Lithium battery positive body employing aluminum phosphate foam glass as current collector and preparation method
A technology of foam glass and aluminum phosphate, applied in electrode manufacturing, battery electrodes, secondary batteries, etc., to achieve the effects of improving cycle life, preventing collapse, and requiring less equipment
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Embodiment 1
[0028] A method for preparing a lithium battery anode body using aluminum phosphate foam glass as a current collector, which specifically includes the following steps:
[0029] (1) Ferric phosphate, lithium hydroxide, and oxalic acid are prepared as a precursor solution, dispersed in ethylene glycol, and ultrasonically treated at room temperature to obtain a lithium-ion battery cathode material precursor dispersion;
[0030] (2) After crushing glass, aluminum phosphate, sodium carbonate, urea, sodium phosphate, and calcium sulfate, they are mixed and ball-milled by dry method, and mixed with mullite fiber; put into a flat mold, sintered and formed, and after cooling, flake phosphoric acid is obtained Aluminum foam glass; glass: 80 parts; aluminum phosphate: 15 parts; sodium carbonate: 3 parts; urea: 1 part; sodium phosphate: 1 part; calcium sulfate: 1 part;
[0031] (3) Immerse the sheet-shaped aluminum phosphate foam glass obtained in step (2) into the lithium-ion battery cat...
Embodiment 2
[0035] A method for preparing a lithium battery anode body using aluminum phosphate foam glass as a current collector, which specifically includes the following steps:
[0036] (1) Dispersing the precursor of lithium cobaltate in acetone, and ultrasonically treating it at room temperature, to obtain the dispersion liquid of the precursor of lithium ion battery positive electrode material;
[0037] (2) After glass, aluminum phosphate, sodium nitrate, ethylenediamine, rosin, boric acid, calcium sulfate, and aluminum oxide are crushed, they are mixed with ball mills in a dry process and mixed with slag fibers; they are put into a flat mold and sintered to form, After cooling, flake aluminum phosphate foam glass is obtained; glass: 70 parts; aluminum phosphate: 20 parts; sodium nitrate and ethylenediamine: 7 parts; rosin: 1 part; boric acid: 1 part; Aluminum oxide: 1 part;
[0038] (3) Immerse the sheet-shaped aluminum phosphate foam glass obtained in step (2) in the lithium-ion ...
Embodiment 3
[0041] A method for preparing a lithium battery anode body using aluminum phosphate foam glass as a current collector, which specifically includes the following steps:
[0042] (1) Disperse the nickel cobalt lithium manganese oxide precursor in ethylene glycol and absolute ethanol, and perform ultrasonic treatment at room temperature to obtain a lithium ion battery cathode material precursor;
[0043] (2) After crushing glass, aluminum phosphate, sodium fluorosilicate, urea, iron oxide, and barium sulfate, they are mixed and ball-milled by dry method and mixed with glass fibers; they are put into flat molds, sintered and formed, and flake phosphoric acid is obtained after cooling Aluminum foam glass; glass: 60 parts; aluminum phosphate: 17.5%; sodium fluorosilicate: 9%; urea: 10 parts; iron oxide: 2 parts; barium sulfate: 1.5 parts;
[0044] (3) Immerse the sheet-shaped aluminum phosphate foam glass obtained in step (2) into the lithium-ion battery cathode material precursor o...
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