Dispensing adhesive agent for connection of mosaics and production process

An adhesive and mosaic technology, applied in the direction of adhesives, adhesive types, polyurea/polyurethane adhesives, etc., can solve the problems of poor moisture resistance, affect the bonding strength, mosaic peeling, etc., to improve construction efficiency and Quality, guaranteed aesthetics, good weather resistance effect

Inactive Publication Date: 2013-10-30
佛山市智韧新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] (2) The water resistance of the previous two generations of adhesives is not good, and the water resistance is ordinary. In boiling water (100°C under standard environment), the adhesiveness is lost or the adhesive strength is obviously attenuated in 5 to 10 minutes. At room temperature, it is resistant to heat and humidity. The humidity is not good, and the requirements for the storage of the mosaic after forming are relatively high, and the mosaic particles are prone to fall off
[0005] (3) The last two generations of adhesives seriously affect the construction effect of the mosaic after the mosaic is connected.
Seriously affect the wetting contact between mosaic particles and cement or tile adhesive, thus affecting the bonding strength during construction
As a result, the mosaic is easy to fall off from the wall or building, especially when the exterior wall decoration of high-rise buildings is prone to safety hazards

Method used

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  • Dispensing adhesive agent for connection of mosaics and production process
  • Dispensing adhesive agent for connection of mosaics and production process
  • Dispensing adhesive agent for connection of mosaics and production process

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0056] Formula one (the total mass of the formula is 100g)

[0057] (1) Plasticizer: 5g of dibutyl phthalate, 12g of dioctyl phthalate, 10g of dioctyl adipate

[0058] (2) PVC paste resin: homopolyvinyl chloride paste resin (K value 70) 12g

[0059] Copolymerized polyvinyl chloride paste resin (K value 75) 13g

[0060] (3) Curing agent: Hexamethylene diisocyanate (HDI) trimer 1.5g

[0061] (4) Blocked polyurethane prepolymer: 5.0 g of toluene diisocyanate prepolymer blocked by methyl ethyl ketone oxime

[0062] (5) Nano calcium carbonate: 10g

[0063] (6) Heavy calcium carbonate: 8g

[0064] (7) Calcite powder: 18g

[0065] (8) Coupling agent: γ-(2,3-epoxypropoxy)propyltrimethoxysilane 0.5g

[0066] (9) Heat stabilizer: zinc oxide 0.6g, dibutyltin dilaurate 1.0g

[0067] (10) Water remover: bicyclic oxazolidine 0.2g, calcium oxide 1.0g

[0068] (11) Thixotropic agent: fumed silica 1.2g

[0069] (12) Thinner: solvent kerosene 1.0g

[0070] In this formula example, aft...

Embodiment 2

[0075] Formula two (the total mass of the formula is 100g)

[0076] (1) Plasticizer: butyl benzyl phthalate 10g, diisodecyl phthalate 5g,

[0077] Dioctyl adipate 7g;

[0078] (2) PVC paste resin: homopolyvinyl chloride paste resin (K value 75) 18g

[0079] (3) Curing agent: 1.2 g of TDI-TMP adduct prepared by reaction of toluene diisocyanate and trimethylolpropane

[0080] (4) Blocked polyurethane prepolymer: 3,5-dimethylpyrazole-blocked hexamethylene diisocyanate (HDI) trimer prepolymer 6g

[0081] (5) Nano calcium carbonate: 13g

[0082] (6) Heavy calcium carbonate: 12g

[0083] (7) Calcite powder: 23g

[0084] (8) Coupling agent: γ-aminopropyltriethoxysilane 0.3g

[0085] (9) Heat stabilizer: butyltin maleate 1.2g

[0086](10) Water remover: calcium oxide 2.0g

[0087] (11) Thixotropic agent: fumed silica 1.3g

[0088] (12) Thinner: 0g

[0089] In this formula example, after dispersing and mixing evenly, after aging for 24 hours, the mosaic is bonded. The size of...

Embodiment 3

[0093] Formula three (the total mass of the formula is 100g)

[0094] (1) Plasticizer: epoxy soybean oil 8g, butyl benzyl phthalate 15g, dioctyl phthalate 8g

[0095] (2) Polyvinyl chloride paste resin: Copolymerized polyvinyl chloride paste resin 30g

[0096] (3) Curing agent: Hexamethylene diisocyanate (HDI) biuret 1.8g

[0097] (4) Blocked polyurethane prepolymer: 9g of hexamethylene diisocyanate (HDI) prepolymer blocked by 3,5-dimethylpyrazole

[0098] (5) Nano calcium carbonate: 10g

[0099] (6) Heavy calcium carbonate: 3g

[0100] (7) Calcite powder: 4g

[0101] (8) Coupling agent: γ-(2,3-epoxypropoxy)propyltrimethoxysilane 0.6g

[0102] (9) Heat stabilizer: zinc oxide 1.2g

[0103] Dibutyltin oxide (dibutyltin oxide) 2.0g

[0104] (10) Dehydrating agent: calcium oxide 5g, p-methylphenylsulfonyl isocyanate 1.0g

[0105] (11) Thixotropic agent: fumed silica 1.4g

[0106] (12) Thinner: 0g

[0107] In this formula example, after dispersing and mixing evenly, after...

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Abstract

The invention discloses a dispensing adhesive agent for connection of mosaics and a production process. The adhesive agent comprises, by weight, 20%-30% of plasticizers, 18%-33% of polyvinyl chloride paste resins, 0.5%-2% of curing agents, 1.0%-12% of endcapped polyurethane prepolymers, 6%-13% of nano calcium carbonate, 3%-16% of heavy calcium carbonate, 3%-23% of calcite powder, 0.1%-1% of coupling agents, 0.3%-4.5% of heat stabilizers, 0.2%-6% of water-removal agents, 0.4%-1.8% of thixotropic agents and 0%-2% of diluents. The adhesive agent for connection of mosaics does not need base materials such as paper, silk screens and the like, has excellent water resistance and can raise the bonding strength of mosaics.

Description

technical field [0001] The invention relates to a dispensing adhesive for forming joints of mosaics and a manufacturing process thereof. Background technique [0002] At present, domestic mosaics need to be connected by paper stickers or net stickers, and most of the adhesives used are white latex, which is water-resistant, weather-resistant, and durable. White latex or other existing adhesives cannot achieve the purpose of connecting and forming a joint, and the overall connection must be realized through kraft paper, synthetic fiber net or glass fiber net. The adhesive itself only plays the role of bonding the mosaic block and the substrate (kraft paper, synthetic fiber mesh or glass fiber mesh). Paper mosaic is the first generation of mosaic bonding technology, and net-sticking mosaic is the second generation of mosaic bonding technology. The adhesives of the previous two generations have many shortcomings: [0003] (1) Adhesives used in the last two generations for for...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J127/06C09J175/04C09J11/04C09J11/06
Inventor 邵杰惠畅廖作桂
Owner 佛山市智韧新材料有限公司
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