Material with high biological safety, for nephrostomy tube
A biosafety and ostomy technology, used in catheters, drug delivery, pharmaceutical formulations, etc., can solve the problems of complex components, high cost, poor compatibility, etc., and achieve good biocompatibility, soft material, improved effect on survival
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Embodiment 1
[0032] A preparation method of a nephrostomy tube material, comprising the steps of:
[0033] Ⅰ Add 1.39 kg of 2,2-bis(4-isocyanatophenyl)hexafluoropropane, 1,3-bis(3-hydroxyisobutyl)tetramethyldisiloxane into a three-necked flask with a stirring device 1 kg of alkane, 0.3 kg of dibutyltin dilaurate, and 10 kg of dimethyl sulfoxide were stirred and reacted at 85°C for 10 hours under a nitrogen atmosphere. Ether is removed by rotary evaporation to obtain fluorosilicone polyurethane;
[0034] Ⅱ Add 1 kg of ethyl 3-[2-bromo-4-(trifluoromethyl)phenyl]-2-cyanoacrylate, 1 kg of [bis(trifluoromethylsulfonyl)amino]trimethylsilane, and 0.8 kg of sodium carbonate kg was added to 10 kg of hexafluoroisopropanol, stirred and reacted at 30°C for 8 hours, then filtered, the hexafluoroisopropanol was removed by rotary evaporation, and the product was washed with ether for 3 times, and then the ether was removed by rotary evaporation to obtain an intermediate product;
[0035] ⅢAdd 900g of t...
Embodiment 2
[0039] A preparation method of a nephrostomy tube material, comprising the steps of:
[0040]Ⅰ Add 1.39 kg of 2,2-bis(4-isocyanatophenyl)hexafluoropropane, 1,3-bis(3-hydroxyisobutyl)tetramethyldisiloxane into a three-necked flask with a stirring device 1kg of alkane, 0.35kg of stannous octoate and 12kg of N,N-dimethylformamide were stirred and reacted at 88°C for 10.5 hours under a helium atmosphere. times, after rotary evaporation to remove ether to obtain fluorosilicone polyurethane;
[0041] Ⅱ Add 1 kg of ethyl 3-[2-bromo-4-(trifluoromethyl)phenyl]-2-cyanoacrylate, 1 kg of [bis(trifluoromethylsulfonyl)amino]trimethylsilane, and 0.85 kg of potassium carbonate kg was added to 12 kg of tetrahydrofuran, stirred and reacted at 33°C for 8.5 hours, then filtered, the tetrahydrofuran was removed by rotary evaporation, and the product was washed 4 times with ether, and the ether was removed by rotary evaporation to obtain an intermediate product;
[0042] III Add 900g of the inter...
Embodiment 3
[0046] A preparation method of a nephrostomy tube material, comprising the steps of:
[0047] Ⅰ Add 1.39 kg of 2,2-bis(4-isocyanatophenyl)hexafluoropropane, 1,3-bis(3-hydroxyisobutyl)tetramethyldisiloxane into a three-necked flask with a stirring device 1kg of alkanes, 0.4kg of triethylamine and 13kg of N-methylpyrrolidone were stirred and reacted at 89°C for 11 hours under a neon atmosphere. Distillation removes ether to obtain fluorosilicone polyurethane;
[0048] Ⅱ Add 1kg of ethyl 3-[2-bromo-4-(trifluoromethyl)phenyl]-2-cyanoacrylate, 1kg of [bis(trifluoromethylsulfonyl)amino]trimethylsilane, sodium hydroxide Add 0.9 kg to 13 kg of hexafluoroisopropanol, stir and react at 35°C for 9 hours, then filter, remove hexafluoroisopropanol by rotary evaporation, wash the product with ether for 4 times, and then remove ether by rotary evaporation to obtain an intermediate product;
[0049] III Add 900g of the intermediate product prepared in step II, 300g of 1,2-epoxy-4-vinylcyclo...
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