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High-efficiency cleaner for electronic products

A technology of electronic products and cleaning agents, applied in the field of cleaning agents, can solve problems such as unsafe use, environmental pollution, pollution, etc.

Active Publication Date: 2020-07-07
广州诺拜因化工有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The electronic materials used to make electronic products have potential pollution in every production process, which may lead to defects and device failures. If the cleaning effect is not good, it will cause short circuits or even fires, which will directly affect the yield of devices. , performance and reliability
[0003] The cleaning effect of electronic products is determined by the cleaning agents used. The cleaning agents used in the traditional electronics industry contain a large number of substances that destroy the ozone layer, such as trifluorotrichloroethane and 1,1,1-trichloroethane, It will cause pollution to the environment and has been gradually eliminated. The existing cleaning agents for electronic products have high production costs and the cleaning ability needs to be further improved. After cleaning, they will have a certain corrosive effect on materials and contain sodium silicate and sodium carbonate salt pollution. Environmental substances will cause certain pollution to the environment and are relatively unsafe to use

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] A high-efficiency cleaning agent for electronic products is made of the following raw materials in parts by weight:

[0027]

[0028] The preparation method of described fluorine-containing amphoteric surfactant, comprises the steps:

[0029] 1) Dissolve 100 g of N-tris(hydroxymethyl)methyl-2-aminoethanesulfonic acid in 400 g of acetonitrile, and add 200 g of 1-bromooctadecane therein, stir and react at 40° C. for 6 hours, and then pass Rotary steaming, washing 5 times with ether, and rotary steaming again to obtain the intermediate product;

[0030] 2) 90 g of the intermediate product prepared in step 1) was dissolved in 150 g of deionized water, and then 45 g of sodium hydroxide and 36 g of tetrabutylammonium bromide were added thereto, and stirred at room temperature for 0.5 hours, and then added 75g of perfluorodecane bromide, reflux and stir at 70°C for 1 hour, cool down after the reaction, extract with dichloromethane, wash 3 times with water, take the organic...

Embodiment 2

[0032] A high-efficiency cleaning agent for electronic products is made of the following raw materials in parts by weight:

[0033]

[0034] The preparation method of described fluorine-containing amphoteric surfactant, comprises the steps:

[0035] 1) Dissolve 100 g of N-tris(hydroxymethyl)methyl-2-aminoethanesulfonic acid in 500 g of ether, and add 220 g of 1-bromohexadecane to it, stir and react at 43°C for 7 hours, then pass Rotary steaming, washing with ether 6 times, rotary steaming again to obtain the intermediate product;

[0036] 2) 90 g of the intermediate product prepared in step 1) was dissolved in 160 g of deionized water, then 55 g of sodium hydroxide and 38 g of tetrabutylammonium bromide were added thereto, and stirred at room temperature for 1 hour, and then added 80g perfluorooctyl bromide, refluxed and stirred at 75°C for 17 hours, cooled after the reaction, extracted with dichloromethane, washed 4 times with water, dried the organic layer with anhydrous...

Embodiment 3

[0038] A high-efficiency cleaning agent for electronic products is made of the following raw materials in parts by weight:

[0039]

[0040] The preparation method of described fluorine-containing amphoteric surfactant, comprises the steps:

[0041] 1) 100 g of N-tris(hydroxymethyl)methyl-2-aminoethanesulfonic acid was dissolved in 550 g of ethyl acetate, and 280 g of 1-chlorohexadecane was added thereto, and the reaction was stirred at 50° C. for 7 hours, Then by rotary evaporation, washed 6 times with ether, and rotary evaporation again to obtain the intermediate product;

[0042] 2) 90 g of the intermediate product prepared in step 1) was dissolved in 170 g of deionized water, and then 49 g of sodium hydroxide and 39 g of tetrabutylammonium bromide were added thereto, and stirred at room temperature for 0.9 hours, and then added 86g perfluorodecane bromide, reflux and stir at 79°C for 19 hours, cool down after the reaction, extract with dichloromethane, wash 5 times wit...

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Abstract

The invention discloses a high-efficient detergent for an electronic product. The high-efficient detergent is prepared from the following raw materials in parts by weight: 65 to 75 parts of fluorine-containing ampholytic surfactant, 10 to 15 parts of cosolvent, 1 to 3 parts of defoaming agent, and 10 to 15 parts of deionized water. A preparation method of the ampholytic surfactant comprises the following steps: (1) dissolving N-tri(hydroxymethyl)methyl-2-amino ethanesulfonic acid in a solvent, adding long-chained haloalkane, stirring and reacting for 6 to 8 hours at 40 to 50 DEG C, performingthe rotary evaporation, cleaning for 5 to 7 times by using diethyl ether, and then performing the rotary evaporation again to obtain an intermediate product; and (2) dissolving the intermediate product prepared in the step (1) in the deionized water, then adding sodium hydroxide and tetrabutylammonium bromide, stirring for 0.5 to 1.5 hours at the room temperature, adding fluorine-containing long-chained halohydrocarbon, refluxing, stirring and reacting for 15 to 20 hours at 70 to 85 DEG C, after the reaction is ended, cooling, extracting by using dichloromethane, washing for 3 to 5 times by using water, drying organic layer anhydrous magnesium sulfate over night, and performing the rotary evaporation to remove the solvent. The high-efficient detergent for the electronic product has highercleaning capacity and a higher cleaning effect, achieves lower cost and environment-friendlomess, and has the antibacterial performance.

Description

technical field [0001] The invention relates to the technical field of cleaning agents, in particular to a high-efficiency cleaning agent for electronic products. Background technique [0002] With the advancement of science and the development of society, electronic products have entered thousands of households and are closely related to people's lives. In the process of production, processing and preparation of electronic products, due to the precision and technical requirements of electronic products, the products need to be processed and cleaned. The surface cleanliness of electronic materials directly affects the physical and electrical properties of electronic materials, which in turn affects the normal use of electronic products. The electronic materials used to make electronic products have potential pollution in every production process, which may lead to defects and device failures. If the cleaning effect is not good, it will cause short circuits or even fires, whi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C11D1/88C11D3/60C11D3/48C11D3/20C11D3/36C11D3/37C07C303/32C07C309/14
CPCC07C303/32C11D1/88C11D3/201C11D3/2017C11D3/2044C11D3/2072C11D3/2093C11D3/362C11D3/373C11D3/48C07C309/14
Inventor 杨俊
Owner 广州诺拜因化工有限公司
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