The present invention is directed to an
electrochemical cell based on
lithium technology, comprising the following components: a positive
electrode containing a
cathode material, a separator made of an electrically insulating material, a negative
electrode containing an
anode material, the electrodes and the separator having layer or sheet form, a liquid and / or
solid ion conductor material for transportation of
lithium ions between the positive and the negative
electrode, the said components being sealed within a casing, wherein the positive and the negative electrode each comprise an electrically conducting structure extending through a wall of the casing for further
electrical connection, characterized in that it further comprises: a
reference electrode within the said casing which is electrically insulated from the positive and the negative electrode, the
reference electrode having layer or sheet form comprising at least one non-
metallic lithium compound, and an electrically conducting structure in layer or sheet form being in electrical contact with the said
reference electrode, the electrically conducting structure extending through a wall of the casing for further
electrical connection. The invention is further directed to a method for the preparation of this
electrochemical cell, to a method for measuring the
voltage or the impedance of a
cathode and / or of an
anode of such an
electrochemical cell based on
lithium technology, and to driving methods of said
cell, decreasing aging phenomena and improving its life duration.