One-step preppn process of flocculant
A technology of flocculant and corn starch, which is applied in chemical instruments and methods, flocculation/sedimentation water/sewage treatment, inorganic chemistry, etc., can solve the problems of great harm to human health, poor effect, high dosage, etc., and improve ecological safety performance, elimination of toxicity of aluminum salts, and optimization of spatial structure
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Embodiment 1
[0032] The present invention takes aluminum salt, cornstarch, sodium hydroxide (NaOH) as raw material, wherein: aluminum salt (AlCl 3 ), corn starch is the main component, NaOH is used for the modification of corn starch and the prepolymerization of inorganic aluminum salt; AlCl 3 The mass ratio of aluminum element to corn starch is 1:1;
[0033] Its preparation method is:
[0034] 1) Proportioning of causticized starch: 25% NaOH solution and 10% starch solution are fully mixed according to the mass ratio of NaOH to starch of 1:4.
[0035]2) Proportioning basic AlCl3: Add 25% NaOH solution and inorganic aluminum salt to the reaction system of 1) successively, wherein the mass ratio of NaOH to aluminum element (2.9:1), the mass ratio of aluminum element to cornstarch in 1) The ratio is 1:1.
[0036] 3) Control the reaction temperature to 40°C and pH value to 3, and carry out starch causticization, aluminum salt prepolymerization and composite reaction for 1 hour to obtain a ...
Embodiment 2
[0039] The present invention takes aluminum salt, cornstarch, sodium hydroxide (NaOH) as raw material, wherein: aluminum salt (Al 2 (SO 4 ) 3 ), corn starch is the main component, NaOH is used for the modification of corn starch and the prepolymerization of inorganic aluminum salt; AlCl 3 The mass ratio of aluminum element to corn starch is 2:1;
[0040] Its preparation method is:
[0041] 1) Proportion causticized starch: 15% NaOH solution and 8% starch solution are fully mixed according to the mass ratio of NaOH to starch of 1:3.
[0042] 2) Proportioning basic Al 2 (SO 4 ) 3 : Add 15% NaOH solution and inorganic aluminum salt to the reaction system of 1) successively, wherein the mass ratio of NaOH to aluminum element (2.5:1), the mass ratio of aluminum element to cornstarch in 1) is 2:1.
[0043] 3) Control the reaction temperature to 45° C., pH value to 4, carry out starch causticization, aluminum salt prepolymerization and composite reaction for 2 hours to obtain ...
Embodiment 3
[0046] The present invention takes aluminum salt, cornstarch, sodium hydroxide (NaOH) as raw material, wherein: aluminum salt (AlCl 3 ), corn starch is the main component, and sodium hydroxide is used for the modification of corn starch and the prepolymerization of inorganic aluminum salt; AlCl 3 The mass ratio of aluminum element to corn starch is 2:3;
[0047] Its preparation method is:
[0048] 1) Proportion causticized starch: 30% NaOH solution and 20% starch solution are fully mixed according to the mass ratio of NaOH to starch of 2:1.
[0049] 2) Proportioning basic AlCl 3 : 25% NaOH solution and inorganic aluminum salt are added to the reaction system of 1) successively, wherein the mass ratio of NaOH to aluminum element (3.1:1), and the mass ratio of aluminum element to cornstarch in 1) is 2:3.
[0050] 3) Control the reaction temperature to 55° C., pH value to 3, carry out starch causticization, aluminum salt pre-polymerization and composite reaction for 4 hours to...
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