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Heat-resistant and anti-corrosion 3D printing material for electronic engineering and preparation method thereof

A 3D printing and electronic engineering technology, applied in the field of 3D printing materials, it can solve the problems of macromolecular fracture, easy loss of electrons, material aging, etc.

Inactive Publication Date: 2017-09-08
HEFEI SKE INTELLIGENT TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Polyphenylene sulfide was developed in the late 20th century with good heat resistance, superior chemical corrosion resistance and flame retardancy, excellent electrical insulation properties and good dimensional stability, but due to the molecular structure of polyphenylene sulfide resin Sulfur exists in a divalent state. The electrons in the outermost layer of sulfur are unstable, and it is easy to lose electrons and combine with oxygen, resulting in oxidative degradation, macromolecular breakage, and macroscopic manifestations of material aging, damage, and shortened service life, so its application is limited.
However, polyphenylene sulfide is one of the 3D printing materials, and its heat-resistant and anti-corrosion properties cannot meet the needs of actual use. Therefore, it is urgent to design a heat-resistant and anti-corrosion 3D printing material for electronic engineering to solve the problems in the prior art.

Method used

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  • Heat-resistant and anti-corrosion 3D printing material for electronic engineering and preparation method thereof
  • Heat-resistant and anti-corrosion 3D printing material for electronic engineering and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0016] A heat-resistant and anti-corrosion 3D printing material for electronic engineering proposed by the present invention, its raw materials include by weight: 100 parts of modified polyphenylene sulfide, 25 parts of EPDM rubber, 10 parts of styrene-butadiene rubber, and 6 parts of epoxy resin 4.5 parts of polyurethane acrylate, 3.5 parts of melamine hydrobromide, 2.5 parts of EPDM rubber, 5.5 parts of polyphosphate amine, 4.5 parts of aluminum hydroxide, 6 parts of talcum powder, 3 parts of mica iron oxide, 3.5 parts of zinc oxide , 4 parts of magnesium oxide, 4.5 parts of asbestos fiber, 4 parts of glass fiber, 4.5 parts of nano-titanium dioxide, 3.5 parts of ethyl orthosilicate, 3 parts of silane coupling agent KH-560, 4.5 parts of trioctyl trimellitate, hard 4 parts of sodium fatty acid, 6 parts of dioctyl phthalate, 3.5 parts of dicumyl peroxide, 2.5 parts of m-xylylenediamine, 4.5 parts of benzotriazole, 4 parts of ammonium polyphosphate, dimethyl phosphate 6 parts of...

Embodiment 2

[0021] A heat-resistant and anti-corrosion 3D printing material for electronic engineering proposed by the present invention, its raw materials include: 80 parts of modified polyphenylene sulfide, 35 parts of EPDM rubber, 5 parts of styrene-butadiene rubber, and 9 parts of epoxy resin in parts by weight. 3 parts of polyurethane acrylate, 6 parts of melamine hydrobromide, 1 part of EPDM rubber, 8 parts of polyphosphate amine, 3 parts of aluminum hydroxide, 9 parts of talcum powder, 1 part of mica iron oxide, 5 parts of zinc oxide , 3 parts of magnesium oxide, 6 parts of asbestos fiber, 3 parts of glass fiber, 6 parts of nano-titanium dioxide, 2 parts of ethyl orthosilicate, 5 parts of silane coupling agent KH-560, 3 parts of trioctyl trimellitate, hard 5 parts of sodium fatty acid, 3 parts of dioctyl phthalate, 6 parts of dicumyl peroxide, 1 part of m-xylylenediamine, 6 parts of benzotriazole, 3 parts of ammonium polyphosphate, dimethyl phosphate 8 parts of methyl ester, 3 part...

Embodiment 3

[0026]A heat-resistant and anti-corrosion 3D printing material for electronic engineering proposed by the present invention, its raw materials include by weight: 120 parts of modified polyphenylene sulfide, 15 parts of EPDM rubber, 15 parts of styrene-butadiene rubber, and 3 parts of epoxy resin 6 parts of polyurethane acrylate, 1 part of melamine hydrobromide, 4 parts of EPDM rubber, 3 parts of polyphosphate amine, 6 parts of aluminum hydroxide, 3 parts of talcum powder, 5 parts of mica iron oxide, 2 parts of zinc oxide , 5 parts of magnesium oxide, 3 parts of asbestos fiber, 5 parts of glass fiber, 3 parts of nano-titanium dioxide, 5 parts of ethyl orthosilicate, 1 part of silane coupling agent KH-560, 6 parts of trioctyl trimellitate, hard 3 parts of sodium fatty acid, 9 parts of dioctyl phthalate, 1 part of dicumyl peroxide, 4 parts of m-xylylenediamine, 3 parts of benzotriazole, 5 parts of ammonium polyphosphate, dimethyl phosphate 4 parts of methyl ester, 5 parts of liqu...

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PUM

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Abstract

The invention discloses a heat-resistant and anti-corrosion 3D printing material for electronic engineering. The heat-resistant and anti-corrosion 3D printing material for electronic engineering comprises the following raw materials: modified polyphenylene sulfide, ethylene-propylene-diene monomer rubber, butadiene styrene rubber, epoxy resin, polyurethane acrylate, tripolycyanamide hydrobromide, ethylene-propylene-diene monomer rubber, ammonium polyphosphate, aluminum hydroxide, talcum powder, mica iron oxide, zinc oxide, magnesium oxide, asbestos fiber, glass fiber, nano-sized titanium dioxide, ethyl orthosilicate, a silane coupling agent KH-560, trioctyl trimellitate, sodium stearate, dioctyl phthalate, dicumyl peroxide, m-xylylenediamine, phenylpropyl triazole, ammonium polyphosphate, dimethyl methylphosphate, liquid paraffin, a phase solvent, an antioxidant, a defoaming agent and a modified filler. The invention further provides a preparation method of the heat-resistant and anti-corrosion 3D printing material for electronic engineering. The 3D printing material prepared according to the preparation method provided by the invention has excellent heat resistance and corrosion resistance and high in mechanical properties.

Description

technical field [0001] The invention relates to the technical field of 3D printing materials, in particular to a heat-resistant and anti-corrosion 3D printing material for electronic engineering and a preparation method thereof. Background technique [0002] Polyphenylene sulfide is a thermoplastic material with excellent properties. According to its structure, it is mainly divided into two types: polymer linear type and bridging type. Linear polyphenylene sulfide has good dimensional stability due to acid, alkali and high temperature resistance. The nutritional range is relatively wide. Polyphenylene sulfide was developed in the late 20th century with good heat resistance, superior chemical corrosion resistance and flame retardancy, excellent electrical insulation properties and good dimensional stability, but due to the molecular structure of polyphenylene sulfide resin Sulfur exists in a divalent state. The electrons in the outermost layer of sulfur are unstable, and it ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L81/02C08L23/16C08L9/06C08L63/00C08L75/14C08L91/06C08K13/06C08K5/3492C08K3/22C08K3/34C08K7/12C08K3/26C08K5/098B33Y70/00
CPCB33Y70/00C08K2003/222C08K2003/2241C08K2003/2296C08K2003/265C08K2201/011C08K2201/014C08L81/02C08L2201/08C08L2203/20C08L2205/025C08L2205/035C08L2205/08C08L23/16C08L9/06C08L63/00C08L75/14C08L91/06C08K13/06C08K5/34922C08K3/22C08K3/34C08K7/12C08K3/26C08K5/098
Inventor 吕月林
Owner HEFEI SKE INTELLIGENT TECH
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