A carbonyl composite carbon source biological carbon supplement and preparation method thereof
A composite carbon source, biological technology, applied in chemical instruments and methods, biological water/sewage treatment, water pollutants, etc. The problem of poor effluent quality, etc., achieves good economic and social benefits, short domestication period, and no waste water and exhaust emissions.
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Embodiment 1
[0032] This example is used to illustrate the preparation of the carbonyl complex carbon source biological carbon supplement of the present invention.
[0033] 1. Raw materials
[0034] 1. Starch liquefaction pulp: starch liquefaction pulp with a mass fraction of 30% to 35%, purchased from Xiwang Group Co., Ltd.;
[0035] 2. Acetic acid solution: the mass fraction is 42wt%;
[0036] 3. Methanol solution: the volume fraction is 95%;
[0037] 4. Saccharification catalyzing enzyme: a commercially available product, which can be purchased from Shanghai Macklin Biochemical Technology Co., Ltd. as the product "Amyloglucosidase".
[0038] Two, the preparation method of biological carbon supplement
[0039] (1) to 5m 3 Add 2.8m into the reactor 3 The above-mentioned starch liquefaction slurry, start the mixer, add acetic acid solution, make the pH value of the starch liquefaction slurry about 4.5, and complete the deployment of the starch liquefaction slurry.
[0040] (2) Turn o...
experiment example 1
[0043] A sewage treatment plant in Ningxia, with a wastewater treatment capacity of 10,000 m 3 / day, pH=6.5~7.2, COD of sewage plant influent is 360mg / L~410mg / L. The total nitrogen fluctuates greatly, the lowest value is 39.8mg / L, the highest value is 110.5mg / L, ammonia nitrogen is 16mg / L~56mg / L, and the designed effluent is Class A discharge.
[0044] The AAO treatment process is adopted in the biological treatment section of the sewage treatment plant, and the radial flow sedimentation tank is used in the latter section.
[0045] The original design of the system is to add food-grade glucose: when the total nitrogen of the effluent exceeds 15mg / L, glucose is added, and the dosage is added in proportion to the detection value of total nitrogen, and 900kg-1300kg of food-grade glucose is added every day. The total nitrogen reached the standard on the third day after the addition. However, with the fluctuation of total nitrogen, the total nitrogen of the effluent exceeded the s...
experiment example 2
[0048] A sewage treatment plant in Hebei, with a wastewater treatment capacity of 20,000 m 3 / day, using the SBR+biological aerated filter process, the pH of the raw water is 6.4~6.9, and the average value of COD in the wastewater treatment plant is 395mg / L. The average value of total nitrogen is 78mg / L, the average value of ammonia nitrogen is 37mg / L, and the effluent is designed to be discharged at the first level A.
[0049] The operation of the sewage plant is stable in summer, and the total nitrogen and ammonia nitrogen exceed the standard intermittently in winter, and it operates in winter.
[0050] The original process uses sodium acetate, a by-product of chemical enterprises, as a supplementary carbon source: the dosage is 2.6 tons per day, and 16 hours after the addition, it can be seen that the total nitrogen in the water drops, but as the addition time increases, the pH of the effluent drops further. , the lowest pH value is 5.8, and the total phosphorus effluent i...
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