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Water treatment agent for removing phenolic compounds from water

A technology of phenolic compounds and water treatment agents, applied in water/sewage treatment, water/sludge/sewage treatment, energy wastewater treatment, etc., can solve the problems of high cost, many factors of dephenolization efficiency, and high operating cost. Achieve the effect of low equipment requirements, strong complexing ability and low processing cost

Active Publication Date: 2015-09-23
佛山亚特表面技术材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The disadvantage is that this method can only remove low-boiling point phenols, and consumes a lot of energy. It takes about 180 kg of fuel equivalent to standard coal to evaporate 1 ton of waste water.
[0006] 3. Incineration method: The phenolic wastewater is sprayed into the incinerator, so that the phenolic organic matter undergoes an oxidation reaction at a high temperature of about 1100 ° C, and finally produces CO 2 and H 2 O emission, this method is simple in process and easy to operate, but it consumes a lot of energy, and the cost of incinerating 1 ton of phenol-containing wastewater is relatively high
Another key disadvantage of using the incineration method to treat phenol-containing wastewater is that once the operation is careless, the furnace temperature will drop, which will often cause incomplete combustion and easily cause secondary pollution.
This method must use high-efficiency extractant and alkali, and the operating cost is relatively high
[0008] 5. Resin dephenolization method: The main process of this method includes adsorption and desorption, using resin to adsorb phenol in wastewater, and then desorbing with lye to generate sodium phenolate. The process of this method is relatively complicated, and factors that affect the efficiency of dephenolization Many, relatively high operating costs
The biochemical method has relatively strict requirements on the quality of the wastewater entering the biochemical pool. The concentration of organic matter such as tar and phenol in the wastewater should not exceed the concentration that microorganisms can bear. Otherwise, the wastewater needs to be diluted before entering the biochemical pool, which limits the amount of treated water.
At the same time, it is difficult to domesticate microorganisms. The concentration of influent water exceeds the standard and the ambient temperature is not suitable, which can easily limit the survival of microorganisms.
[0011] The above-mentioned processes have some defects and cannot be used normally in practical applications.
For example, in addition to the steam dephenolization method and incineration method, several other treatment methods have very strict requirements for wastewater pretreatment and their own processes are relatively complicated. The one-time investment is relatively large, which is unbearable for some small and medium-sized enterprises.
Affected by its own dephenolization process and dephenolization efficiency, the operating costs of conventional methods for treating phenolic wastewater are relatively high
Moreover, the dephenolization efficiency is not high, the treatment is not thorough, and secondary pollution is easy to form, which is another key point that restricts the popularization and application of certain dephenolization methods

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0054] A water treatment agent for removing phenolic compounds in water, comprising the following raw materials by weight fraction:

[0055] 12 parts of γ-terpinene,

[0056]18 parts of 3-phenyl-2-propyl acrylate,

[0057] Rabeprazole 1 part,

[0058] 18 parts of ferric ammonium oxalate,

[0059] α-Cubene 16 parts,

[0060] 0.8 part of oxadiazolone,

[0061] Methoxypyridine 11 parts,

[0062] Vinyl laurate 13 parts,

[0063] 15 parts of ferric chloride,

[0064] 5 parts of asiaticoside,

[0065] Phthalsulfathiazole 2 parts,

[0066] 3 parts of 3-nonen-2-one,

[0067] 20 parts polyacrylamide,

[0068] [R-(R*,R*)]-2,3,4-trihydroxybutyraldehyde 8 parts,

[0069] Fucoxanthin 8 parts,

[0070] 2-hydroxyethyl cellulose 4 parts.

[0071] Before treatment: 1L water sample contains m-cresol 10mg, 2,4,6-trichlorophenol 10mg, p-nitrophenol 5mg, add 50mg of this water treatment agent;

[0072] After treatment: m-cresol 0.01mg, 2,4,6-trichlorophenol and p-nitrophenol were not...

Embodiment 2

[0074] A water treatment agent for removing phenolic compounds in water, comprising the following raw materials by weight fraction:

[0075] 18 parts of γ-terpinene,

[0076] 25 parts of 3-phenyl-2-propyl acrylate,

[0077] Rabeprazole 1 part,

[0078] 18 parts of ferric ammonium oxalate,

[0079] α-Cubene 15 parts,

[0080] 0.8 part of oxadiazolone,

[0081] Methoxypyridine 10 parts,

[0082] Vinyl laurate 12 parts,

[0083] 13 parts of ferric chloride,

[0084] 4 parts of asiaticoside,

[0085] Phthalsulfathiazole 3 parts,

[0086] 4 parts of 3-nonen-2-one,

[0087] 22 parts polyacrylamide,

[0088] [R-(R*,R*)]-2,3,4-trihydroxybutyraldehyde 10 parts,

[0089] Fucoxanthin 9 parts,

[0090] 5 parts of 2-hydroxyethyl cellulose.

[0091] Before treatment: 1L water sample contains 10mg of phenol, 10mg of 2,4-dichlorophenol, 5mg of p-nitrophenol, add 50mg of this water treatment agent;

[0092] After treatment: phenol, 2,4-dichlorophenol and p-nitrophenol were not de...

Embodiment 3

[0094] A water treatment agent for removing phenolic compounds in water, comprising the following raw materials by weight fraction:

[0095] γ-terpinene 15 parts,

[0096] 20 parts of 3-phenyl-2-propyl acrylate,

[0097] Rabeprazole 0.8 part,

[0098] 18 parts of ferric ammonium oxalate,

[0099] α-Cubene 15 parts,

[0100] 0.8 part of oxadiazolone,

[0101] Methoxypyridine 12 parts,

[0102] Vinyl laurate 12 parts,

[0103] 15 parts of ferric chloride,

[0104] 6 parts of asiaticoside,

[0105] Phthalsulfathiazole 3 parts,

[0106] 4 parts of 3-nonen-2-one,

[0107] 24 parts polyacrylamide,

[0108] [R-(R*,R*)]-2,3,4-trihydroxybutyraldehyde 9 parts,

[0109] Fucoxanthin 8 parts,

[0110] 5 parts of 2-hydroxyethyl cellulose.

[0111] Before treatment: 1L water sample contains m-cresol 20mg, 2,4,6-trichlorophenol 18mg, 2,4-dichlorophenol 12mg, add 50mg of this water treatment agent;

[0112] After treatment: No mesocresol, 2,4-dichlorophenol and 2,4,6-trichlorophe...

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PUM

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Abstract

The invention relates to a water treatment agent for removing phenolic compounds from water. The water treatment agent is composed of Nu-terpinene, 3-phenyl-2-acrylic acid n-propyl ester, rabeprazole, iron ammonium oxalate, Alpha-copaene, climbazole, buflomedil, vinyl laurate, ferric chloride, asiaticoside, phthalylsulfathiazole, 3-nonene-2-one, polyacrylamide, (R-(R*, R*))-2, 3, 4-trihydroxybutyraldehyde, fucoxanthine, and 2-hydroxyethyl cellulose. The water treatment agent is highly able to complex with the phenolic compound, complex precipitate forms fast, the removal rate of the phenolic compounds is up to 99%, toxicity is low, little usage is required, no hazard is caused to the water, and treatment cost is low.

Description

technical field [0001] The invention relates to a water treatment agent for removing phenolic compounds in water, belonging to the technical field of environmental protection. Background technique [0002] Phenolic compounds are protoplasmic poisons, which can produce toxicity to all biologically active bodies and cause cell damage. High-concentration phenol solution can coagulate protein and continue to penetrate into the body, causing deep tissue damage, necrosis and even systemic poisoning. Even low-concentration phenol solution can also denature protein. Phenolic wastewater not only poses a serious threat to human health, but also harms animals and plants. The treatment of phenolic wastewater has always been a major problem in the field of sewage treatment at home and abroad. In my country, phenol, m-cresol, 2,4-dichlorophenol, 2,4,6-trichlorophenol, pentachlorophenol, and p-nitrophenol are listed as phenolic pollutants for priority control. [0003] Domestic dephen...

Claims

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Application Information

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IPC IPC(8): C02F1/00C02F1/58
CPCY02W10/37
Inventor 缪琼华
Owner 佛山亚特表面技术材料有限公司
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