Preparation method of low stress state composite substrate for GaN growth

A composite substrate, low stress technology, applied in electrical components, circuits, semiconductor devices, etc., can solve the problems of GaN epitaxial film wrinkling, poor high temperature stability, stress residual and other problems, to improve the quality of epitaxial growth, good thermal conductivity and electrical conductivity, The effect of suppressing the wrinkle of the epitaxial film

Active Publication Date: 2016-04-20
SINO NITRIDE SEMICON
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

The patent (patent application number: 201210068033.0 and patent application number: 201210068026.0) describes the preparation of a composite substrate for GaN growth based on low-temperature bonding and laser lift-off technology and its preparation method, but previously used dielectric bonding and laser The following problems exist in the preparation of thermally and electrically conductive GaN composite substrates by the lift-off process: (1) In the past, lower temperatures below 600°C were mainly used for bonding, and the high temperature stability was poor. The combined structure will change again, which will seriously affect the quality of homoepitaxial and chip preparation in the later stage; (2) The changes in the substrate transfer process and thermal and conductive substrates will generate greater stress in the transferred substrate, resulting in composite substrates Some warping occurs, even wrinkles are formed on the GaN epitaxial film, making it difficult to achieve high-performance GaN single crystal epitaxy and chip preparation
Poor high temperature stability and severe stress residue are the main reasons restricting the further application of substrate transfer technology on high-performance GaN composite substrates

Method used

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  • Preparation method of low stress state composite substrate for GaN growth
  • Preparation method of low stress state composite substrate for GaN growth
  • Preparation method of low stress state composite substrate for GaN growth

Examples

Experimental program
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Effect test

Embodiment 1

[0044] Embodiment 1: Using Ni as the stress compensation layer, conductive Agpaste bonding CuMo metal substrate and GaN epitaxial layer, obtain the preparation method of the low stress state composite substrate used for GaN growth:

[0045] (1) Epitaxial growth of a GaN single crystal layer on a sapphire substrate: On a 2-inch 430-micron-thick flat sapphire substrate, first use MOCVD technology to epitaxially grow a 4-micron-thick GaN single-crystal layer, and then grow thicker in HVPE The thickness of the GaN layer is up to 15 microns.

[0046] (2) use magnetron sputtering deposition thickness to be the Ni thin layer of 500 nanometers on the back side of 300 microns thick CuMo metal substrate (wherein the mass percentage of Mo and Cu is respectively 20% to 80%), as stress compensation layer, as Figure 4 (a) shown.

[0047] (3) On the GaN surface of the above-mentioned sapphire-based GaN composite substrate and the front surface of the CuMo substrate with a thickness of 300 ...

Embodiment 2

[0049] Example 2: Using Au / Pd as the stress compensation layer, Ti / Pd bonded Si substrate and adhesively transferred GaN epitaxial layer to obtain a low-stress state composite substrate for GaN growth with the gallium polarity facing outward Preparation:

[0050] (1) Preparation of adhesive transfer sapphire-based GaN composite substrate: On a 2-inch 430-micron-thick flat sapphire substrate, a 4-micron-thick GaN single crystal layer is epitaxially grown by MOCVD technology, and then grown in HVPE to thicken GaN layer thickness to 15 microns, and then use UV anaerobic adhesive to bond the GaN epitaxial film to a 2-inch 430-micron thick sapphire temporary substrate, the new sapphire substrate is used as a transfer support substrate, and then the original The epitaxial sapphire substrate is removed, and the GaN single crystal layer bonded on the new sapphire substrate is obtained, such as Figure 5 a) as shown.

[0051] (2) On the back of the Si substrate with a thickness of 30...

Embodiment 3

[0054] Example 3: Using SiN x As a stress compensation layer, AuAu bonded AlSi metal substrate and GaN epitaxial layer to obtain the preparation method of the low stress state composite substrate for GaN growth, the specific process steps are as follows (such as Image 6 shown):

[0055] (1) Epitaxial growth of a GaN single crystal layer on a sapphire substrate: On a 2-inch 430-micron-thick flat sapphire substrate, first use MOCVD technology to epitaxially grow a 4-micron-thick GaN single-crystal layer, and then grow thicker in HVPE The thickness of the GaN layer is up to 15 microns.

[0056] (2) Using plasma-enhanced chemical vapor deposition to prepare SiN with a thickness of 5 microns on the back of a 150 micron thick AlSi metal substrate (wherein the composition of Al is 30%, and the composition of Si is 70%) x thin layer, as a stress compensation layer.

[0057] (3) On the GaN surface of the above-mentioned sapphire-based GaN composite substrate, use magnetron sputteri...

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Abstract

The invention discloses a preparation method of a low stress state composite substrate for GaN growth. The preparation method comprises that a GaN monocrystal epitaxial layer is prepared on a sapphire substrate; a stress compensation layer is deposited at the back side of a thermally and electrically conductive transfer substrate of high welding point; bonding dielectric layers of high welding point are prepared at the surfaces of a GaN epitaxial wafer and the transfer substrate respectively; the GaN epitaxial wafer is bonded to the thermally and electrically conductive substrate by the high-temperature diffusion bonding technology; and the composite substrate with high temperature stability and low stress state for GaN growth is obtained. According to the composite substrate of the invention, homoepitaxy can be realized and a vertical structural device can be directly prepared as a traditional composite substrate, the low stress state and high-temperature stability can be also realized, and the quality of subsequent GaN epitaxial growth and chip preparation can be effectively improved.

Description

technical field [0001] The invention relates to the technical field of semiconductor optoelectronic devices, in particular to transferring a GaN epitaxial film to a thermally conductive substrate by using a high-temperature diffusion bonding process, and combining a stress compensation layer to realize a low-stress thermally conductive composite substrate for GaN homoepitaxial growth method of preparation. Background technique [0002] Wide bandgap GaN-based semiconductor materials have excellent optoelectronic properties and have been widely used in the production of light-emitting diodes, lasers, ultraviolet detectors and high-temperature, high-frequency, high-power electronic devices, and can be applied to the preparation of high-end microelectronics required by aerospace Devices, such as high-mobility transistors (HEMTs) and heterojunction transistors (HFETs), have become research hotspots in the international optoelectronics field. [0003] Since the preparation of GaN...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L33/00H01L33/12H01L33/20
Inventor 汪青孙永健陈志忠张国义童玉珍
Owner SINO NITRIDE SEMICON
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