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Triazine-functionalized silsesquioxane-based hybrid porous polymer, preparation method and application thereof

A silsesquioxane, porous polymer technology, applied in chemical instruments and methods, special compound water treatment, organic compound/hydride/coordination complex catalysts, etc., can solve the problem of limited applicable monomers and harsh reaction conditions. and other problems, to achieve the effect of preventing π-π stacking, simple preparation steps, and easy control of preparation process conditions

Active Publication Date: 2022-03-15
SHANDONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, the applicable monomers of these methods are limited and the reaction conditions are harsh

Method used

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  • Triazine-functionalized silsesquioxane-based hybrid porous polymer, preparation method and application thereof
  • Triazine-functionalized silsesquioxane-based hybrid porous polymer, preparation method and application thereof
  • Triazine-functionalized silsesquioxane-based hybrid porous polymer, preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0059] A preparation method of a phenyl-substituted triazine functionalized silsesquioxane-based hybrid porous polymer (3Ph-TSHPP), comprising the steps of:

[0060] (1) Add 0.189g of octavinylsilsesquioxane (OVS) with a cage structure, 0.524g of 2,4,6-tri (4-Bromophenyl)-1,3,5-triazine (3Ph-TA), 30 mL N,N-dimethylformamide, 0.138 g tetrakis(triphenylphosphine)palladium, 0.50 g sodium bicarbonate, room temperature Stir under low temperature for 30 minutes, then heat to 120°C, and react for 72 hours; Drying at 80° C. for 10 hours gave light yellow powder solid I (0.40 g, mass yield 93%).

[0061] (2) Soxhlet extract the obtained solid I with methanol and dichloromethane for 24 hours, and dry the obtained solid under vacuum at 80° C. for 24 hours to obtain 3Ph-TSHPP.

[0062] The specific surface area of ​​the obtained 3Ph-TSHPP of the present embodiment is 555m 2 g -1 , the pore volume is 0.55cm 3 g -1 .

[0063]The infrared spectrograms of octavinylsilsesquioxane (OVS...

Embodiment 2

[0071] A preparation method of a thiophene-substituted triazine functionalized silsesquioxane-based hybrid porous polymer (3Th-TSHPP), comprising steps:

[0072] (1) Add 0.189g of octavinylsilsesquioxane (OVS) with a cage structure, 0.542g of 2,4,6-tri (5-Bromothiophen-2-yl)-1,3,5-triazine (3Th-TA), 30 mL N,N dimethylformamide, 0.138 g tetrakis(triphenylphosphine) palladium, 0.50 g bicarbonate sodium, stirred at room temperature for 30 minutes, then heated to 120°C, and reacted for 72 hours; The second time, drying at 80° C. for 10 hours under vacuum conditions gave brown yellow powder solid II (yield: 0.37 g, mass yield: 82%).

[0073] (2) Soxhlet-extract the obtained solid II with methanol and dichloromethane for 24 hours, and dry the obtained solid under vacuum at 80° C. for 24 hours to obtain 3Th-TSHPP.

[0074] The specific surface area of ​​the 3Th-TSHPP product obtained in this example is 364m 2 g -1 , with a pore volume of 0.40 cm 3 g -1 .

[0075] The infrare...

Embodiment 3

[0083] A preparation method of a phenyl-substituted triazine functionalized silsesquioxane-based hybrid porous polymer (3Ph-TSHPP), comprising the steps of:

[0084] (1) Add 0.189g of octavinylsilsesquioxane (OVS) with a cage structure, 0.437g of 2,4,6-tri (4-bromophenyl)-1,3,5-triazine (3Ph-TA), 30mL N,N-dimethylformamide, 0.055g tetrakis(triphenylphosphine) palladium, 0.50g sodium bicarbonate, Stir at room temperature for 30 minutes, then heat to 120°C, and react for 72 hours; after the reaction, the reaction system is naturally cooled to room temperature, filtered with suction, and the obtained solid is washed three times with methanol, tetrahydrofuran, chloroform, and acetone respectively. Drying at 80° C. for 10 hours under vacuum condition gave light yellow powder solid III.

[0085] (2) Soxhlet extract the obtained solid III with methanol and dichloromethane for 24 hours, and dry the obtained solid in vacuum at 80°C for 24 hours to obtain 3Ph-TSHPP.

[0086] The speci...

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Abstract

The invention provides triazine functionalized silsesquioxane based hybrid porous polymer, its preparation method and its application in catalytic degradation of dye pollutants. The invention uses octavinylsilsesquioxane (OVS) and triazine monomers (TAs) substituted by bromophenyl or thiophene as raw materials to prepare a hybrid porous material with photocatalytic performance through Heck reaction; the preparation method is simple, The reaction conditions are easy to realize; the obtained material has good chemical stability, thermal stability and fluorescence characteristics, which greatly improves the specific surface area and pore volume of the silsesquioxane-based hybrid porous material, and exhibits high efficiency for dyes in wastewater Catalytic degradation ability has great potential application value in the field of sewage treatment.

Description

technical field [0001] The invention relates to a triazine-functionalized silsesquioxane-based hybrid porous polymer, a preparation method and application thereof, and belongs to the technical fields of polymer material preparation, catalytic degradation, sewage detection and treatment. Background technique [0002] In recent years, more and more synthetic dyes have been widely used in industries such as textile and printing. Many dyes used in large quantities, due to their toxicity, difficulty in biodegradation, and potential carcinogenicity and mutagenicity, etc., so that their release into the environment will cause serious ecological damage. These custom-designed and synthesized dye molecules, such as azo-based dyes (Congo red, CR), thiazide-based dyes (methylene blue, MB) and fluorescein-based dyes (rhodamine B, RB; sangrin T, ST), usually have The chromophore unit has high bond energy, so it is very stable; at the same time, its ionic structure also makes it have high...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G77/04C08G77/388C08G77/392B01J31/12B01J35/10C02F1/30C02F1/32C09K11/06C02F101/30
CPCC08G77/045C08G77/388C08G77/392B01J31/127C02F1/30C02F1/32C09K11/06C02F2305/10C02F2101/308C09K2211/1491C09K2211/1466C09K2211/1458B01J35/617B01J35/635B01J35/39
Inventor 刘鸿志杜雅静
Owner SHANDONG UNIV
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