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Graphene-based nanometer zero-valent aluminum coating and preparation method thereof

A graphene-based, nano-zero-valent technology, used in anti-corrosion coatings, conductive coatings, epoxy resin coatings, etc. , The key role of graphene has not been maximized, and the best performance of graphene and other nanoparticles has not been exerted to achieve low cost, easy industrial mass production, and excellent anti-corrosion effect.

Inactive Publication Date: 2015-03-04
HUNAN ORIENTOP GRAPHENE APPL TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Although graphene is used as the main modification additive in the coating patents related to the addition of graphene, the simple stirring and mixing method in the preparation method cannot completely and uniformly disperse graphene and other nanoparticles in the coating, so that Graphene and other nanoparticles do not play the role of mutual promotion of waterproof and corrosion resistance, high temperature resistance, weather resistance, alkali resistance, impact resistance and aging resistance, and the best effect of graphene and other nanoparticles has not been realized. Get the best out of graphene and other nanoparticles without maximizing the critical role graphene plays in coatings

Method used

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  • Graphene-based nanometer zero-valent aluminum coating and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034]A graphene-based nano-zero-valent aluminum-based coating, each component is weighed in the following parts by weight:

[0035] 5 parts of graphene-based nano zero-valent aluminum,

[0036] 6 parts of graphene-based nano zero-valent zinc,

[0037] 3 parts of graphene-based nano-titanium dioxide,

[0038] 3 parts of graphene-based nano silicon dioxide,

[0039] 5 parts of graphene-based nano calcium carbonate,

[0040] Silicone epoxy resin 45 parts

[0041] 20 parts of polyphenylene sulfide resin,

[0042] 5 parts melamine formaldehyde resin

[0043] 25 parts of n-butanol

[0044] 20 parts ethanol

[0045] 1.0 parts of alkylphenol polyoxyethylene ether,

[0046] 0.8 part of polyhydroxy acid sodium salt,

[0047] 0.5 parts of methylcellulose,

[0048] 0.2 parts of methyl silicone oil,

[0049] 0.3 parts of dioctyl phthalate,

[0050] 0.3 part of polyether polyester modified organosiloxane,

[0051] Titanium dioxide 4 parts

[0052] Zinc oxide 4 parts

[0053]...

Embodiment 2

[0062] A graphene-based nano-zero-valent aluminum-based coating, each component is weighed in the following parts by weight:

[0063] 8 parts of graphene-based nano zero-valent aluminum,

[0064] 6 parts of graphene-based nano zero-valent zinc,

[0065] 3 parts of graphene-based nano-titanium dioxide,

[0066] 3 parts of graphene-based nano silicon dioxide,

[0067] 5 parts of graphene-based nano calcium carbonate,

[0068] Silicone epoxy resin 45 parts

[0069] 20 parts of polyphenylene sulfide resin,

[0070] 5 parts urea-formaldehyde resin

[0071] 25 parts of n-butanol

[0072] 20 parts ethanol

[0073] 1.0 parts of alkylphenol polyoxyethylene ether,

[0074] 0.8 parts of sodium bisuccinate sulfonate,

[0075] 0.5 parts of hydroxyethyl cellulose,

[0076] 0.2 parts of tributyl phosphate,

[0077] 0.3 parts of dibutyl phthalate,

[0078] 0.3 parts of polydimethylsiloxane leveling agent,

[0079] 8 parts of paint,

[0080] 3 parts superfine talc powder

[0081...

Embodiment 3

[0089] A graphene-based nano-zero-valent aluminum-based coating, each component is weighed in the following parts by weight:

[0090] 10 parts of graphene-based nano-zero-valent aluminum,

[0091] 6 parts of graphene-based nano zero-valent zinc,

[0092] 3 parts of graphene-based nano-titanium dioxide,

[0093] 3 parts of graphene-based nano silicon dioxide,

[0094] 5 parts of graphene-based nano calcium carbonate,

[0095] Silicone epoxy resin 45 parts

[0096] 20 parts of polyphenylene sulfide resin,

[0097] 5 parts urea-formaldehyde resin

[0098] 25 parts of n-butanol

[0099] 20 parts ethanol

[0100] 1.0 parts of alkylphenol polyoxyethylene ether,

[0101] 0.8 parts of sodium bisuccinate sulfonate,

[0102] 0.5 parts of hydroxyethyl cellulose,

[0103] 0.2 parts of tributyl phosphate,

[0104] 0.3 parts of dibutyl phthalate,

[0105] 0.3 parts of polydimethylsiloxane leveling agent,

[0106] 8 parts of paint,

[0107] 0.3 parts of superfine talcum powder ...

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Abstract

The invention discloses a graphene-based nanometer zero-valent aluminum coating comprising the following components in parts by weight: 1-20 parts of graphene-based nanometer zero-valent aluminum, 1-20 parts of graphene-based nanometer zero-valent zinc, 1-15 parts of graphene-based nanometer titanium dioxide, 1-15 parts of graphene-based nanometer silicon dioxide, 1-15 parts of graphene-based nanometer calcium carbonate, 5-60 parts of epoxy resin, 3-30 parts of polyphenylene sulfide resin, 1-15 parts of an amino resin crosslinking agent, 3-50 parts of a mixed-type organic alcohol solvent, 0.5-1.9 parts of a nonionic surfactant, 0.8-1.6 parts of a dispersing agent, 0.5-1.5 parts of a thickening agent, 0.1-0.3 part of a defoaming agent, 0.1-5 parts of a plasticizer, 0.2-0.5 part of a flatting agent, 1-10 parts of pigment and 0.5-1.0 part of a filler. The invention also provides a preparation method of the coating. The performances such as high temperature resistance, corrosion resistance, hardness, surface adhesion, weather resistance, acid and alkaline resistance and impact resistance of the coating disclosed by the invention are remarkably improved.

Description

technical field [0001] The invention relates to a coating, in particular to a graphene-based nano-zero-valent aluminum coating and a preparation method thereof, belonging to the field of high-tech materials and their applications. Background technique [0002] With the increasing attention to environmental issues and energy issues worldwide, traditional coatings can no longer meet the actual needs. Multifunctional coatings such as wear-resistant, anti-corrosion, high-temperature resistant, and environmentally friendly are currently the development direction of countries all over the world. In order to promote the wide application of coatings in aerospace, navigation, petroleum and petrochemical, metallurgy, electric power, automobile, construction, machinery, electronic appliances, national defense and other fields, researchers have improved the functions of coatings such as wear resistance, corrosion resistance and high temperature resistance: ① Improve the heat resistance ...

Claims

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Application Information

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IPC IPC(8): C09D163/00C09D181/02C09D5/10C09D5/24C09D7/12
CPCC09D163/00C08K2201/011C08K2201/014C08L2201/08C08L2205/035C09D5/103C09D5/106C09D7/61C09D7/63C09D7/65
Inventor 邓凌峰刘小花刘永正王钟民张远和文建民
Owner HUNAN ORIENTOP GRAPHENE APPL TECH
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