the average value of COD in the wastewater treatment plant is 395mg / L. The average value of total nitrogen is 78mg / L, the average value of ammonia nitrogen is 37mg / L, and the effluent is designed to be discharged at the first level A.

[0049] The operation of the sewage plant is stable in summer, and the total nitrogen and ammonia nitrogen exceed the standard intermittently in winter, and it operates in winter.

[0050] The original process uses sodium acetate, a by-product of chemical enterprises, as a supplementary carbon source: the dosage is 2.6 tons per day, and 16 hours after the addition, it can be seen that the total nitrogen in the water drops, but as the addition time increases, the pH of the effluent drops further. , the lowest pH value is 5.8, and the total phosphorus effluent i...

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PUM

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Abstract

The invention relates to the technical field of sewage treatment. The invention particularly discloses a carbonyl composite carbon source biological carbon supplementing agent and a preparation methodthereof. The biological carbon supplementing agent is prepared by taking starch liquefied slurry as a raw material, adding an organic acid, controlling a reasonable pH value, converting starch into acarbonyl intermediate product under the action of a saccharification catalytic enzyme, then adding the organic acid and alcohol, and controlling the temperature so as to generate a carbonyl compoundbeneficial to the growth of microorganisms. The product not only ensures the functional requirements of the carbon supplementing agent, but also does not introduce salt and other harmful ions, and meanwhile, the starch is used as a renewable resource, so that the raw materials are rich in source and low in price. The biological carbon supplementing agent provided by the invention can be widely applied to the field of sewage pretreatment, enhances the microbial activity, promotes the microbial denitrification reaction, and particularly has the obvious advantages of small dosage, short microbialadaptation period and easiness in management and use under the condition of lower water temperature in winter.

Description

technical field [0001] The invention relates to the technical field of sewage treatment, in particular to a biological carbon supplement for promoting biological denitrification. Background technique [0002] As the country attaches great importance to the ecological environment, especially the management of ecological river basins, the quality of water discharged into the water environment is strictly controlled, and the standards are gradually improved. China's current sewage treatment plant (station) discharge standard implements the national standard GB 18918-2002 pollutant discharge standard for urban sewage plants. The maximum allowable value of total nitrogen in the first grade A of this discharge standard is 15mg / L, and ammonia nitrogen is 8mg / L; much higher than In the surface water environment index standard, the water quality of Class V should be lower than 2.0mg / L. A large amount of high-nitrogen wastewater will be discharged into the water body, causing a large ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F3/30C02F101/16
CPCC02F3/302C02F2101/16
Inventor 武仁超虞红波徐绪筝李科吉
Owner 北京环球中科水务科技股份有限公司
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