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Temperature-resistant and salt-resistant low-tension nanometer microsphere regulating and displacing agent and preparation method thereof

A temperature-resistant, salt-resistant, nano-microsphere technology, applied in chemical instruments and methods, earthwork drilling, wellbore/well components, etc., can solve problems such as reducing costs, reducing the amount of common emulsifiers, and reducing the ability of oil-water interface, etc. Achieve the effects of cost reduction, high extractable solids content, and ultra-low plugging performance

Active Publication Date: 2021-05-11
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] One of the technical problems to be solved by the present invention is that the polymer microspheres in the prior art mainly play the role of profile control, and the surfactant mainly plays the role of oil washing. Generally, the combination of the two is required to achieve both adjustment and flooding. To solve the problem of function, provide a temperature-resistant, salt-resistant and low-tension nano-microsphere regulating and displacing agent. By adopting the method of inverse microemulsion polymerization, the surfactant for oil displacement with the ability to reduce the oil-water interface is partially replaced by the emulsifying agent in the reaction system. After the reaction is completed, add a surfactant that can form an ion-pair interaction with the ionic or amphoteric surfactant in the composite emulsifier as a phase inversion agent to form an anion-positive composite surfactant micelle to enhance oil displacement. One is to reduce the amount of common emulsifiers that are ineffective for oil displacement and reduce the cost. The other is that surfactants for oil displacement are arranged on the oil-water interface of nano-microspheres as emulsifiers and act on the oil-water interface in the form of microemulsions. It not only improves the oil washing efficiency of the surfactant used in oil displacement, but also has a certain effect of regulating and driving

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] First add 1200g of white oil, 150g of SPAN80, 120g of coconut acid monoethanolamide, 50g of tetradecyl polyoxyethylene ether sulfobetaine (the HLB of the emulsifier system is about 6.8) into the reaction kettle, and stir until completely mixed , the temperature in the kettle was controlled to be 28° C., and the stirring speed was maintained at 400 rpm. In another container, add 670g of water, 850g of acrylamide, 200g of sodium 2-acrylamido-2-methylpropanesulfonate, 4g of sodium 2-acrylamidotetradecylsulfonate, 40g of sodium acetate, ethylenediamine Disodium tetraacetate 0.8g, urea 12g, isopropanol 25g, methylene bisacrylamide 2.5g, stirred and dissolved evenly as the water phase; 1.6g of ammonium persulfate and 1.2g of sodium bisulfite were dissolved in 20g of water for later use . Add 700g of water phase to the oil phase in the reaction kettle, stir for several minutes until emulsified evenly, add all the oxidizing agent aqueous solution after 10 minutes of nitrogen g...

Embodiment 2

[0042] First add 1200g cyclohexane, 120g SPAN80, 120g oleic acid monoethanolamide, 100g palmitic acid polyoxyethylene ether (EO number=3) sodium sulfonate (emulsifier system HLB is about 6.6) in the reaction kettle, stir until Mix completely and uniformly, as the oil phase I, control the temperature in the kettle to 20°C, and the stirring speed to 400rpm; in addition, dissolve 5g of N-phenylmaleimide and 6g of azobisisobutyronitrile in 29g of ethyl acetate, as oil phase II. In another container, add 670g of water, 900g of acrylamide, 150g of sodium 2-acrylamido-2-methylpropanesulfonate, 35g of sodium acetate, 0.8g of disodium edetate, 10g of urea, and 30g of n-butanol, 2.5g of methylenebisacrylamide was stirred and dissolved evenly as the water phase; 1.4g of ammonium persulfate and 1.2g of sodium bisulfite were dissolved in 20g of water respectively for later use. Add 700g of water phase and 16g of oil phase II to the oil phase in the reaction kettle, stir for several minute...

Embodiment 3

[0045]First add 1200g of liquid paraffin, 200g of SP85, 70g of cocoic acid monoalcoholamide, 50g of N,N-dicetanoylhexamethylene diamine dipropionic acid dipolyoxyethylene ether (EO number = 3) dicarboxylate in the reaction kettle (The HLB of the emulsifier system is about 7.2), stir until it is completely mixed evenly, as the oil phase I, the temperature in the kettle is controlled at 25°C, and the stirring speed is 400rpm; The nitrile was dissolved in 28 g of ethyl acetate as oil phase II. In another container, add 670g of water, 800g of acrylamide, 120g of sodium 2-acrylamido-2-methylpropanesulfonate, 80g of N-vinylpyrrolidone, 45g of sodium acetate, and 1.2g of disodium edetate, 12g of urea, 30g of n-hexanol, and 2.8g of polyethylene glycol diacrylate were stirred and dissolved evenly as the water phase; 1.3g of ammonium persulfate and 1.1g of sodium bisulfite were dissolved in 20g of water for later use. Add 700g of water phase and 16g of oil phase II to the oil phase in ...

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Abstract

The invention relates to a temperature-resistant, salt-resistant, low-tension nanometer microsphere regulating and displacing agent and a preparation method thereof, which mainly solves the problems in the prior art that the polymer microsphere mainly plays the role of profile control, and the surfactant mainly plays the role of washing oil. Generally, the compounding of the two is needed to achieve the functions of regulating and driving. The invention adopts a temperature-resistant, salt-resistant, low-tension nano-microsphere regulating and displacing agent, which is prepared by reacting a reaction system comprising the following components in the presence of a composite initiator in parts by weight: 20 to 70 parts of oil Soluble solvent; 5-20 parts of composite emulsifier system containing surfactants for oil displacement; 20-70 parts of water phase containing water-soluble monomers such as acrylamide and temperature-resistant and salt-resistant monomers, monomers in the water phase The content of cross-linking agent is 40-70%; the technical scheme of 0.05-2 parts of cross-linking agent solves this problem better, and can be used for deep profile control and oil displacement in high-temperature and high-salt reservoirs to enhance recovery Live application.

Description

technical field [0001] The invention relates to a temperature-resistant, salt-resistant, low-tension nanometer microsphere regulating and displacing agent and a preparation method thereof. Background technique [0002] The inverse microemulsion polymerization system is a thermodynamically stable colloidal dispersion system. The formation of the microemulsion does not require external work, and it mainly depends on the matching of various components in the system to form spontaneously. The matching between the oil phase, the water phase and the emulsifier system is the microemulsion. The key to formation and stability. The structure of the microemulsion varies with the ratio of oil to water, type of surfactant, temperature, electrolyte concentration, chemical properties of the oil phase and the proportion of each component. The preparation and optimization of the microemulsion system before polymerization is the basis of inverse microemulsion polymerization. In order to incr...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K8/584C09K8/588C08F220/56C08F2/32C08F4/40C08F220/58C08F222/38C08F226/10C08F220/06C08F212/36C08F220/34E21B43/22
CPCE21B43/16C09K8/584C09K8/588C08F2/32C08F4/40C08F220/56C08F220/585C08F222/385C08F226/10C08F220/06C08F212/36C08F220/34
Inventor 夏燕敏宋晓芳许汇苏智青王兰
Owner CHINA PETROLEUM & CHEM CORP