Toner, developer, toner container, process cartridge, image forming apparatus and image forming method

A technology of toner and colorant, which is applied in the direction of developer, equipment and instrument of electrical recording process using charge pattern, and can solve the problems of miniaturization, lower yield, acceleration and coloring, etc.

Inactive Publication Date: 2006-09-20
RICOH KK
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Therefore, when it is easy to form a wide particle size distribution and produce good resolution and color tone in the abrasive composition particles in the actual reproduced image, it is necessary to remove the fine powder with a size of less than 3 μm and a size greater than 20 μm by classification. micron coarse particles, which detrimentally reduces the yield
Also, in the grinding method, it is difficult to uniformly disperse colorants and charge control agents in thermoplastic resins
In addition, since the colorant added to the toner is exposed on the surface of the toner, there is a problem that the charge distribution on the toner surface is unstable, broadening the charge distribution of the toner and degrading the developing performance
Also, since the toner is prepared simultaneously with the polymerization of the resin, many materials commonly used in toners cannot be used
Although commonly used materials are polymerizable, there are cases where the particle size cannot be sufficiently controlled due to the action of additives such as resins and colorants
Therefore, this method has the problem of having less flexibility in the choice of materials
[0006] In particular, there are problems in that polyester resins generally used in kneading and grinding methods for developing excellent fixing performance and coloring performance cannot be used, and downsizing, acceleration and coloring cannot be satisfied to a satisfactory degree
Therefore, there is also the problem: Insufficient dispersion of colorants reduces OHP transparency
However, because the release agent cannot be refined like a colorant, it is more difficult to add and disperse evenly
There is also a problem: poor dispersion of the release agent suppresses charging performance, developing performance, storage stability and OHP transparency
As described above, toners for electrophotography and related methods capable of satisfying higher performance requirements have not yet been realized.

Method used

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  • Toner, developer, toner container, process cartridge, image forming apparatus and image forming method
  • Toner, developer, toner container, process cartridge, image forming apparatus and image forming method
  • Toner, developer, toner container, process cartridge, image forming apparatus and image forming method

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0119] Preparation of sample: 0.5 g of toner (0.3 g for ethyl acetate soluble component) was added to 120 mL of toluene, and the mixture was stirred at room temperature (23° C.) for 10 hours to dissolve. Also, 30 mL of ethanol was added to prepare a sample solution.

[0120] The acid value can be calculated by the above-mentioned equipment, and the specific calculation procedure is as follows.

[0121] The sample was titrated with a pre-evaluated 10 / N caustic potash ethanol solution, and the acid value was obtained from the consumption rate of the caustic potash ethanol solution as follows:

[0122] Acid value = KOH (in mL) × N × 56.1 / sample mass

[0123] where N is a factor in N / 10KOH.

[0124]

[0125] In a 100 mL volumetric flask, add 0.5 g of accurately weighed sample, to which 5 mL of acetylated sample is appropriately added. Next, the flask was immersed in a heating bath at a temperature of 100±5°C and heated. After 1 to 2 hours, the flask was removed from the heat...

Embodiment 1

[0334] ~Synthesis of resin particle emulsion~

[0335] In a reaction vessel equipped with a stirrer and a thermometer, 683 parts of water, 11 parts of sodium salt of methacrylic acid ethylene oxide adduct sulfate (ELEMINOL RS-30 manufactured by Sanyo Chemical Industries, Ltd.), 83 parts of styrene, 83 parts of methacrylic acid, 110 parts of butyl acrylate and 1 part of ammonium persulfate and stirred at 400 rpm for 15 minutes to obtain a white emulsion. The emulsion was heated until the temperature of the system reached 75°C and reacted for 5 hours. Furthermore, 30 parts of a 1-% aqueous solution of ammonium persulfate was added, and the mixture was aged at 75° C. for 5 hours to obtain a vinyl resin (sodium salt of sulfate ester of ethylene oxide adduct of methacrylic acid-styrene - Aqueous dispersion of methacrylic acid-butyl acrylate copolymer), resin particle dispersion 1. The volume average particle diameter of the resin particle dispersion 1 was measured by a laser diff...

Embodiment 2

[0362] Toner 2 was obtained in the same manner as in Example 1 except that Master Batch 2 prepared as described below was used instead of Master Batch 1 in Example 1.

[0363] ~Pigment treatment~

[0364] In a 10-liter kneader, 500 parts of crude copper phthalocyanine blue having a purity of 95% were introduced together with 2,000 parts of common salt and 550 parts of diethylene glycol. After the mixture was kneaded at 100°C for 4 hours, 25 parts of natural rosin was added to the mixture and further mixed for 30 minutes. The obtained mixture was placed in 10,000 parts of water, and stirred at 80°C until table salt and diethylene glycol were dissolved. After further adding 50 parts of 98-% sulfuric acid and stirring for 1 hour, the mixture was filtered and washed until it became neutral, obtaining a pigment composition in the form of a slurry. This was further dried and pulverized to obtain 490 parts of a pigment composition.

[0365] ~Synthesis of masterbatch~

[0366] In ...

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PUM

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Abstract

The present invention provides a toner and a developer which includes the toner. The toner is produced in an aqueous medium and includes at least a binding resin, a colorant and a dispersant which disperses the colorant. The binding resin contains 50% by mass to 100% by mass of a polyester resin, and the colorant is a pigment whose surface is given an acid treatment. The acid value of the dispersant is 1 mg KOH / g to 30 mg KOH / g, and the amine value of the dispersant is 1 mg KOH / g to 100 mg KOH / g.

Description

technical field [0001] The present invention relates to a toner for image formation, which has excellent charge properties, fluidity, stability and transfer properties, has good charge properties and good image quality, and can form a toner having excellent OHP optical transparency an image; a developer using the toner; a toner container; a process cartridge; an image forming apparatus; and an image forming method. Background technique [0002] In electrophotographic apparatuses and electrostatic recording apparatuses, an electric latent image or a magnetic latent image is developed by toner. In the electrophotographic method, for example, after an electrostatic image (latent image) is formed, then, the latent image is developed with a toner to form a toner image. For example, a toner image is generally transferred onto a transfer member such as paper, and then fixed by heating. Toners used to develop electrostatic images are generally toner particles including colorants, ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G03G9/08G03G9/087G03G15/08G03G21/16G03G15/00G03G13/00
Inventor 大木正启渡边真弘井上竜太齐藤彰法江本茂山田雅英田中千秋杉山恒心渡辺阳一郎
Owner RICOH KK
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