Deformation adaptive macromolecule bearing composite material and preparation method and application thereof
A composite material, self-adaptive technology, used in bearing components, shafts and bearings, chemical instruments and methods, etc., can solve the problems of low speed friction coefficient, stick-slip noise, stress concentration bearing damage, etc., to improve wear resistance. , No stick-slip noise, the effect of improving impact resistance
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[0034] The preparation method of deformable self-adaptive polymer bearing composite material, the steps are as follows:
[0035] Step 1. According to the requirements of the above-mentioned elastic intermediate layer, the isocyanate and polyol are reacted to obtain polyurethane prepolymer, and then the chain extender and the polyurethane prepolymer are used for chain extension reaction to obtain the mixture, and then the mixture is poured on the fiber reinforced resin composite material And curing and molding under the conditions of 90~130℃, 1~30min, to obtain the elastic intermediate layer;
[0036] Step 2. According to the requirements of the friction surface layer, the isocyanate and the lubricant are mixed uniformly, and then reacted with the polyol to obtain a polyurethane prepolymer, and then the chain extender and the polyurethane prepolymer are used for chain extension reaction to obtain the mixture, and then the mixture It is poured onto the elastic middle layer, and cured...
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[0039] Example 1
[0040] Preparation of Deformation Adaptive Polymer Bearing Composite:
[0041] Such as figure 1 As shown, 1 mol of polytetrahydrofuran polyol (molecular weight 2000g / mol, average functionality of 2) was reacted with 3 mol of MDI at 70°C for 2 hours to obtain a prepolymer with a mass percentage of NCO groups of 5.6%, and then 1.8 mol of 1,4-butanediol and prepolymer were used for chain extension reaction, the reaction temperature was 40℃, and the time was 10min to obtain the mixture. The mixture was poured on the outer wall of the glass fiber reinforced epoxy resin cylinder by a centrifuge. , After curing and molding, an elastic intermediate layer with a hardness of 75 Shore A is obtained;
[0042] Mix 0.7 mol polycarbonate polyol (molecular weight 2000g / mol, average functionality 2), 0.3 mol polypropylene oxide polyol (molecular weight 400g / mol, average functionality 2) and 76g molybdenum disulfide. Then react with 5mol of TDI at 60℃ for 3h to obtain a prepolymer...
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[0043] Example 2
[0044] Preparation of Deformation Adaptive Polymer Bearing Composite Material:
[0045] Such as figure 2 As shown, 1 mol of polycaprolactone polyol (molecular weight 2000g / mol, average functionality is 2.2) is reacted with 2.2 mol of PPDI at 70°C for 3 hours to obtain a prepolymer with a mass percentage of NCO groups of 3.9% Then, 0.80 mol of 2-methyl-propylene glycol is used for chain extension reaction with the prepolymer. The reaction temperature is 70°C and the time is 10 minutes to obtain the mixture. Then the carbon fiber reinforced unsaturated polyester fiber board is placed in the mold and centrifuged. The machine casts the mixture on the carbon fiber reinforced unsaturated polyester fiber board, and after curing and molding, an elastic middle layer with a hardness of 80 Shore A is obtained;
[0046] 0.2mol polycarbonate polyol (molecular weight 2000g / mol, average functionality 2), 0.8mol polytetrahydrofuran ether polyol (molecular weight 1000g / mol, aver...
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