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Fireproof door core material and preparation method thereof

A fire door and core material technology, applied in the field of flame retardant materials, can solve the problems of high energy consumption, environmental pollution, high price, complex process, etc., and achieve the effects of good flame retardant effect, easy large-scale production and simple preparation process.

Pending Publication Date: 2018-12-11
江苏凯尔消防工程设备有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The fire door core board is the material filled in the fire door. As the core material of the steel fire door, one is aluminum silicate cotton board. The production process requires high temperature sintering to make cotton, which has the defects of high energy consumption and environmental pollution. , especially its board is formed by the added organic binder, not only is not waterproof, its binder produces a lot of harmful smoke in case of fire, it has been banned; the other is perlite board, although it has non-combustible, light weight, sound insulation , heat insulation and other advantages, but expanded perlite is a substance with a small density and is easy to generate dust during the production process. Severe dust pollution will cause damage to human health. At the same time, its strength is very poor. Some data show that its transportation The damage rate during installation and installation is as high as 30%, which not only increases the cost of use, but also affects the fireproof, heat preservation and sound insulation effects of the board due to its fragility; there is also a vermiculite fireproof board, which not only has perlite-like The brittle defect of slate also has the problem of complex process and higher price than the above two kinds of plates; another is the mixed molding of magnesite material and foaming agent, which is the material selected by most fire door enterprises now, but its existence Problems such as easy deformation, back brine, hardness drop, etc.

Method used

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  • Fireproof door core material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] A method for preparing an intumescent flame retardant material containing silicon, nitrogen and phosphorus, comprising the steps of:

[0025] (1) Under the protection of an inert gas and at room temperature, the solvent for the reaction is dichloromethane, and chlorosilane and dimethyl phosphonate are reacted for 3 hours to obtain dimethyl silyl phosphonate; the chlorosilane is Trimethylchlorosilane; the molar ratio of said chlorosilane to dimethyl phosphonate is 1: 3.5;

[0026] (2) Under the protection of an inert gas and at 370°C, react the product obtained in step (1) with dimethyl alkylsilylphosphonate and melamine for 4 hours under the action of anhydrous magnesium chloride, and cool to 300°C; the obtained product in step (1) The mol ratio of alkyl silyl phosphonate dimethyl and melamine is 1: 1.1;

[0027] Sampling, washing, drying and pulverization, the degree of polymerization of the product is 750, and the decomposition temperature of 1% thermal weight loss i...

Embodiment 2

[0031] A method for preparing an intumescent flame retardant material containing silicon, nitrogen and phosphorus, comprising the steps of:

[0032] (1) Under the protection of an inert gas and at room temperature, the solvent for the reaction is dichloromethane, and chlorosilane and dimethyl phosphonate are reacted for 3 hours to obtain dimethyl silyl phosphonate; the chlorosilane is Triethylchlorosilane; the molar ratio of said chlorosilane to dimethyl phosphonate is 1: 3;

[0033] (2) Under the protection of an inert gas and at 350°C, react the product obtained in step (1) with dimethyl alkylsilylphosphonate and melamine for 4 hours under the action of anhydrous magnesium chloride, and cool to 300°C; the obtained product in step (1) The molar ratio of dimethyl silicon-based phosphonate to melamine is 1:1.1.

[0034] Sampling, washing, drying and crushing, the degree of polymerization of the product is 990, and the decomposition temperature of 1% thermal weight loss is 235....

Embodiment 3

[0038] A method for preparing an intumescent flame retardant material containing silicon, nitrogen and phosphorus, comprising the steps of:

[0039] (1) Under the protection of an inert gas and at room temperature, the solvent for the reaction is chloroform, and chlorosilane and dimethyl phosphonate are reacted for 2 hours to obtain dimethyl silyl phosphonate; the chlorosilane is tripropyl Chlorosilane; the molar ratio of silane and dimethyl phosphonate is 1:4;

[0040] (2) Under the protection of an inert gas and at 350°C, react the dimethyl alkylsilylphosphonate obtained in step (1) with melamine under the action of triphenyl phosphate for 3 hours, and cool to 300°C; step (1) The molar ratio of the resulting alkylsilylphosphonic acid dimethyl to melamine is 1:1.1.

[0041] Sampling, washing, drying and crushing, the product has a degree of polymerization of 800 and a decomposition temperature of 1% thermal weight loss of 237.6°C.

[0042] (3) Cool down to 250°C at a rate o...

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Abstract

The invention provides a fireproof door core material. The fireproof door core material is at least prepared from the following components: 10 to 15 parts of light calcined magnesium powder, 10 to 15parts of aluminum hydroxide, 10 to 20 parts of fireproof ceramic, 30 to 50 parts of an expansion type flame-retarding material containing silicon nitrogen phosphorus, 10 to 15 parts of attapulgite, 3to 8 parts of tricresyl phosphate, 5 to 10 parts of carboxymethyl cellulose, 1 to 2 parts of a dispersant, 1.5 to 2 parts of a de-foaming agent, 30 to 50 parts of solvent oil and 5 to 15 parts of dimethicone. The invention further provides a preparation method of the fireproof door core material. The fireproof door core material has the advantages of simple preparation technology, can be easily produced in a large scale and has a good flame-retarding effect.

Description

technical field [0001] The invention belongs to the field of flame retardant materials, and in particular relates to a fire door core material and a preparation method thereof. Background technique [0002] A fire door is a door that can meet the requirements of fire resistance stability, integrity and thermal insulation within a certain period of time. It is a fire-resistant partition with certain fire resistance located in fire compartments, evacuation stairwells, vertical shafts, etc. In addition to the function of ordinary doors, fire doors also have the function of preventing the spread of fire and smoke. It can prevent the spread of fire within a certain period of time and ensure the evacuation of people. [0003] The fire door core board is the material filled in the fire door. As the core material of the steel fire door, one is aluminum silicate cotton board. The production process requires high temperature sintering to make cotton, which has the defects of high ene...

Claims

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Application Information

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IPC IPC(8): C08L85/02C08L1/28C08K3/22C08K3/34C08K5/523C08K3/00
CPCC08L85/02C08L2201/02C08K2003/2227C08K2003/222C08L1/286C08K3/22C08K3/346C08K5/523C08K3/00
Inventor 朱善义张庆雳邱小庆
Owner 江苏凯尔消防工程设备有限公司
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