Preparation method of water-soluble modified starch resin

A starch resin and water-soluble technology, which is applied in the field of preparation of water-soluble modified starch resin, can solve the problem of long-term anti-icing without relevant research and investigation, no effective solution for water condensation or sublimation icing, and unable to meet the long-lasting anti-icing Icing performance and other issues, to meet the long-term requirements, to meet the hydrophilicity and anti-icing performance, good substrate adhesion effect

Inactive Publication Date: 2016-12-21
合肥普庆新材料科技有限公司
View PDF7 Cites 2 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Existing anti-icing/frost technology mainly adopts super-hydrophobic surface treatment, such as Chinese patent CN 104341901 A discloses a kind of organic-inorganic system coating, uses acrylic resin as film-forming material, adds diatomite, carbon black, isocyanate, hexadecimal Sodium phosphate and silicone defoamer are blended and melted to prepare a wear-resistant anti-icing coating; Chinese patent CN 103013316 A "a super-weather-resistant, wear-resistant and anti-icing wind power blade coating and its preparation method" discloses a Organic-inorganic system coatings, fluorocarbon resins and polyester resins as film-forming materials, supplemented with nano-fillers and dispersants to prepare wear-resistant, weather-resistant, and anti-icing wind turbine blade coatings. These surfaces are controlled by certain surface mor

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Preparation method of water-soluble modified starch resin
  • Preparation method of water-soluble modified starch resin
  • Preparation method of water-soluble modified starch resin

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0070] 1. Preparation of hydrophilic acrylic starch modified superabsorbent resin:

[0071] Basic formula (parts by weight):

[0072] N, N dimethylbisacrylamide 5, acrylamide 50, starch 80, acrylic acid 50, ammonium persulfate 5, water 120, propylene glycol methyl ether 2, ethylene glycol butyl ether 20, water 100 (residual water).

[0073] According to the basic formula, mix N,N dimethylbisacrylamide, acrylamide, starch, acrylic acid, and water at a temperature of 80°C for 1 hour, add ammonium persulfate and the rest of water dropwise for 2 hours, and then keep warm for 10 hours to obtain a hydrophilic Acrylic starch modified superabsorbent resin.

[0074] 2. Preparation of anti-icing hydrophilic coating:

[0075] Basic formula (parts by weight):

[0076] Hydrophilic acrylic starch modified superabsorbent resin 80, sodium silicate 200, water-based acrylic polyurethane 30, polyethylene glycol 50, water 50, defoamer 2, dispersant 4, wetting agent 1.2, pH regulator 0.5, Rheo...

Embodiment 2

[0094] 1. Preparation of hydrophilic acrylic starch modified superabsorbent resin:

[0095] Basic formula (parts by weight):

[0096] N, N dimethylbisacrylamide 10, acrylamide 20, starch 100, acrylic acid 25, ammonium persulfate 10, water 80, propylene glycol methyl ether 10, ethylene glycol butyl ether 10, water 140 (residual water).

[0097] According to the basic formula, mix N,N dimethylbisacrylamide, acrylamide, starch, acrylic acid, and water at a temperature of 50°C for 1 hour, add ammonium persulfate and the rest of water dropwise for 2 hours, and then keep warm for 10 hours to obtain a hydrophilic Acrylic starch modified superabsorbent resin.

[0098] 2. Preparation of anti-icing hydrophilic coating:

[0099] Basic formula (parts by weight):

[0100] Hydrophilic acrylic starch modified superabsorbent resin 200, sodium silicate 100, water-based acrylic polyurethane 25, polyethylene glycol 60, water 90, defoamer 1, dispersant 8, wetting agent 0.5, pH regulator 7, Rh...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention relates to the technical field of anti-icing coatings, in particular to a preparation method of water-soluble modified starch resin. The water-soluble modified starch resin is formed by copolymerizing 70-110 parts of soluble starch, 20-55 parts of a water-soluble acid or salt monomer containing one double bond, 1-30 parts of a water-soluble hydroxy monomer containing one double bond, 15-55 parts of a water-soluble nitrogen-containing monomer containing one double bond, 1-20 parts of a water-soluble crosslinking monomer containing two double bonds, 50-150 parts of water and 1-20 parts of a water-soluble thermal initiator; a water-based organic-inorganic hybrid anti-icing coating is prepared from water-based resin, a curing agent, a filler, a surfactant and a solvent; an aluminum foil which is subjected to degreasing, washing with deionized water and drying, and treatment with coating type zirconate is coated with the prepared coating, so as to obtain an anti-icing coating aluminum foil with icing resistance. The water-soluble modified starch resin prepared in the invention is particularly suitable for the treatment of air-conditioning coating aluminum foils, refrigerator/freezer liners and other heat exchange surfaces.

Description

technical field [0001] The invention relates to the technical field of anti-icing coatings, in particular to a preparation method of water-soluble modified starch resin. Background technique [0002] In transportation, aerospace, heat exchange, power communication and many other fields, icing / frost has brought great harm and potential safety hazards to human beings and society. Although the existing anti-icing methods such as mechanical deicing, heating deicing and spraying chemical reagents are effective, they have problems such as large energy consumption, environmental pollution and poor durability. The use of anti-icing functional coatings to modify the surface of substrates is convenient and effective, and sacrificial coatings, ice-phobic coatings and super-hydrophobic coatings have become research hotspots. [0003] Existing anti-icing / frost technology mainly adopts super-hydrophobic surface treatment, such as Chinese patent CN 104341901 A discloses a kind of organic-...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C08F251/00C08F220/56C08F220/06C09D151/02C09D175/14C09D163/10C09D5/08C09D7/12
CPCC08F251/00C08L2205/03C09D5/08C09D151/02C09D163/10C09D175/14C08F220/56C08F220/06C08L75/14C08L71/02C08K3/34C08L63/10C08K3/24C08K3/32
Inventor 何宗文候伟
Owner 合肥普庆新材料科技有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap