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Solvent type spraying photocuring antibacterial coating as well as preparation method and application thereof

An antibacterial coating and photocuring technology, which is applied in epoxy resin coatings, antifouling/underwater coatings, polyurea/polyurethane coatings, etc., can solve the problems of antibacterial effect failure and achieve synergistic, effective and durable antibacterial effects , the effect of improving compatibility

Pending Publication Date: 2020-10-02
邦弗特(东莞)新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This method of physical addition imparts antibacterial properties to the coating with a certain timeliness. As time goes by, it dissolves and wears out on the surface of the coating, and the antibacterial effect gradually fails.

Method used

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  • Solvent type spraying photocuring antibacterial coating as well as preparation method and application thereof
  • Solvent type spraying photocuring antibacterial coating as well as preparation method and application thereof

Examples

Experimental program
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Effect test

preparation example Construction

[0045] The raw materials for the preparation of the prepolymer I, in parts by weight, include: 12.9-15.4 parts of choline chloride, 18.9-25.9 parts of diisocyanate, 0.06-0.1 part of the second catalyst, and 33-41 parts of diluent; Diisocyanate is selected from at least one of isophorone diisocyanate, dicyclohexylmethane diisocyanate, toluene diisocyanate, hexamethylene diisocyanate, diphenylmethane diisocyanate; the second catalyst is selected from organic bismuth , one or more of organotin, organozinc, potassium iodide; the diluent is an acrylate reactive diluent; more preferably, the acrylate reactive diluent is selected from 1,6-hexanediol diacrylate , tripropylene glycol diacrylate, neopentyl glycol diacrylate, 1,4-butanediol diacrylate, trimethylolpropane triacrylate, pentaerythritol tetraacrylate, ethoxylated trimethylolpropane triacrylate One or more of acrylates.

[0046] The preparation method of the prepolymer I comprises the following steps: adding choline chloride...

Embodiment 1

[0115] Embodiment 1 provides a kind of solvent-based spraying light-curing antibacterial coating, the preparation raw material of described antibacterial coating, by weight percentage, comprises following component: 10% butyl acetate, 20% ethyl acetate, 6% bis-trisulfite Propylene Glycol Diacrylate, 12% Trimethylolpropane Triacrylate, 20% Urethane Acrylate, 15% Epoxy Acrylate, 12% Photocurable Antimicrobial Resin, 2.5% Initiator, 0.3% Leveling Agent, 2.2% Propylene Glycol Methyl ether acetate.

[0116] The urethane acrylate is selected from allnex group EBECRYL 246; the epoxy acrylate is selected from Changxing Chemical 621A-80; the photoinitiator is selected from BASF photoinitiator Irgacure 184; the leveling agent is selected from From BYK-333 leveling agent;

[0117] The preparation raw material of described photocurable antibacterial resin comprises: 56.7g prepolymer I, 89.4g prepolymer II, 104.2g hydroxyl-terminated polydimethylsiloxane (the number average molecular weig...

Embodiment 2

[0126] The difference between embodiment 2 and embodiment 1 is that the preparation raw material of described antibacterial paint, by weight percentage, comprises following component: 10% butyl acetate, 20% ethyl acetate, 6% tripropylene glycol diacrylate , 10% trimethylolpropane triacrylate, 19% urethane acrylate, 15% epoxy acrylate, 18% photocurable antibacterial resin, 2.5% initiator, 0.3% leveling agent, 2.2% propylene glycol methyl ether acetate .

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Abstract

The invention relates to the technical field of photocureable coating, in particular to solvent type spraying photocuring antibacterial coating as well as a preparation method and application thereof.The invention discloses the solvent type spraying photocuring antibacterial coating. The preparation raw materials of the antibacterial coating at least comprise the following components in percentage by weight: 15-25% of urethane acrylate, 10-20% of epoxy acrylate, 5-20% of light-cured antibacterial resin, 15-25% of an active monomer, 25-40% of a solvent, 1-5% of an initiator and 0.1-0.5% of anassistant. According to the coating, by adjusting the ratio of the raw materials, the compatibility and the synergistic effect between systems are improved, the spraying process requirements of the solvent type photocuring coating are met, consumer electronic products such as mobile phones, laptops and household appliances are coated with the solvent type photocuring coating in a spraying mode, surface decoration and protection are conducted, and the excellent and lasting antibacterial effect is achieved.

Description

technical field [0001] The invention relates to the technical field of light-curing coatings, in particular to a solvent-based spraying light-curing antibacterial coating and its preparation method and application. Background technique [0002] For a long time, pathogens such as bacteria and molds have caused great harm to the health of humans or animals, and can also cause decomposition and damage of materials and deterioration of food, resulting in great health and economic losses. Therefore, how to reduce or even avoid the harm of bacteria and other pathogens to the environment and human body has become a problem that people have always hoped to solve. application. Photocurable coatings have the characteristics of 5E, namely Efficient (high efficiency), Enabling (wide application), Economical (economical), Energy saying (energy saving), Environmental-friendly (environmental friendly). At present, UV-curable coatings have been widely used in fields closely related to lif...

Claims

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Application Information

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IPC IPC(8): C09D175/14C09D163/10C09D5/14B05D7/24B05D5/00B05D1/02
CPCC09D175/14C09D5/14B05D7/24B05D5/00B05D1/02C08L2205/025C08L2205/03
Inventor 谢佳武张冬明李新雄毛斌
Owner 邦弗特(东莞)新材料有限公司
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