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Zero-aldehyde adhesive for plywood and preparation method of zero-aldehyde adhesive

An adhesive and plywood technology, applied in the field of plywood, can solve problems such as unsatisfactory, formaldehyde pollution, leukemia in children, etc., and achieve the effects of low cost, good viscosity performance, and cheap and easy-to-obtain components.

Inactive Publication Date: 2018-03-16
临沂绿醛胶业有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, these adhesives are likely to cause formaldehyde pollution, which may cause leukemia in children; formaldehyde also has toxic effects on the eyes, respiratory system, lung function, nervous system function and immune system of the human body, and has been defined as the first cause of indoor air pollution. Hazardous substances have received more and more attention and awareness from people. The problem of indoor formaldehyde pollution is also an urgent problem to be solved in the wood-based panel industry. How to eliminate the release of formaldehyde from the root cause, many companies have also tried many methods, such as adding amines However, these methods are unsatisfactory and there are still many deficiencies. The formaldehyde emission of the board can barely reach the E0 standard, but the formaldehyde in the adhesive is still is sustained release

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Embodiment one kind of zero-aldehyde adhesive for plywood, comprises each component of following parts by weight: 10 parts of water glass, 5 parts of auxiliary agent, 30 parts of sodium alginate, 20 parts of gelatin, 3 parts of sodium fluorosilicate, halogen-free barrier 10 parts of fuel; 25 parts of cationic water.

[0027] The auxiliary agent includes 8 parts of thickener, 1.5 parts of preservative, and 2 parts of silane coupling agent.

[0028] The thickener includes the following components in parts by weight: 10 parts of flour, 6 parts of pyrophyllite powder, 5 parts of cassava flour, 11 parts of titanium dioxide, 5 parts of pentaerythritol, 12 parts of modified attapulgite clay, 7 parts of modified bentonite 4 parts, 4 parts of polyvinyl alcohol, 20 parts of deionized water. Mix all components evenly before use.

[0029] The preservative is potassium sorbate.

[0030] The halogen-free flame retardant is a phosphorus series flame retardant.

[0031] The prepara...

Embodiment 2

[0037] Embodiment two, a kind of zero-aldehyde adhesive for plywood, comprises each component of following parts by weight: 15 parts of water glass, 15 parts of auxiliary agent, 25 parts of sodium alginate, 15 parts of gelatin, 4 parts of sodium fluorosilicate, halogen-free 5 parts of flame retardant; 30 parts of cationic water.

[0038] The auxiliary agent includes 10 parts of thickener, 1 part of preservative and 1 part of silane coupling agent.

[0039] The thickener includes the following components in parts by weight: 5 parts of flour, 5 parts of pyrophyllite powder, 2 parts of cassava flour, 10 parts of titanium dioxide, 6 parts of pentaerythritol, 11 parts of modified attapulgite clay, 9 parts of modified bentonite 6 parts, 6 parts of polyvinyl alcohol, 10 parts of deionized water. Mix all components evenly before use.

[0040] The preservative is sodium nitrite.

[0041] The halogen-free flame retardant is a combination of one or more of aluminum hydroxide and zinc ...

Embodiment 3

[0048]Embodiment three, a kind of zero-aldehyde adhesive for plywood, comprises each component of following parts by weight: 20 parts of water glass, 10 parts of auxiliary agent, 20 parts of sodium alginate, 10 parts of gelatin, 5 parts of sodium fluorosilicate, halogen-free 7 parts of flame retardant; 20 parts of cationic water.

[0049] The auxiliary agent includes 3 parts of thickener, 2 parts of preservative, and 3 parts of silane coupling agent.

[0050] The thickener includes the following components in parts by weight: 8 parts of flour, 4 parts of pyrophyllite powder, 7 parts of cassava flour, 12 parts of titanium dioxide, 4 parts of pentaerythritol, 10 parts of modified attapulgite clay, 8 parts of modified bentonite , 5 parts of polyvinyl alcohol, 30 parts of deionized water. Mix all components evenly before use.

[0051] The preservatives are potassium sorbate, sodium nitrite and dodecyl dimethyl benzyl ammonium chloride.

[0052] The halogen-free flame retardant ...

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PUM

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Abstract

The invention relates to the technical field of plywood, in particular to a zero-aldehyde adhesive for plywood and a preparation method of the zero-aldehyde adhesive. The zero-aldehyde adhesive for plywood comprises the following components in parts by weight: 10-20 parts of water glass, 5-15 parts of a promoter, 20-30 parts of sodium alginate, 10-20 parts of gelatin, 3-5 parts of sodium fluosilicate, 5-10 parts of a halogen-free flame retardant and 20-30 parts of cationic water. The adhesive is good in viscosity, does not contain formaldehydes products, does not release formaldehyde, methylbenzene, xylene or the like, and can reach fireproof A2 level; and poisonous gas or smoke is not discharged.

Description

technical field [0001] The invention relates to the technical field of plywood, in particular to a zero-aldehyde adhesive for plywood and a preparation method thereof. Background technique [0002] In recent years, my country's wood-based panel industry has developed rapidly. According to records, the output of plywood in my country in 2003 was 21.02 million cubic meters, and the output of blockboard was 6.17 million cubic meters. So far, it has become the world's largest wood-based panel manufacturing and exporting country. The production of wood-based panels inevitably involves the application of adhesives. Nowadays, the main components of adhesives are urea-formaldehyde glue (UF), phenolic glue (PF) and urea-melamine-formaldehyde resin (UMF). According to the wood-based panel industry adhesive dominance of the agent. For example, the Chinese invention patent with application number CN201710317130.1 discloses a special adhesive for wood plywood, which is mainly made of t...

Claims

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Application Information

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IPC IPC(8): C09J105/04C09J189/00C09J11/04C09J11/06C09J11/08C09J1/02
CPCC09J105/04C08K2003/2224C08K2003/2227C08K2003/387C08L2201/02C08L2205/035C09J1/02C09J11/04C09J11/06C09J11/08C08L89/00C08L29/04C08L3/02C08K3/34C08K3/22C08K3/38
Inventor 郑祯勋周中龙
Owner 临沂绿醛胶业有限公司
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