Germanate glass optical fiber with emission wavelength of 1.5-2.2 mu m
A technology of germanate glass and emission wavelength, which is applied in the direction of cladding optical fiber, optical waveguide light guide, optics, etc., can solve the problems of low fiber laser quantum efficiency and slope efficiency, low laser damage threshold, low quantum efficiency, etc., and achieve good Chemical stability and environmental adaptability, strong chemical stability and environmental adaptability, high fluorescent quantum efficiency
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Embodiment 1
[0026] A germanate glass single-clad optical fiber with an emission wavelength of 1.5-2.2 μm, the composition of the core glass is: 20mol% BaO-5mol% Ga 2 O 3 -70mol% GeO 2 -5mol% Y 2 O 3 , plus 4.0 mol% Tm 2 O 3 ; The cladding glass is germanate glass with the same composition as the core glass, but not doped with rare earth ions; the optical fiber preform with a circular cross-section is obtained by the tube rod method; the outer diameter is 200 μm drawn on the drawing tower , A germanate glass fiber with a core diameter of 30 μm can obtain luminescence of 1.5-2.2 μm under the excitation of 808 nm LD.
Embodiment 2
[0028] A germanate glass single-clad optical fiber with an emission wavelength of 1.5-2.2 μm, the composition of the core glass is: 30 mol% Ga 2 O 3 -25mol%PbO-40mol%GeO 2 -5mol% La 2 O 3 , plus 0.2 mol% Ho2 O 3 ; The outer layer is made of silicate optical glass whose refractive index, glass transition temperature, and crystallization start temperature match the core glass, and the optical fiber preform is obtained by the tube rod method; the outer diameter is 125 μm and the core diameter is drawn on the drawing tower. It is a standard germanate glass fiber of 7 μm, and can obtain luminescence of 1.5-2.2 μm under the excitation of a 2.0 μm thulium-doped laser or a 1535 nm erbium-doped laser.
Embodiment 3
[0030] A germanate glass double-clad optical fiber with an emission wavelength of 1.5-2.2 μm, the composition of the core glass is: 15mol% BaO-10mol% Ga 2 O 3 -70mol% GeO 2 -5mol% Ln 2 O 3 , plus 1 mol% Ho 2 O 3 and 1mol% Yb 2 O 3 ; The lanthanum crown glass with matching refractive index and glass transition temperature is used as the inner cladding material of the optical fiber, and the optical fiber preform with a square cross-section of the inner cladding is prepared by the tube-rod method; the plastic with matching refractive index is used as the outer cladding, in the drawing tower A germanate double-clad glass fiber with an outer diameter of 200 μm and a core diameter of 30 μm is pulled up, and the luminescence of 1.5-2.2 μm can be obtained under the excitation of 980 nm LD.
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