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High-tension main grid silver paste applied to N-type solar cell and preparation method thereof

A technology of solar cells and high tensile force, which is applied in the direction of cable/conductor manufacturing, conductive materials dispersed in non-conductive inorganic materials, circuits, etc., and can solve the problem of connection strength between over-welding ribbon and main grid, deformation of battery sheets, and increase in series connection Resistance and other problems, to achieve high photoelectric conversion efficiency, strong welding tension, good adhesion

Active Publication Date: 2020-10-30
NANTONG T SUN NEW ENERGY CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Factors that affect the welding quality of busbar and ribbon mainly include silver paste of busbar, welding temperature and time, ribbon, flux, welding pressure of manual operation and return temperature speed of welding equipment, etc. Due to personnel and environmental influences, problems such as virtual soldering, over-soldering, and poor connection strength between the ribbon and the main grid occur
False welding will increase the series resistance of the module and reduce the current output efficiency of the module; over-welding will cause deformation and cracks of the cell

Method used

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  • High-tension main grid silver paste applied to N-type solar cell and preparation method thereof
  • High-tension main grid silver paste applied to N-type solar cell and preparation method thereof
  • High-tension main grid silver paste applied to N-type solar cell and preparation method thereof

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preparation example Construction

[0048] According to above-mentioned formula, a kind of preparation method of the high tension busbar silver paste that is applied to N-type solar cell of the present invention comprises the following steps:

[0049] Step 1: Accurately weigh the weight of each component with an analytical balance, add the organic carrier and glass powder into a centrifuge tube and mix evenly, then put the centrifuge tube into a centrifuge and centrifuge for 1-3 times to prepare a glass slurry. The rotational speed of the centrifuge is 800-1200rmp, and the centrifugation time is 3-7min. Firstly, the glass slurry is prepared to realize the dispersion of the nanometer system, so that the dispersion of the system is more uniform.

[0050] Step 2: Put the glass paste prepared in Step 1 into a three-roll machine for three-roll grinding treatment. The distance between the rolls of the three-roll machine is 5-40 μm, and the speed of the three-roll machine is 100-200 rpm. There are three rollers in the ...

Embodiment 1

[0055] A kind of high-tensile busbar silver paste applied to N-type solar cells of the present invention comprises the following components:

[0056] 87.5wt% silver powder: the weight ratio of spherical silver powder A to spherical silver powder B is 7:3, the median particle size of spherical silver powder A is 800nm, the tap density is 5.5g / mL, and the median particle size of spherical silver powder B is The diameter is 365nm, and the tap density is 4.5g / mL.

[0057] 10wt% organic vehicle: the quality of the organic vehicle is 100%, and the organic vehicle of the present invention contains 10wt% resin (polyvinyl butyral ester resin: acrylic resin: ethyl cellulose resin=3:6:1 ), 82.5wt% organic solvent (alcohol fat twelve: terpineol: tributyl citrate=20:30:32.5) and 7.5wt% organic auxiliary agent (leveling agent: thixotropic agent: defoamer= 2:2:3.5), wherein the molecular weight of polyvinyl butyral resin of the present invention is 25000, the molecular weight of acrylic res...

Embodiment 2

[0064] A kind of high-tensile busbar silver paste applied to N-type solar cells of the present invention comprises the following components:

[0065] 80wt% silver powder: wherein the weight ratio of spherical silver powder A to spherical silver powder B is 17:3, the median diameter of spherical silver powder A is 900nm, the tap density is 6g / mL, and the median diameter of spherical silver powder B is 450nm, the tap density is 5g / mL.

[0066] 15wt% organic vehicle: the quality of the organic vehicle is 100%, and the organic vehicle of the present invention contains 10wt% resin (polyvinyl butyral ester resin: acrylic resin: rosin resin=4:5:1), 85wt% % organic solvent (alcohol fat twelve: terpineol: tributyl citrate: butyl carbitol acetate=4:4:4:5) and 5wt% organic additive (leveling agent: thixotropic agent : defoamer: drier: dispersant=1:1:1:1:1), wherein the molecular weight of polyvinyl butyral ester resin of the present invention is 40000, the molecular weight of acrylic re...

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Abstract

The invention discloses high-tension main grid silver paste applied to an N-type solar cell and a preparation method thereof. The high-tension main grid silver paste applied to the N-type solar cell is prepared from silver powder (the value particle size is 700-900nm, the tap density of the spherical silver powder A is 5-6 g / mL, the median particle size of the spherical silver powder A is 280-450nm, and the tap density is a mixture of 4-5 g / mL spherical silver powder B), an organic carrier (a mixture of 3-5 wt% polyvinyl butyral ester resin and 5-10 wt% acrylic resin as main resin) and glasspowder (the median particle size is 0.7-1 [mu]m, and the copper-bismuth-manganese-tellurium series glass powder with the softening temperature of 600-800 DEG C) through mixing. The formula system canenable the silver paste to be good in adhesion with the surface of the n-type silicon wafer after sintering, enables the welding tension of the silver paste to be large, enables the welding tension ofa front main grid line to be 4N or above, is good in compactness of the paste, and is high in photoelectric conversion efficiency.

Description

technical field [0001] The invention belongs to the technical field of conductive materials containing metals or alloys, and in particular relates to a high-tension busbar silver paste applied to N-type solar cells and a preparation method thereof. Background technique [0002] Commercial crystalline silicon solar cells mainly use P-type crystalline silicon as raw material, through production lines such as texturing, diffusion, etching and edge removal, silicon nitride anti-reflection coating, printing front silver grid lines, back aluminum and back silver electrodes, etc. process to obtain P-type crystalline silicon solar cells. Among them, the P-n junction of the P-type crystalline silicon solar cell is located on the front surface of the cell, and the photogenerated carriers in the P-type base can be effectively separated by diffusion and transported to the front surface of the cell, thereby realizing photoelectric conversion. According to the International Photovoltaic ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01B1/16H01B1/22H01L31/0224H01B13/00
CPCH01B1/16H01B1/22H01L31/022425H01B13/00Y02E10/50C03C3/062C03C8/02C03C8/18C03C14/004C03C2214/08C03C4/14C03C8/16C03C2205/00H01L31/022441
Inventor 毛平张舒管玉龙杨环
Owner NANTONG T SUN NEW ENERGY CO LTD
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