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Waste material regenerative lead-free bronze alloy and preparation method thereof

A technology of lead-free bronze and waste materials, which is applied in the field of regenerated lead-free bronze alloys from waste materials and its preparation, which can solve the problems of high price and poor corrosion resistance after immersion, and achieve the improvement of corrosion resistance fatigue strength and cavitation corrosion resistance. , The effect of improving the fluidity of the alloy liquid

Active Publication Date: 2017-10-27
河北雄安地一新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The above-mentioned alloys use a large amount of precious metal refined tin and refined bismuth, which are not only expensive, but also have poor corrosion resistance when soaked in acidic and alkaline water environments

Method used

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  • Waste material regenerative lead-free bronze alloy and preparation method thereof
  • Waste material regenerative lead-free bronze alloy and preparation method thereof
  • Waste material regenerative lead-free bronze alloy and preparation method thereof

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preparation example Construction

[0042] The present invention also provides a method for preparing lead-free bronze alloy regenerated from waste materials described in the above technical solution, comprising the following steps:

[0043] (1) first smelting lead-free copper alloy waste and retort charcoal to obtain molten materials;

[0044] (2) refining after mixing the molten material obtained in the step (1) with a refining agent to obtain a refined material;

[0045] (3) The refined material obtained in the step (2), the boron source, the titanium source, the zirconium source and the mixed rare earth are mixed and then subjected to a second smelting to obtain a lead-free bronze alloy regenerated from waste materials.

[0046] In the invention, lead-free copper alloy waste materials and retort charcoal are first smelted to obtain molten materials. In the present invention, the lead-free copper alloy waste material contains tin element, zinc element, bismuth element, selenium element and nickel element. T...

Embodiment 1

[0061] A lead-free bronze alloy regenerated from waste and old materials, comprising the following elements by mass percentage:

[0062] Tin 2.1%, Zinc 4.1%, Bismuth 0.5%, Selenium 0.15%, Nickel 1.2%, Boron 0.01%, Titanium 0.01%, Zirconium 0.01%, Misch 0.01%, Lead 0.03%, Iron 0.25%, Phosphorus 0.04%, Silicon 0.0015%, aluminum 0.0015%, the balance of copper;

[0063] The mixed rare earths include the following components in mass percentage: lanthanum 40%, cerium 50%, praseodymium 9%, neodymium 1.0%.

[0064] A method for preparing lead-free bronze alloy regenerated from waste and old materials, comprising the following steps:

[0065] Cover dry distillation charcoal 2cm higher than the surface of lead-free copper alloy waste, and first melt at 1200°C to obtain molten material. After mixing the molten material and refining agent, refine at 1100°C for 24 hours to obtain refined material. The mass of refining agent It is 0.15% of the molten material, and the refining agent inclu...

Embodiment 2

[0068] A lead-free bronze alloy regenerated from waste and old materials, comprising the following elements by mass percentage:

[0069] Tin 2.7%, Zinc 5.1%, Bismuth 1.0%, Selenium 0.1%, Nickel 0.6%, Boron 0.05%, Titanium 0.04%, Zirconium 0.05%, Misch 0.015%, Lead 0.02%, Iron 0.2%, Phosphorus 0.03%, Silicon 0.0013%, aluminum 0.0014%, the balance of copper;

[0070]The mixed rare earths include the following components in mass percentage: lanthanum 40%, cerium 55%, praseodymium 4%, neodymium 1.0%.

[0071] Cover dry distillation charcoal 3cm higher than the surface of lead-free copper alloy scrap, and first melt at 1250°C to obtain molten material. After mixing the molten material and refining agent, refine at 1150°C for 12 hours to obtain refined material. The mass of refining agent It is 0.4% of the molten material, and the refining agent includes components in mass percentage: 40% fluorite, 30% sodium carbonate, 15% cryolite, 15% calcium carbonate, copper-boron master alloy...

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Abstract

The invention provides waste material regenerative lead-free bronze alloy and belongs to the field of lead-free bronze alloy. The manufacturing cost of the waste material regenerative lead-free bronze alloy is 80 percent that of a newborn resource preparation alloy. The waste material regenerative lead-free bronze alloy has excellent casting performance, free-cutting performance and corrosion-resistant performance, accords with the requirement of international environment-protecting health safety standard, is suitable for a large-scale low-pressure and gravity casting process, can be applied to parts which are soaked in water environments for a long time, and in particular has prominent corrosion resistance and cavitation corrosion resistance in acidic or alkaline water quality environments. Data of the embodiment indicate that the tensile strength of the waste material regenerative lead-free bronze alloy is improved by 25 percent, the elongation percentage is increased by 45 percent, the complete recrystallization temperature of the alloy is increased to more than 500 DEG C, the corrosion-resistant fatigue limit can be increased by above 18 percent, the corrosion-resistant fatigue strength is increased by 30 percent, the flowability of the alloy liquid is improved by 30 to 40 percent, and the cavitation corrosion resistance is improved by 50 percent.

Description

technical field [0001] The invention relates to the field of lead-free bronze alloys, in particular to a lead-free bronze alloy regenerated from waste materials and a preparation method thereof. Background technique [0002] Lead-containing bronze alloys are widely used in machinery manufacturing, electrical instruments, building hardware, drinking water system faucets, valves, pumps, pipe fittings and other fields. The harm to human beings and the environment has become increasingly apparent, and it has become a social problem that people generally pay attention to. Governments of various countries have successively issued restrictions on the use of lead-containing copper alloys. The United States stipulates that the amount of lead leaching in drinking water is less than 0.001mg / L, and Japan is less than 0.01mg / L. The Chinese government has also carried out legislation, such as "Management Measures for the Prevention and Control of Pollution by Electronic Information Produc...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C9/04C22C9/02C22C1/03C22C1/06
CPCC22C1/03C22C1/06C22C9/02C22C9/04
Inventor 杨桂香杨景浩杨景周
Owner 河北雄安地一新材料科技有限公司