Treatment and high-value application method of biodegradable sewage
A sewage treatment and high-value technology, which is applied in the fields of environmental protection and comprehensive utilization of resources, can solve the problems of small treatment scale, high requirements for control of feeding and operating conditions, and high cost, and achieves easy storage and transportation, good hydrophobicity, and high cost. Avoid the effect of the input of electrical energy
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Embodiment 1
[0048] The treatment object is the papermaking wastewater produced by a paper mill, COD Cr About 25000~30000mg / L. The anaerobic granular sludge from the anaerobic sewage treatment of the plant was introduced into the anaerobic reactor of the fermentation unit and the carbon chain biological extension unit as the starting agent, and the inoculation amount was 10g VS / L. In the carbon chain extension reactor, 50mM 2-BES (sodium 2-bromoethanesulfonate) is added to inhibit the metabolic activity of methanogens, and domesticate the dominant bacteria group for carbon chain extension metabolism. The reaction temperature is 35±1°C. pH 7±0.2, hydraulic retention time equal to 6 days. The carbon chain extension unit passes into brewery wastewater (which contains 5-6% ethanol) to provide electron donor electrons. Separation of n-hexanoic acid by liquid-liquid osmotic extraction.
[0049] During 120 days of operation, the average yield of n-hexanoic acid is about 5.32g / L / d, the maximum ...
Embodiment 2
[0051] The treatment object is beer wastewater produced by a brewery, COD Cr About 20000~25000mg / L. The anaerobic sludge produced by domestic sewage treatment was introduced into the anaerobic reactor of the fermentation unit and the carbon chain biological extension unit as the starting agent, and the inoculation amount was 8g VS / L. In the carbon chain elongation reactor, the metabolic activity of methanogens is inhibited by controlling pH=5.5, and the dominant bacteria group for carbon chain elongation metabolism is domesticated. The reaction temperature is 30±1°C, pH 5.5, and the hydraulic retention time is equal to 5 days. The sewage itself contains 5% to 6% of ethanol, and there is no need to add alcohol-containing sewage. Extraction and separation of n-hexanoic acid by hollow fiber membrane.
[0052] During the 550-day running time, the average yield of n-hexanoic acid was 3.38±0.42g / L / d, and the COD removal rate was greater than 85%.
Embodiment 3
[0054] The object of treatment is anaerobic fermentation broth of syngas, COD Cr About 15000~20000mg / L, containing 11.4g / L ethanol and 2.3g / L acetic acid. The anaerobic sludge produced by domestic sewage treatment was introduced into the anaerobic reactor of the fermentation unit and the carbon chain biological extension unit as the starting agent, and the inoculation amount was 6g VS / L. In the carbon chain extension reactor, the metabolic activity of methanogenic bacteria is inhibited by controlling pH=5.5, and the dominant bacteria group for carbon chain extension metabolism is domesticated. The reaction temperature is 30±1°C, pH 5.5-6.5, and the hydraulic retention time is equal to 8 days. . The sewage itself contains ethanol, and there is no need to add alcohol-containing sewage. Extraction and separation of n-hexanoic acid by ion exchange membrane.
[0055] During 550 days of operation, the average yield of n-hexanoic acid is about 1.7g / L / d, and the average yield of n-...
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