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Nylon raw material of medical non-toxic dust-free 3D printing isolation eyeshade and manufacturing method of medical non-toxic dust-free 3D printing isolation eyeshade

A 3D printing and manufacturing method technology, applied in the field of medical materials, can solve problems such as toxic dioxin gas, toxic and harmful adhesives or plasticizers, and escaping dust, so as to reduce the number of infected people and the risk of medical staff, Improved performance and comfort, reliable bond strength

Inactive Publication Date: 2020-12-25
贵州森远增材制造科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, there are several pain points in the existing technology that correspond to the actual working conditions, namely: 1. If my country encounters a severe epidemic this year, plastic products need at least half a month to open the mold, and it is very likely that they cannot meet the surge in a short period of time. production needs of medical supplies
2. At present, most of the products on the market are made of plastic products (such as PE, PVC), which are generally added with plasticizer DEHP. If they are used for a long time in an environment with high humidity, they will endanger the health and safety of protectors and medical staff.
3. Add stabilizers containing metal ions, long-term use may cause metal ions to harm the patient's body
4. After use, incineration will produce toxic dioxin gas
[0004] It can meet the requirements of rapid mold opening and short-term (within two days) sprint production to meet the necessary requirements of medical isolation goggles. At present, 3D laser printing is the most mature and available method. At present, the more mature and better material performance is nylon-based 3D printing products, but it has several fatal flaws in the medical field, namely: 1. It also contains toxic and harmful adhesives or plasticizers
2. The material is polar and easy to absorb dust. At the same time, because the raw materials are mostly a variety of powders, and the sintering degree is not high, the dust itself will escape
4. After use, recycling and incineration will also produce toxic dioxin gas

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] A kind of nylon raw material for medical non-toxic and dust-free 3D printing isolation goggles. The nylon raw material is composed of two parts, which are TPE-g-MAH modified polymer 70g-72g and nylon 12 250g in parts by weight; wherein TPE-g The -MAH modified polymer is specifically based on 32g of isobutylene gas in parts by weight, and is successively subjected to terminal tertiary chlorination treatment, terminal alkenyl treatment, and block polymerization to obtain an alkenyl-terminated polyethylene butene polymer, and then Based on alkenyl-terminated polyethylene butylene polymer combined with 30g~36g of EPDM rubber and 0.45g~0.6g of maleic anhydride in parts by weight, it is finally obtained by modified polymerization;

[0022] The manufacture method of this nylon raw material comprises the following steps:

[0023] S1: Prepare nylon 12 250g, styrene 6.8g, isobutylene gas 32g, sufficient amount of dichloromethane, sufficient amount of n-hexane, sufficient amount o...

Embodiment 2

[0034] The whole is consistent with Example 1, the difference is:

[0035] The amount of raw materials is 255g of nylon 12, 6g of styrene, 30g of isobutylene gas, sufficient amount of dichloromethane, sufficient amount of n-hexane, sufficient amount of tetrahydrofuran, sufficient amount of α-methyl styrene, sufficient amount of dry hydrogen chloride gas, sufficient amount of pyridine, sufficient amount Selective hydroboration reagent 9-BBN, sufficient amount of titanium tetrachloride, sufficient amount of potassium tert-butoxide, sufficient amount of petroleum ether, sufficient amount of oxygen, sufficient amount of butanone, EPDM rubber 30g, maleic anhydride 0.45 g.

Embodiment 3

[0037] The whole is consistent with Example 1, the difference is:

[0038] The amount of raw materials is 240g of nylon 12, 7.5g of styrene, 36g of isobutylene gas, sufficient amount of dichloromethane, sufficient amount of n-hexane, sufficient amount of tetrahydrofuran, sufficient amount of α-methyl styrene, sufficient amount of dry hydrogen chloride gas, sufficient amount of pyridine, sufficient amount Amount of selective hydroboration reagent 9-BBN, sufficient amount of titanium tetrachloride, sufficient amount of potassium tert-butoxide, sufficient amount of petroleum ether, sufficient amount of oxygen, sufficient amount of butanone, 36g of EPDM rubber, maleic anhydride 0.6g.

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PUM

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Abstract

The invention discloses a nylon raw material of a medical non-toxic dust-free 3D printing isolation eyeshade and a manufacturing method of the nylon raw material. The nylon raw material is composed ofthe following two parts in parts by weight: 20 parts of TPE-g-MAH modified polymer and 80 parts to 85 parts of nylon 12; the TPE-g-MAH modified polymer is specifically prepared by the following stepsof: taking 10-12 parts by weight of isobutene gas as a basic raw material, sequentially carrying out terminal tertiary chlorination treatment, terminal alkenyl treatment and block polymerization to obtain an alkenyl-terminated polybutylene polymer; and based on the alkenyl-terminated polybutylene polymer, carrying out modified polymerization on 10-12 parts by weight of ethylene propylene diene monomer and 0.15-0.2 part by weight of maleic anhydride to finally obtain the TPE-g-MAH modified polymer. The method is non-toxic, harmless, free of dust and free of toxic and harmful components, and incineration products are non-toxic.

Description

technical field [0001] The invention relates to the technical field of medical materials, in particular to a nylon raw material for medical non-toxic and dust-free 3D printing isolation goggles and a manufacturing method thereof. Background technique [0002] Medical isolation goggles are used to prevent unpredictable damage to the eyes caused by blood, liquid medicine, certain viruses and other toxic liquids or virus vectors that cause damage to the skin. It can prevent the impact of objects on the eyes during close-up surgery. The internal space of the eye mask should be large enough to be used by doctors who wear myopia glasses, and the lens part must have anti-fog function. [0003] However, there are several pain points in the existing technology that correspond to the actual working conditions, namely: 1. If my country encounters a severe epidemic this year, plastic products need at least half a month to open the mold, and it is very likely that they cannot meet the s...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L77/02C08L51/06C08L51/04B33Y70/00
CPCC08L77/02B33Y70/00C08L2205/03C08L51/06C08L51/04
Inventor 古文全吴健梁寅吴泽宏孙茂银李英于云峰
Owner 贵州森远增材制造科技有限公司