Nano-porous thermal insulating material and method for producing the same
A technology of thermal insulation materials and nanopores, applied in the field of preparation of thermal insulation materials, can solve the problems of long production cycle, harsh preparation conditions, large solvent consumption, etc., and achieve the effects of high operating temperature, low thermal conductivity and easy forming.
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Embodiment 1
[0037] The weight in material is the weight of the solids content fraction.
[0038] Silica sol (including SiO weight part) 20, flame silica fume 35, white carbon black 10, silicon-acrylic emulsion 4, hydroxyl silicone oil 1, high-purity glass fiber 5, titanium dioxide 25.
[0039] First prepare the liquid part, dilute the silica sol with water until the weight content of silicon dioxide in the sol is 15%, adjust the pH value of the solution to 6 with lactic acid, then add silicon-acrylic emulsion and hydroxyl silicone oil and stir for 5-10 minutes . Then add the mixture of flame silica fume, white carbon black and titanium dioxide into the liquid material under stirring at 3000 rpm, stir, inject the stirred material into the mold, and seal the material, and put it at 80°C Put it in a special oven for 24 hours, and finally remove the sealing layer of the mold material and put it in a vacuum box, and treat the material at 70°C for 4 hours until it is dry, and then you can obta...
Embodiment 2
[0041] First, hydrolyze tetraethyl orthosilicate, and form a mixed solution of 80 g of tetraethyl orthosilicate, 20 g of ethanol, 30 g of water, and 4 g of simethicone, adjust the pH value to 4 with hydrochloric acid, and reflux at 80° C. for 2.5 hours. Then add 5g of silicone resin emulsion to the ethyl silicate hydrolyzate for mixing, then add 35g of fumed silicon dioxide, 20g of titanium dioxide and 4g of glass fiber for stirring and mixing, pour into a closed mold, and place it at 60°C for 24 hours. Gel and age. Finally, after demolding the aged material, put it in a drying oven and dry it at 40°C for 8 hours under negative pressure, and then a nanoporous thermal insulation material product with complete structure and no cracks can be obtained. Observation by Scanning Electron Microscope (SEM), the nanopore void is above 80%; detection by GB / T10699 standard, the bulk density is 220kg / m 3 , the thermal conductivity at room temperature is 0.023W / m.k, the average thermal con...
Embodiment 3
[0043] The weight in material is the weight of the solids content fraction.
[0044] Silica sol (in which SiO weight part) 20, fumed silica 45, silicon-acrylic emulsion 8, hydrogen-containing silicone oil 2, aluminum silicate fiber 5, silicon carbide 20.
[0045]First prepare the liquid part, dilute the silica sol with water until the weight content of silica in the sol is 12%, adjust the pH value of the solution to 7 with oxalic acid, then add silicon-acrylic emulsion and hydrogen-containing silicone oil for high-speed stirring for 10-15 minute. Then gradually add the mixture of fumed silica, aluminum silicate fiber, and silicon carbide into the liquid material under high-speed stirring. After fully stirring, inject the stirred material into the mold, and seal the material, and release it for 100 ℃ oven for 12 hours. Finally, remove the sealing layer from the material in the mold and put it into a vacuum box to pump air to treat the material until it is dry, and then a nano...
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Abstract
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