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Purifier and preparation method thereof

A purifier and alumina powder technology, applied in ceramic products, other household utensils, applications, etc., can solve the problems of complex synthesis process, high brittleness, strong ionic bond, etc., and achieve simple and efficient preparation method, small thermal expansion coefficient, The effect of high compressive strength

Inactive Publication Date: 2016-03-16
宁波科森净化器制造有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Precipitation encapsulation method and sol-gel method have relatively strict process requirements, complex synthesis process, raw materials are mostly organic compounds, expensive, and some are harmful to human body, so it is difficult to meet the requirements of industrial applications
In terms of improving the properties of cordierite ceramics by adding additives, most of the additives are a single component, and the average thermal expansion coefficient is often small, but there is a large difference in the thermal expansion coefficients of the a-axis and c-axis, and it is difficult to make "zero expansion" Harmonizes with anisotropic thermal effects, thereby reducing the thermal performance of cordierite ceramics
[0006] Alumina is also a common ceramic material, which has many excellent properties such as high temperature resistance, wear resistance, corrosion resistance, and oxidation resistance. High energy, low diffusion coefficient, high sintering temperature, and its application is limited due to its high brittleness and high thermal expansion coefficient, so it is urgent to find an effective method to solve the above problems.

Method used

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  • Purifier and preparation method thereof

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Effect test

preparation example Construction

[0035] The preparation method of the purifier of the present invention comprises the following steps:

[0036] 1) Preparation of ceramic slurry: Mix the alumina powder, sintering aids, rare earth oxides and binders evenly to obtain mixed powder, and mix the mixed powder with water in a mass ratio of (80-85):100. Mixing, then adding carbon fiber, dispersing evenly to obtain ceramic slurry;

[0037] 2) forming a blank to obtain a blank;

[0038] 3) Sintering: a. After sintering the green body at 1100-1200℃ for 60-90min under normal pressure, b. Adjust the pressure to 20MPa, adjust the temperature to 800-1000℃ and continue sintering for 30-60min, c. Heat preservation at 700°C for 90-120min to obtain a honeycomb ceramic carrier;

[0039] 4) carrier coating and dipping: the slurry solution is coated on the surface of the prepared honeycomb ceramic carrier, and after drying treatment, the carrier is put into the active component solution containing palladium, platinum and rhodium ...

Embodiment 1

[0043] The purifier of this embodiment includes a housing and a honeycomb ceramic carrier. The honeycomb ceramic carrier is arranged in the housing. The porous structure of the honeycomb ceramic carrier includes a curved serpentine channel and a straight channel. The straight channel is connected to the serpentine channel. The components of the carrier and their mass fractions include: sintering aid: 6%, rare earth oxide: 5%, methyl cellulose: 4%, carbon fiber: 2%, and the remaining 83% is alumina powder. The sintering aids are MgO and CaO with a mass ratio of 1:1, and the rare earth oxides can be one or two of rare earth oxides such as lanthanum oxide, cerium oxide, rubidium oxide, praseodymium oxide, dysprosium oxide, promethium oxide, etc. A mixture of two or more. The length ratio of the straight channel to the serpentine channel is 5:3, and the average wall thickness of the honeycomb ceramic is 1mm.

Embodiment 2

[0045] The purifier of this embodiment includes a housing and a honeycomb ceramic carrier. The honeycomb ceramic carrier is arranged in the housing. The porous structure of the honeycomb ceramic carrier includes a curved serpentine channel and a straight channel. The straight channel is connected to the serpentine channel. The components of the carrier and their mass fractions include: sintering aid: 7%, rare earth oxide: 4%, methyl cellulose: 2%, carbon fiber: 2%, and the remaining 85% is alumina powder. The sintering aids are MgO and SiO with a mass ratio of 2:1:1 2 and Fe 2 O 3 The rare earth oxide can be one or a mixture of two or more rare earth oxides such as lanthanum oxide, cerium oxide, rubidium oxide, praseodymium oxide, dysprosium oxide, and promethium oxide. The length ratio of the straight channel and the serpentine channel is 5:2, and the average wall thickness of the honeycomb ceramic is 1.5mm.

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Abstract

The invention discloses a purifier and a preparation method thereof. The purifier comprises a shell and a honeycomb ceramic carrier, wherein the honeycomb ceramic carrier is arranged in the shell; the porous structure of the honeycomb ceramic carrier comprises S-shaped passages and straight passages; the straight passages are communicated with the S-shaped passages; the honeycomb ceramic carrier comprises the following ingredients by mass: 6 to 10 percent of sintering additives, 2 to 5 percent of one or more rare earth oxides, 2 to 4 percent of a binding agent, 1 to 2 percent of carbon fiber, and the balance of aluminum oxide powder. According to the preparation method, the particle diameter of aluminum oxide is reduced, and rare earth oxide and carbon fiber are added, so that the carrier is high in compressive strength, low in thermal expansion coefficient, and relatively low in sintering temperature; the preparation method is simple and efficient, and is suitable for mass production of purifiers.

Description

technical field [0001] The invention relates to the field of automobile exhaust gas purification, in particular to a purifier and a preparation method thereof. Background technique [0002] With the increasingly prominent air pollution problem and the rapid increase in the number of automobiles, the exhaust gas emitted by automobiles has become one of the main sources of urban air pollution. The harmful substances in automobile exhaust mainly include CO, NOx and HC, polycyclic aromatic hydrocarbons (PAH) and suspended solids (SPM). NOx and HC undergo a series of photochemical reactions in the atmosphere, and easily generate a variety of highly oxidizing substances such as ozone, forming photochemical smog. Photochemical smog not only seriously harms human health, but also causes serious damage to animals, plants and various materials. [0003] The purifier is the most important external purification device installed in the automobile exhaust system. It can convert the harm...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B38/00C04B41/89C04B35/10C04B35/80
Inventor 戎永波周巧燕余勇陈培华张国文
Owner 宁波科森净化器制造有限公司