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Lithium battery positive body employing aluminum phosphate foam glass as current collector and preparation method

A technology of foam glass and aluminum phosphate, applied in electrode manufacturing, battery electrodes, secondary batteries, etc., to achieve the effects of improving cycle life, preventing collapse, and requiring less equipment

Active Publication Date: 2017-08-15
上海太洋科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the above-mentioned method of coating the positive electrode active material with aluminum phosphate cannot be easily applied to the treatment of lithium-ion battery current collectors.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] A method for preparing a lithium battery anode body using aluminum phosphate foam glass as a current collector, which specifically includes the following steps:

[0029] (1) Ferric phosphate, lithium hydroxide, and oxalic acid are prepared as a precursor solution, dispersed in ethylene glycol, and ultrasonically treated at room temperature to obtain a lithium-ion battery cathode material precursor dispersion;

[0030] (2) After crushing glass, aluminum phosphate, sodium carbonate, urea, sodium phosphate, and calcium sulfate, they are mixed and ball-milled by dry method, and mixed with mullite fiber; put into a flat mold, sintered and formed, and after cooling, flake phosphoric acid is obtained Aluminum foam glass; glass: 80 parts; aluminum phosphate: 15 parts; sodium carbonate: 3 parts; urea: 1 part; sodium phosphate: 1 part; calcium sulfate: 1 part;

[0031] (3) Immerse the sheet-shaped aluminum phosphate foam glass obtained in step (2) into the lithium-ion battery cat...

Embodiment 2

[0035] A method for preparing a lithium battery anode body using aluminum phosphate foam glass as a current collector, which specifically includes the following steps:

[0036] (1) Dispersing the precursor of lithium cobaltate in acetone, and ultrasonically treating it at room temperature, to obtain the dispersion liquid of the precursor of lithium ion battery positive electrode material;

[0037] (2) After glass, aluminum phosphate, sodium nitrate, ethylenediamine, rosin, boric acid, calcium sulfate, and aluminum oxide are crushed, they are mixed with ball mills in a dry process and mixed with slag fibers; they are put into a flat mold and sintered to form, After cooling, flake aluminum phosphate foam glass is obtained; glass: 70 parts; aluminum phosphate: 20 parts; sodium nitrate and ethylenediamine: 7 parts; rosin: 1 part; boric acid: 1 part; Aluminum oxide: 1 part;

[0038] (3) Immerse the sheet-shaped aluminum phosphate foam glass obtained in step (2) in the lithium-ion ...

Embodiment 3

[0041] A method for preparing a lithium battery anode body using aluminum phosphate foam glass as a current collector, which specifically includes the following steps:

[0042] (1) Disperse the nickel cobalt lithium manganese oxide precursor in ethylene glycol and absolute ethanol, and perform ultrasonic treatment at room temperature to obtain a lithium ion battery cathode material precursor;

[0043] (2) After crushing glass, aluminum phosphate, sodium fluorosilicate, urea, iron oxide, and barium sulfate, they are mixed and ball-milled by dry method and mixed with glass fibers; they are put into flat molds, sintered and formed, and flake phosphoric acid is obtained after cooling Aluminum foam glass; glass: 60 parts; aluminum phosphate: 17.5%; sodium fluorosilicate: 9%; urea: 10 parts; iron oxide: 2 parts; barium sulfate: 1.5 parts;

[0044] (3) Immerse the sheet-shaped aluminum phosphate foam glass obtained in step (2) into the lithium-ion battery cathode material precursor o...

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PUM

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Abstract

The invention provides a lithium battery positive body employing aluminum phosphate foam glass as a current collector and a preparation method. The method comprises the steps of carrying out colloidal reaction on a precursor of a positive material for a lithium battery in flake aluminum phosphate foam glass and sintering to form a novel positive body employing the aluminum phosphate foam glass as the current collector. The novel positive body is different from the positive body formed by coating the current collectors, such as aluminum foil with different positive materials, and is a novel positive body formed by reacting the precursor of the positive material in glass foam cells and sintering into a whole, and the novel positive body has good micro-elasticity, and can be directly cut and assembled, and an adhesive does not need to be added in use. The lithium battery positive body has the significant effects that the adhesive and the aluminum foil for preparing a positive plate are reduced and relatively high energy density is ensured. The positive material is stabilized by the foam glass micro-elasticity of a lattice structure in the charge and discharge processes to prevent collapse of the lattice structure, and the cycle life of a positive electrode of the lithium battery is effectively prolonged.

Description

technical field [0001] The invention belongs to the field of lithium ion battery materials, and in particular relates to a lithium battery anode body using aluminum phosphate foam glass as a current collector and a preparation method thereof. Background technique [0002] Lithium-ion battery, as a new generation of green high-energy rechargeable battery, has achieved rapid development in the past 20 years due to its outstanding advantages such as high voltage, high energy density, good cycle performance, small self-discharge and environmental friendliness since it came out in 1990. It is widely used as the power source of precious and heavy household appliances such as mobile phones, portable computers, video cameras, cameras, etc. At present, the cathode materials of lithium-ion batteries mainly include lithium cobalt oxide, lithium iron phosphate, and high-nickel cathode materials. Lithium-ion battery is the battery with the highest voltage and the largest energy density a...

Claims

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Application Information

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IPC IPC(8): H01M4/66H01M4/80H01M4/136H01M4/1397H01M4/04H01M10/0525
CPCH01M4/0416H01M4/0471H01M4/136H01M4/1397H01M4/664H01M4/666H01M4/805H01M4/808H01M10/0525Y02E60/10
Inventor 陈庆王镭迪曾军堂
Owner 上海太洋科技有限公司
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