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Nano-porous thermal insulating material and method for producing the same

A technology of thermal insulation materials and nanopores, applied in the field of preparation of thermal insulation materials, can solve the problems of long production cycle, harsh preparation conditions, large solvent consumption, etc., and achieve the effects of high operating temperature, low thermal conductivity and easy forming.

Active Publication Date: 2008-07-16
SHANGHAI SHIPBUILDING TECH RES INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The disadvantage of this method is that 4-6 times of solvent cleaning will bring great trouble to the preparation of the product. In addition, the production cycle is long and the solvent consumption is large, which also brings difficulties to the preparation of the material.
[0007] Although the materials prepared by the above invention patents have good thermal insulation properties, the preparation conditions are harsh, which causes great inconvenience to the actual operation.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] The weight in material is the weight of the solids content fraction.

[0038] Silica sol (including SiO weight part) 20, flame silica fume 35, white carbon black 10, silicon-acrylic emulsion 4, hydroxyl silicone oil 1, high-purity glass fiber 5, titanium dioxide 25.

[0039] First prepare the liquid part, dilute the silica sol with water until the weight content of silicon dioxide in the sol is 15%, adjust the pH value of the solution to 6 with lactic acid, then add silicon-acrylic emulsion and hydroxyl silicone oil and stir for 5-10 minutes . Then add the mixture of flame silica fume, white carbon black and titanium dioxide into the liquid material under stirring at 3000 rpm, stir, inject the stirred material into the mold, and seal the material, and put it at 80°C Put it in a special oven for 24 hours, and finally remove the sealing layer of the mold material and put it in a vacuum box, and treat the material at 70°C for 4 hours until it is dry, and then you can obta...

Embodiment 2

[0041] First, hydrolyze tetraethyl orthosilicate, and form a mixed solution of 80 g of tetraethyl orthosilicate, 20 g of ethanol, 30 g of water, and 4 g of simethicone, adjust the pH value to 4 with hydrochloric acid, and reflux at 80° C. for 2.5 hours. Then add 5g of silicone resin emulsion to the ethyl silicate hydrolyzate for mixing, then add 35g of fumed silicon dioxide, 20g of titanium dioxide and 4g of glass fiber for stirring and mixing, pour into a closed mold, and place it at 60°C for 24 hours. Gel and age. Finally, after demolding the aged material, put it in a drying oven and dry it at 40°C for 8 hours under negative pressure, and then a nanoporous thermal insulation material product with complete structure and no cracks can be obtained. Observation by Scanning Electron Microscope (SEM), the nanopore void is above 80%; detection by GB / T10699 standard, the bulk density is 220kg / m 3 , the thermal conductivity at room temperature is 0.023W / m.k, the average thermal con...

Embodiment 3

[0043] The weight in material is the weight of the solids content fraction.

[0044] Silica sol (in which SiO weight part) 20, fumed silica 45, silicon-acrylic emulsion 8, hydrogen-containing silicone oil 2, aluminum silicate fiber 5, silicon carbide 20.

[0045]First prepare the liquid part, dilute the silica sol with water until the weight content of silica in the sol is 12%, adjust the pH value of the solution to 7 with oxalic acid, then add silicon-acrylic emulsion and hydrogen-containing silicone oil for high-speed stirring for 10-15 minute. Then gradually add the mixture of fumed silica, aluminum silicate fiber, and silicon carbide into the liquid material under high-speed stirring. After fully stirring, inject the stirred material into the mold, and seal the material, and release it for 100 ℃ oven for 12 hours. Finally, remove the sealing layer from the material in the mold and put it into a vacuum box to pump air to treat the material until it is dry, and then a nano...

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PUM

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Abstract

The invention discloses a heat insulation material with nanometer pores and a manufacturing method thereof; the heat insulation material with nanometer pores is prepared from the following components: silica of nanometer level, silicon source sol, inorganic reinforced fiber, structural strengthening agent, surface modifier, sunscreen, catalyst and diluents. The heat insulation material with nanometer pores prepared by the invention can be easily shaped, with small bulk density, small thermal conductivity, high utilization temperature, non-combustible performance, and certain mechanical strength; the interspace of the nanometer pores is over 80 percent, and the bulk density is from 150 to 250kg / m<3>; the thermal conductivity under room temperature is less than 0.025W / m.k, and the average thermal conductivity under 500 DEG C is no more than 0.050W / m.k, with the highest utilization temperature 950 DEG C; the invention is suitable for heat insulation in boats, industrial pipes and heating furnaces.

Description

technical field [0001] The invention belongs to the field of inorganic heat-insulating materials, and in particular relates to a preparation method of a heat-insulating material with a nanopore structure. technical background [0002] Currently commonly used inorganic thermal insulation materials such as fibrous materials such as asbestos, glass wool, rock wool, aluminum silicate fibers, and foam materials such as expanded perlite, foam glass, and microporous calcium silicate have been widely used. However, their heat insulation effect is not good under high temperature conditions (such as above 500°C), because the void scale in the material is relatively large, which cannot effectively prevent convective heat transfer in heat transfer. If the size range of the voids in the internal structure of a material and the particles of the national phase part is 100nm or below, it can effectively limit the heat convection and heat conduction of the material, so that good thermal insu...

Claims

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Application Information

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IPC IPC(8): C04B28/00C04B14/06C04B14/38C04B24/24
Inventor 石明伟胡津津
Owner SHANGHAI SHIPBUILDING TECH RES INST
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