A treatment method for steel rolling oily sludge

A treatment method, oil sludge technology, applied in sludge treatment, water/sludge/sewage treatment, metallurgical wastewater treatment, etc., can solve the problems of high iron content, long treatment process, high energy consumption, etc., and reach the total iron content High efficiency, low operating cost, and low processing energy consumption

Active Publication Date: 2021-05-14
BAOSHAN IRON & STEEL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] 1) landfill, final disposal but there are shortcomings of occupying land and waste of iron resources;
[0004] 2) Incineration, the oil (organic matter) removal effect is good, but it has the disadvantages of high energy consumption and the need to deal with the exhaust gas;
[0005] 3) Low-temperature distillation can recover oil and iron resources, but oil purification is more complicated and costly, and is suitable for the treatment of high oily sludge;
[0006] 4) Solvent extraction can recover oil and iron resources, but there are long processing procedures, troublesome waste solvent reuse and solvent safety issues;
[0011] 3) Back-coking requires drying and coal-mixing pretreatment, and because of the high iron content, it has negative effects on coke gas permeability and coke oven refractory bricks;
[0012] 4) Back to sintering, during the sintering process, the oil will volatilize and enter the flue gas of the main flue, which will have a negative impact on the safety of the electrostatic precipitator;

Method used

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  • A treatment method for steel rolling oily sludge

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] 1. The oily sludge produced by hot-rolling circulating water treatment has an oil content of 7.4%, a water content of 18.1%, and a total iron content of 48.5% (dry basis). 200 meshes of 5% quicklime powder are added to it, and after mixing, it is fed to the sludge by a screw. The feeder is sent into the kiln head of the rotary kiln reactor, and the process parameters in the rotary kiln reactor are controlled as follows: temperature 400°C, air excess coefficient 0.5, reaction time 20min; the average concentration of CO in the discharged combustible gas is 2500ppm, and the The combustible gas is ignited, and the hot flue gas with a temperature of 580°C is returned to the outer jacket of the rotary kiln reactor as an external heat source, and the flue gas after heat exchange is discharged after subsequent treatment; the rotary kiln tail is deoiled The final residue has a total iron content of 60.4%, a CaO content of 10.4%, a total carbon content of 2.4%, an oil content and ...

Embodiment 2

[0040] The oily sludge produced by the treatment of a thick plate circulating water has an oil content of 4.5%, a water content of 15.1%, and a total iron content of 51.6 (dry basis). 200 meshes of 3.5% quicklime are added to it, mixed and passed through a screw feeder Send it into the kiln head of the rotary kiln reactor, and control the process parameters in the rotary kiln reactor as follows: temperature 360°C, air excess coefficient 0.4, reaction time 15min; the average concentration of CO in the discharged combustible gas is 1358ppm, which can be The gas is ignited, and the hot flue gas with a temperature of 520 ° C is returned to the outer jacket of the rotary kiln reactor as an external heat source. The flue gas after heat exchange enters the subsequent treatment and is discharged; The total iron content of the residue is 60.6%, the CaO content is 8.4%, the total carbon content is 2.1%, the oil content and water content are zero, and it is back-sintered for production an...

Embodiment 3

[0042] The oily sludge produced by the first rolling circulating water treatment has an oil content of 9.9%, a water content of 22%, and a total iron content of 47.6% (dry basis). 7.5% quicklime is added to it, and after mixing, it is sent to the sludge by a screw feeder. into the kiln head of the rotary kiln reactor, and the process parameters in the rotary kiln reactor are controlled as follows: temperature 450°C, air excess coefficient 0.7, reaction time 25min; the average concentration of CO in the discharged combustible gas is 2710ppm, and the combustible gas Ignite, return the hot flue gas with a temperature of 700°C to the outer jacket of the rotary kiln reactor as an external heat source, and the flue gas after heat exchange will be discharged after subsequent treatment; the residue after deoiling at the rotary kiln tail The total iron content is 59.8%, the CaO content is 11.6%, the total carbon content is 2.3%, the oil content is less than 0.1%, and the moisture conten...

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Abstract

A method for treating oily sludge from steel rolling. First, the oily sludge from steel rolling is mixed with quicklime powder, and the proportion of quicklime powder added to the oily sludge from steel rolling is 2.5 to 7.5% by weight; then put into a rotary kiln reactor for low-temperature gasification Oil treatment, in which the temperature is 300-500°C, the air excess coefficient is 0.2-0.8, and the reaction time is 10-30 minutes; then the combustible flue gas discharged from the rotary kiln reactor enters the secondary combustion chamber for combustion, and the hot flue gas produced is returned to the Enter the rotary kiln reactor as the external heat source of the rotary kiln reactor, and the oily sludge residue from steel rolling after deoiling is used as the raw material for ironmaking and sintering. The method of the invention has the advantages of low energy consumption, low pollutant discharge, and the deoiling residue can be returned to production and utilization within iron and steel enterprises.

Description

technical field [0001] The invention relates to a waste treatment method, in particular to a treatment method for steel rolling oily sludge. Background technique [0002] There are two main sources of oily sludge from steel rolling: one is the sludge generated by direct cooling of circulating wastewater in processes such as hot rolling, preliminary rolling, and thick plates, which is treated by cyclone sedimentation and then by advection sedimentation; The effluent after precipitation is filtered by the filter and then reused. The laminar flow cooling wastewater of the strip steel is filtered and reused after precipitation. The above two filters backwash the effluent and precipitate the sludge; The characteristics of iron oxide, generally, the water content is 10-20%, the oil content is 1-10%, and the total iron content is 30-55%. The main treatment and disposal methods of steel rolling oily sludge are: [0003] 1) landfill, final disposal but there are shortcomings of occ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F11/00C02F11/10C10B53/00C02F103/16
CPCC02F11/00C02F11/10C02F2103/16C10B53/00
Inventor 王如意李建刘剑平徐万仁
Owner BAOSHAN IRON & STEEL CO LTD
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